Determine the maximum available liquid products and heating value (gross) from a gas of composition given belo

NOTE: When heptanes plus concentration is this low, the molecular weight and specific gravity cannot be measu
Qg [MMSCFD]
330

COMPONENTS
CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+
TOTAL

GAS COMPOSITION
COMPOSITION, (mole fraction)
0.0167
0.0032
0.7102
0.1574
0.0751
0.0089
0.0194
0.0034
0.0027
0.0027
0.0003
1.0000

GPM j 0, 3151

Column A Table Props. GP

Chap. 23

yjM j
gal
oj MMScf

COMPONENT
CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+

GPM CALCULATION
Mj [lb/lbmol]
44.0100
28.0135
16.0420
30.0690
44.0960
58.1220
58.1220
72.1490
72.1490
86.1750
103.0000

Yj
0.0167
0.0032
0.7102
0.1574
0.0751
0.0089
0.0194
0.0034
0.0027
0.0027
0.0003
1.0000
MW GAS [lb/lbmol]
SG GAS [adim]
GPM GAS [gal/MMscf]

Lcideal
z 1

y j 1 z j

22.611
0.780
7.484

y j Lcj

Lcreal

Lcideal
Z

z 1

y j 1 z j

COMPONENT

Yj

CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+

0.0167
0.0032
0.7102
0.1574
0.0751
0.0089
0.0194
0.0034
0.0027
0.0027
0.0003
1.0000

Lcreal

Z real gas [adim]

Lc real gas [BTU/scf] GROSS

Lcideal
Z

HEATING VALUE CALCULATION

Lcj [BTU/scf]
GROSS
0.0
0.0
1010.0
1769.7
2516.2
3252.0
3262.4
4000.9
4008.7
4756.0
5502.5

0.9958
1321.4830

a gas of composition given below.

specific gravity cannot be measured. Use 103 lb/lbmol and 0,7

Column A Table Props. GPSA

Chap. 23

Column E Table Props. GPSA Ch

23

CULATION
YjMj [lb/lbmol]
0.7350
0.0896
11.3930
4.7329
3.3116
0.5173
1.1276
0.2453
0.1948
0.2327
0.0309
22.6106

SG LIQUID [adim]

GPMj

0.3564
0.5074
0.5630
0.5841
0.6246
0.6311
0.6640
0.7000

4.1841
2.0566
0.2895
0.6083
0.1238
0.0973
0.1104
0.0139
7.4838

E CALCULATION
YjLcj
0.0000
0.0000
717.3020
278.5508
188.9666
28.9428
63.2906
13.6031
10.8235
12.8412
1.6508
1315.9713

Column K. Table Props.

GPSA Chap. 23 Zj

0.9943
0.9997
0.9980
0.9919
0.9825
0.9711
0.9667
0.9480
0.9420
0.9100
0.8520

y j 1 z j
1.26E-03
5.54E-05
3.18E-02
1.42E-02
9.93E-03
1.51E-03
3.54E-03
7.75E-04
6.50E-04
8.10E-04
1.15E-04
0.0646

Determine available liquid products, heating value (gross) and shrinkage from a gas of composition given below.
NOTE: When heptanes plus concentration is this low, the molecular weight and specific gravity cannot be measured
Qg [MMSCFD]
330

COMPONENTS
CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+
TOTAL

GAS COMPOSITION
COMPOSITION, (mole fraction)
0.0167
0.0032
0.7102
0.1574
0.0751
0.0089
0.0194
0.0034
0.0027
0.0027
0.0003
1.0000

Complete recovery of these products is not feasible. Recovery efficiencies in a relative simple plant are below.
COMPONENT
C2
C3
i-C4
n-C4
C5+

RECOVERY EFF [%]

5-25
80-90
95
100
100

GPM j 0, 3151

COMPONENT
CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6

yjM j

oj
Yj
0.0167
0.0032
0.7102
0.1574
0.0751
0.0089
0.0194
0.0034
0.0027
0.0027

gal
MMScf

C7+

0.0003
1.0000

MW GAS [lb/lbmol]
SG GAS [adim]
GPM GAS [gal/MMscf]

Lcideal
z 1

y j 1 z j

y j Lcj

Lcreal

Lcideal
Z

HE
WITHOUT LIQUID RECOVERY
COMPONENT

Yj

CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+

0.0167
0.0032
0.7102
0.1574
0.0751
0.0089
0.0194
0.0034
0.0027
0.0027
0.0003
1.0000

Z real gas [adim]

Lc real gas [BTU/scf] GROSS

Shrinkage (Qgi * HHVi ) (Qgf * HHV f )

Qg [MMSCFD]
HHV [BTU/scf]
SHRINKAGE [BTU/d]

) and shrinkage from a gas of composition given below.

molecular weight and specific gravity cannot be measured. Use 103 lb/lbmol and 0,7

very efficiencies in a relative simple plant are below.

gal
MScf

RECOVERY EFF [%] SELECT

25
90
95
100
100
Column A Table Props. GPSA
Chap. 23

Mj [lb/lbmol]
44.0100
28.0135
16.0420
30.0690
44.0960
58.1220
58.1220
72.1490
72.1490
86.1750

Column E Table Props.

