Вы находитесь на странице: 1из 8

Archive of SID

~  {
1383 273-280 5
ISSN : 1016-3255

|~
| }
Investigation of the Mechanical Properties of Polyvinyl Alcohol

Nanocomposite Hydrogels
3~ *2 1| ~

|14115/143 } ~

SI

 ~ - 2 ~ -1 ~ ~ ~ { {

|14115/331 } ~ |  ~ ~ { { - 3

of

|83/4/23 : 82/11/25 :

  } ~  |

ive

| |  | | .
| ||  } |~  .~| |
~ }  { | - } ~ ~
} } |~ | | ~| } .

ch

|~ }  { ~ ~| .~~ }
. } } { ~ }

Ar

~ |
} ~
||
-

~
}  | { ~}
. ~ |
{ } |
| -| ~
.[4| 5] ~ 
~ {  |

{  |
~ | 
} | ~}
[1] ~| ~ ~
[2]  
.~ [3] |}

Key Words
nanocomposite hydrogel,
polyvinyl alcohol, Montmorillonite,
mechanical properties, freezingthawing

mehrir@modares.ac.ir : | { *

www.SID.ir

| ~

Archive of SID

| } |~

|P A A m ~ | ~
|~ [9]| .~|
{ P A A m | } - 
|~ ~ ~ ~ {
. ~ }
_ -  |
{ ~|{ 
| .~|
. } ~|{ }
~ | ~ { | |
.~| { }  }
| | | 1
 } ~ .~| 
{ |
~{ ~ .~| {  |

Ar

ch

ive

of

SI

~ { }
| .~~ 
 |  ~{
| .
~|{ } ~ ~ 
. ~
{ } } ~
~| }  |
| { ~ } .[6]
} {  | {
| |.|[7] ~  }
} | ~ |
~  |
[8] .~| |
~ } ( P A A m ) ~||  } |~

()  () : -  |  | | - 1
| .|[10]| | {  () | { ~ 

1383 - 5 ~  { 

274
www.SID.ir

| ~

Archive of SID

| } |~

SI

Ar

ch

ive

of

} |~ { ~
PVA ~ 15 | ~}| |
) ~ 10 { 0 } ~
| -  ~ { (PVA
| . ~
) ~ | {
{ {  { ( ~
4 h ~ ~} |PVA| .~ ~ 90oC
.~ ~
} ~ }
| .~ { }
~ { ~ ~ {
.~ {
}
 200 rpm
100 rpm } |
.~
| } { 
- { ~ } } }
-20oC | 24 h ~  ~ .
24 h ~  . ~
~ . { { ~ 23oC
|~ .~ { }
| { }
.~~ ~ } |
| ~|{ ~ ~ 1 ~
~ ~ . ~ ~ {
| ~ ~
|.~ { {

|~ {

 | 
} ~ .( 1 ) ~
 |  ~|{
{  |
.| 
_
| |.[10]| ( 1 )
 } } |~ 
| |(PVA) | | ~
| ~ (MONT) ~ ~
}~ ( O M O N T )
|~ { ~ . ~ } |
} .[5]| ~ | -
} |~ ~|
~  { }
|. ~ }

} {

{ } |~ }
{ | | {
.~ } (XRD)
3 | } } ~

275

1383 - 5 ~  { 

 ~{  
~  ~ 98 } ~| || | | 
| | . ~ } { 1700
| | ~{ ( O M O N T ) ~ ( M O N T ) ~
~ | | || Zhejian Fenghong Clay|
~ { { . {
| {| | { . 100 mEq / 100 mg
. ~ } {
|}

( X R D ) { } 
| X R D { ~ Philips|
} { .~ } } |~
  5 ton }  {
Harteprufer |} } | } {
|.~ }

www.SID.ir

| ~

Archive of SID

| } |~

~ {| |Wc|
|: 1 ~
~ ~ |= [(Wi - Wc) / (Wf - Wc)] * 100

| |~ ~ - 1 ~
.~ {

(1)|
|

MONT

PVA

0/3
0/75
1/05
1/5

0/75
1/5

15
15
15
15
15
15
15

1
2
3
4
5
6
7

| 7 { 1 | |
ASTM D 1822 L ~} 
| .~ } ~ { 3 mm
} | (|23oC)
. ~ |~ | 100 mm/min
7 { 1 | } |~ } {
ASTM D 2240 ~} 6 mm
 } | } { .~~ {
} ~} .~ } A
} .~ |~ } 
} ~  15 s
. ~ ~ ~ 

