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ethane / propane mixture

82.06
1.9872

MW Ethane
Tc
Pc

30.07
305.5
48.2

K
atm

a=
b=

97495552
45.0936

MW Propane
Tc
Pc

44.09
370
42

K
atm

a=
b=

180617084
62.6763

T
P
344.6333 27.21661799

ethane
T0
propane
T0
Mixture
T0

T ( R)
P (bar)
T (K)
P (atm)

R
Rgas

h cal/g-mol
0.0000

150

Cv

200

344.63
ethane
propane
sum

cm3atm/(mol-K)

Cv

yi/xi
0.0170
0.9830
1

Cv

h cal/g-mol
-2037.8434

h total
-2037.8434
-83.6484
-3668.0888

Cv_a_E

Cv_b_E

Cv_c_E

Cv_d_E

-0.3392

0.04124

-0.0000153

1.74E-009

Cv_a_P

Cv_b_P

Cv_c_P

Cv_d_P

-2.9532

0.07279

-0.00003755

7.58E-009

Cv_a
Cv_b
Cv_c
Cv_d
-2.9086888 0.072252767 -3.71711E-005 7.481E-009

620.34
27.579
344.6333
27.21662

RK-EOS

iterate to find v
v (cm3/gmol) 135.429261

20.214 lb/ft3

eq (8-11)
6.3459E-007
Fugacity coefficient term by term

Fugacity coefficient calculations

cal/g-mol
Btu/lb
Btu/lb-mol

Bubble-point calculations

a_E
RK-EOS

97495552
a_P

RK-EOS

Ethane
Propane

180617084

Ethane
Propane

h0

b_E
45.0936

s0

4067.66881 5.5412019
h0

b_P
62.6763

2.65492697 -0.62870043
2.65492697 -0.8738402

Ethane
Propane

s0

4576.62465 2.9448348
Ethane
Propane

RK-EOS

a
178988914

b
62.3769

MW
43.8513

Fugacity Coefficient

cient term by term


Sum
-1.5594583 0.466768 1.594832
-2.07941777 -0.298331 0.742056

Fugacity Liquid
0.739116 atm
19.85234 atm

yi with i = 1
0.027157
Sum 1

0.72942
0.756577
yi estimates
0.035894
0.964106

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