GPSA Chap. 23

GPM CALCULATION
YjMj [lb/lbmol]
0.7350
0.0896
11.3930
4.7329
3.3116
0.5173
1.1276
0.2453
0.1948
0.2327

103.0000

0.0309
22.6106

WITHOUT LIQUID RECOVERY

22.611
0.780
7.484

WITH LIQUID RECOVERY

18.834
0.649
4.126

y j Lcj

creal

L
cideal
Z

Column K. Table Props.

GPSA Chap. 23

HEATING VALUE CALCULATION

WITHOUT LIQUID RECOVERY
Lcj [BTU/scf]
YjLcj
GROSS
0.0
0.0000
0.0
0.0000
1010.0
717.3020
1769.7
278.5508
2516.2
188.9666
3252.0
28.9428
3262.4
63.2906
4000.9
13.6031
4008.7
10.8235
4756.0
12.8412
5502.5
1.6508
1315.9713
WITHOUT LIQUID RECOVERY
0.9958
1321.4830

(Qgf * HHV f )

Qgf

WITH LIQUID RECOVERY

0.9973
1108.6896

Qgi nmol f

WITHOUT LIQUID RECOVERY

330.0000
1321.4830
122868.3327

100
WITH LIQUID RECOVERY
282.5147
1108.6896

GPMj real= GPMj ideal*Recovery

Eff (fraction)

Assume Calculation Base:

100 mol

LCULATION
SG LIQUID [adim]

GPMj IDEAL

GPMj REAL

0.3564
0.5074
0.5630
0.5841
0.6246
0.6311
0.6640

4.1841
2.0566
0.2895
0.6083
0.1238
0.0973
0.1104

1.0460
1.8510
0.2751
0.6083
0.1238
0.0973
0.1104

RESIDUE [mol]
1.6700
0.3200
71.0200
11.8050
0.7510
0.0445
0.0000
0.0000
0.0000
0.0000

Yj RESIDUE
0.0195
0.0037
0.8296
0.1379
0.0088
0.0005
0.0000
0.0000
0.0000
0.0000

0.7000

0.0139
7.4838

0.0139
4.1257

0.0000
85.6105

0.0000
1.0000

Compressibility Gas Factor @STD

Conditions

ON
WITH LIQUID RECOVERY
Zj
0.9943
0.9997
0.9980
0.9919
0.9825
0.9711
0.9667
0.9480
0.9420
0.9100
0.8520

y j 1 z j
1.26E-03
5.54E-05
3.18E-02
1.42E-02
9.93E-03
1.51E-03
3.54E-03
7.75E-04
6.50E-04
8.10E-04
1.15E-04
0.0646

Yj RESIDUE

YjLcj

0.0195
0.0037
0.8296
0.1379
0.0088
0.0005
0.0000
0.0000
0.0000
0.0000
0.0000
1.0000

0.0000
0.0000
837.8669
244.0274
22.0728
1.6904
0.0000
0.0000
0.0000
0.0000
0.0000
1105.6575

y j 1 z j
1.47E-03
6.47E-05
3.71E-02
1.24E-02
1.16E-03
8.84E-05
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.0523

YjMj RESIDUE [lb/lbmol]

0.8585
0.1047
13.3080
4.1463
0.3868
0.0302
0.0000
0.0000
0.0000
0.0000

0.0000
18.8345

Find the GPM of the gas mixture with composition showed below. Find the HHV of the feed gas and the HHV of the
What is the shrinkage value of the gas?
Qg [MMSCFD]
330

COMPONENTS
CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+
TOTAL

GAS COMPOSITION
COMPOSITION, (mole fraction)
0.0300
0.0100
0.8500
0.0580
0.0300
0.0070
0.0080
0.0030
0.0020
0.0020
0.0000
1.0000

Complete recovery of these products is not feasible. Recovery efficiencies in a relative simple plant are below.
COMPONENT
C2
C3
i-C4
n-C4
C5+