OMONT

ive

of

SI

} ~ .~ 7

_ { 4 h ~
.
|

}

ch

} |~ | |

Ar

~ MONT| XRD| {{ 3 2 |


O M O N T M O N T| ~ 1 0 } 
.~| |OMONT| ~ 10 } ~
| ~ 2
~ ~ =| 7|/| 8o ~ MONT|
.~| 2 =| 2/| 6o ~ MONT ~ 10 PVA
} ~| 3
~ 10 { 2 =| 6/ 7o ~ OMONT
.~| 2 =| 2/ 2o ~ PVA|
~
{ ~ | | }
) | { (| ~ )
| .|[11]|~|~ {  (
PVA } |~ ~| ~

~ ~ {

| ~ | {
| .| } 
~ {| }
(MONT PVA |OMONT) | ~|{
. } ~
.~ (7 { 1 |) ~ { } |~
(2g ~ ) | _{ |{ ~ ~ {
.|
}
{ | ~
{ (Wi) } ~ ~
.~| ~ { ~ .~|
{ ~ 
| } { ~| |
~ { . } } ~
~ ~| ( 3 { 2 ~ )
~ } .| {
.~|

~ ~ {
.~| | { | (Wf)|
~ ~ Wf| Wi } |

1383 - 5 ~  { 

276
www.SID.ir

| ~

Archive of SID

| } |~

MONT

PVA-%MONT

()

SI

} ~ |MONT| XRD| - 2
.|MONT ~10

{ ~ } OMONT MONT|
|.~ 1 ~} | |
~ ~

~ ~ | ~| ~
}   { ~ ~
~ .~ {
} ~|~ | ~| ~ {
{ | ~ | . ~ 4
} (1 ) PVA ~ ~ |

Ar

ch

ive

of

|O M O N T | M O N T ~ . ~|
| |~ ~| ~ 
~| ~ M O N T ~ 1 0
~| 4 .~| ~ 83/5 ~ 79/4
~ ~| ~
|OMONT| |MONT| } |~
~| ~ ~ } .~}| { _ {
~ ~| { |
{ { | | ~ ~ 
| } .|
P V A |  | | ~  |
|.~|
~| 4
(MONT) ~ | |~
|~ } ~| ~
~ .~ ( O M O N T ) ~ |
~ 81/3 OMONT ~ 10 ~ ~|
MONT ~ 10 ~
|. ~ 83/5
|M O N T } ~ | ~
{| (~ ) | O M O N T| ( ~ )
| P V A | } ~
} . { ~ 
~   }
|. } ~ |

OMONT

PVA-%MONT
MONT
OMONT

()
MONT } |~ ~ ~ - 4

.|OMONT
277

1383 - 5 ~  { 

} ~ |OMONT XRD - 3
.O M O N T ~10

www.SID.ir

| ~

Archive of SID

| } |~

SI

Ar

ch

ive

of

  |
{| . _}  (~ 5  ~ )
 P V A ~
.|  { ~
~|{ } |~
 | { | 
~| .~ ~
} |~  {
| { ~
|{ { ~| } 
.~ (} ) { ~
|  {
~  { ~ | 7 O M O N T MONT

}  | ~ - { - 6
|.|OMONT

10 5 } |~ - {
(7 5 |) OMONT (3 2 |) |MONT ~
6 5 | (1 ) |PVA| ~
|~ | ~ 5 . ~
M O N T } 
~ } {{
| - { .~|
{ { ~  ~|
.~| ~ {
|~ - { }
.| ~ 6 OMONT| }
~ - { {
{ ~ { . }
 { } . ~
~  ~ | }
. ~ | }
|~  { 7
} ~ { OMONT |MONT|
 { | ~ | .~|
 M O N T |
10~ { |PVA|~ MONT| .~|
.~|  { ~ ~
|~  { ~
~ |OMONT| }
~ 7 | .~| { }

MONT
OMONT

~  |~  { - 7
|.

}  | ~ - { - 5
.|MONT

1383 - 5 ~  { 

278
www.SID.ir

| ~

Archive of SID

| } |~

MONT
OMONT

~  |~ } - 8
.

