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Volume of
oxalic Acid
(mL)
100
80
60
40
20
10
Volume of
water (mL)
0
20
40
60
80
90
Diluition factor
of Oxalic Acid
none
4 in 5
3 in 5
2 in 5
1 in 5
1 in 10
The previous values are moles per litre, therefore we must divide by 10 (because
100ml is used, not a litre);
Number of
moles (mol)
0.005
0.004
0.003
0.002
0.001
0.0005
Total
titratio
n
volume
(L)
0.0496
0.04034
0.029
0.0191
0.01155
0.00679
How many moles of KMnO4 does this correspond to? Molarity x vol (l) = no.
of moles
Moles KMnO4
used
0.000496
0.0004034
0.00029
0.000191
0.0001155
0.0000679
Use the reaction ratio from the balanced equation (5:2) to give no. of
moles of oxalic acid
moles of O.A. in
excess
0.00124
0.0010085
0.000725
0.0004775
0.00028875
0.00016975
Multiply by molecular weight of Oxalic acid to give; grams of oxalic acid in
excess
EXCESS
O.A.
Grams of
O.A.
0.1116
0.090765
0.06525
0.042975
0.0259875
0.0152775
0.0297375
Divide by mass/ weight of charcoal (m) to give amount adsorbed per gram
O.A. Adsorbed Per Gram Of
Charcoal
x/m
0.167956541
0.133337459
0.099858626
0.067994097
0.031690089
0.014449006
6. Plot (x/m) vs c
(x/m) is given in 5
C is given in 2
Amount of Oxalic Acid Adsorbed Per Gram of Charcoal (x/m) versus Concentration of Oxalic Acid (c)
0.18
0.16
f(x) = 3.4x - 0
R = 1
0.14
0.12
0.1
0.06
0.04
0.02
0
c (M)
Log x/m
-2
-1.8
Log c
-1.6
-1.4
0
-1.2
-0.2
-0.4
-0.6
-0.8
-1
-1.2
-1.4
-1.6
-1.8
-2