SI

|O M O N T } |~
} |~ }
|OMONT| ~ 10 .~| |MONT
{ { |  | P V A| ~ }
10 } 3/1 
.| 1/4 { |MONT| ~
| ~ {
. |M O N T| O M O N T |
|  OMONT ||
~ ~ }  |
. | }
{ |  |O M O N T| | ~ ~ 
(} ) {| ~
.~
|~ } 8
} ~ O M O N T M O N T }
~ | .~|
 ~ |
{ | |~ }

Ar

ch

ive

of

} PVA ~ ~ |
~ { . }
} MONT } |~
OMONT } |~ }
} } .~
 | ~ }
 ~ ~
|.
 | }
~| | ~|{
~ | { _ { . ~
- { 
~ 2 ~ .~| }
~ } |~
~ } ~| } .
~ .| ~  PVA|
~ | |
| } | O M O N T | ~
|. |MONT|
| } { ~|
} | M O N T O M O N T
}
_ ~ 
.~  {
|M O N T | ~ } {  }
9 } ~ { O M O N T
| ~ . ~

|~ (MPa ) ~ - 2 ~
.}
MONT
OMONT

~
10

. ~  |~ } - 9
279

1383 - 5 ~  { 

3/6 3/3
3/8 3/7 3/6 3/3

3
3

MONT
OMONT

www.SID.ir

| ~

Archive of SID

| } |~

~ } |~ }
.| }  ~
P V A ~ } |~ }
. } ~{ ~
} ~  |
~ ~ {|} } ~ 
~ |  .| ~
~ }
.~ {| 
} ~| 9
} } |MONT } ~
~| } . O M O N T }  ~
~ 1/4 M O N T ~ 1 0 ~ }
|~ {| ~| . O M O N T|
OMONT |~ MONT
 MONT|}~ . |MONT }~
} { } ~ { |
{|} ~ } ~ PVA ~ 
. {|

ive

of

SI

~ ~ {
|~ {  PVA|
~ 10 { .| ~
} ~ | |PVA ~ |OMONT|
{{ } ~  {
~ | 1/5 1/3 3/1 ~
| P V A ~ } . |
.~
~  }
|~ }
~  { O M O N T }
|~ } } } }
|.~| | M O N T | } 
}
} ~} } |~ { }
|~ {| } 
|.

ch

1. Peppas N.A., Development of Crosslinked PVA Biomembrances, Polym. Prepr., 18, 794-797,1977.

Thermal/Mechanical Properties of Poly(ethylene oxide)-Clay


Blends, Polymer, 38, 5115-5118, 1997.
8. Gao D. and Heimann R.B., Structure and Mechanical Properties

Alcohol and Polyvinyl Pyrrolidone Blended Hydrogel for

of Super-absorbent Poly(acrylamide)-Montmorillonite Compos-

Ar

2. Razzak M.T., Darwis D. and Sukirno Z., Irradiation of Polyvinyl

Wound Dressing, Radiat. Phys. Chem., 62, 107-113, 2001.

ite Hydrogles, Polym. Gels. Networks, 1, 225-246, 1993.

3. Peppas N.A., Bures P., Leobandung W. and Ichikawa H., Hydro-

9. Churochkina N.A., Starodoubtsev S.G. and Khokhlov A.R.,

gels in Pharmaceutical Formulations, Eur. J. Pharmace. Bio-

Swelling and Collapse of the Gel Composite Based on Neutral

pharmace., 50, 27-46,2000.

and Slightly Charged Poly(acrylamide) Gels Containing Na-

4. Yoshii F., Makuuchi K., Darwis D., Iriawan T., Razzak M.T. and
Rosiak J.M., Heat Resistance Poly(vinyl alcohol) Hydrogel,
Radiat. Phys. Chem., 46, 169-174, 1995.
5. Stauffer S.R. and Peppas N.A., Poly(vinyl alcohol) Hydrogels
Prepared by Freezing-Thawing Cyclic Processing, Polymer, 33,
3932-3936, 1992.
6. Theng B.K.G., Formation and Properties of Clay-Polymer
Complexes, Elsevier, Amsterdam, 1-22, 1979.

Montmorillonite, Polym. Gels. Networks, 6, 205-215, 1998.


10. Alex M. and Dubois P., Polymer Layered Silicate Nanocomposites: Preparation, Properties and Uses of a New of Materials,
Mater. Sci. Eng., 28, 1-63, 2000.
11. Cypes S.H., Saltzman W.M. and Giannelis E.P., OrganosilicatePolymer Drug Delivery Systems: Controlled Release and
Enhanced Mechanical Properties, J. Controll. Release, 90, 163169, 2003.

7. Ogata N., Kawakage S. and Ikada T., Structure and

1383 - 5 ~  { 

280
www.SID.ir

Вам также может понравиться