RECOVERY EFF [%]

80-90
90-98
90-100
90-100
100

GPM j 0, 3151

COMPONENT
CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6

yjM j

oj
Yj
0.0300
0.0100
0.8500
0.058
0.03
0.007
0.008
0.003
0.002
0.002

gal
MMScf

C7+

0
1.0000

MW GAS [lb/lbmol]
SG GAS [adim]
GPM GAS [gal/MMscf]

Lcideal
z 1

y j 1 z j

y j Lcj

Lcreal

Lcideal
Z

HEA
WITHOUT LIQUID RECOVERY
COMPONENT

Yj

CO2
N2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+

0.0300
0.0100
0.8500
0.0580
0.0300
0.0070
0.0080
0.0030
0.0020
0.0020
0.0000
1.0000

Z real gas [adim]

Lc real gas [BTU/scf] GROSS

Shrinkage (Qgi * HHVi ) (Qgf * HHV f )

Qg [MMSCFD]
HHV [BTU/scf]
SHRINKAGE [BTU/d]

elow. Find the HHV of the feed gas and the HHV of the residue gas.

OSITION
COMPOSITION, (mol)
3
1
85
5.8
3
0.7
0.8
0.3
0.2
0.2
0
100.0000

ry efficiencies in a relative simple plant are below.

gal
MScf

RECOVERY EFF [%] SELECT

90
98
99
99
100
Column A Table Props. GPSA
Chap. 23

Mj [lb/lbmol]
44.0100
28.0135
16.0420
30.0690
44.0960
58.1220
58.1220
72.1490
72.1490
86.1750

GPM CALCULATION
YjMj [lb/lbmol]
1.3203
0.2801
13.6357
1.7440
1.3229
0.4069
0.4650
0.2164
0.1443
0.1724

103.0000

0.0000
19.7079

WITHOUT LIQUID RECOVERY

19.708
0.680
3.105

WITH LIQUID RECOVERY

17.228
0.594
2.930

y j Lcj

creal

Column K. Table Props.

GPSA Chap. 23

Lcideal
Z
HEATING VALUE CALCULATION
WITHOUT LIQUID RECOVERY
Lcj [BTU/scf]
YjLcj
GROSS
0.0
0.0000
0.0
0.0000
1010.0
858.5000
1769.7
102.6426
2516.2
75.4860
3252.0
22.7640
3262.4
26.0992
4000.9
12.0027
4008.7
8.0174
4756.0
9.5120
5502.5
0.0000
1115.0239
WITHOUT LIQUID RECOVERY
0.9971
1118.2916

(Qgf * HHV f )

Qgf

WITH LIQUID RECOVERY

0.9979
973.2804

Qgi nmol f

WITHOUT LIQUID RECOVERY

330.0000
1118.2916
81080.0162

100
WITH LIQUID RECOVERY
295.8615
973.2804

Column E Table Props. GPSA

Chap. 23

GPMj real= GPMj

ideal*Recovery Eff (fraction)

Assume Calculation Base:

100 mol

LCULATION
SG LIQUID [adim]

GPMj IDEAL

GPMj REAL

0.3564
0.5074
0.5630
0.5841
0.6246
0.6311
0.6640

1.5418
0.8216
0.2277
0.2508
0.1092
0.0720
0.0818

1.3876
0.8051
0.2255
0.2483
0.1092
0.0720
0.0818

RESIDUE [mol]
3.0000
1.0000
85.0000
0.5800
0.0600
0.0070
0.0080
0.0000
0.0000
0.0000

Yj RESIDUE
0.0335
0.0112
0.9481
0.0065
0.0007
0.0001
0.0001
0.0000
0.0000
0.0000

0.7000

0.0000
3.1049

0.0000
2.9295

Column K. Table Props.

GPSA Chap. 23

0.0000
89.6550

0.0000
1.0000

Compressibility Gas Factor

@STD Conditions

N
WITH LIQUID RECOVERY
Zj
0.9943
0.9997
0.9980
0.9919
0.9825
0.9711
0.9667
0.9480
0.9420
0.9100
0.8520

y j 1 z j

2.26E-03
1.73E-04
3.80E-02
5.22E-03
3.97E-03
1.19E-03
1.46E-03
6.84E-04
4.82E-04
6.00E-04
0.00E+00
0.0541

Yj RESIDUE

YjLcj

0.0335
0.0112
0.9481
0.0065
0.0007
0.0001
0.0001
0.0000
0.0000
0.0000
0.0000
1.0000

0.0000
0.0000
957.5595
11.4486
1.6839
0.2539
0.2911
0.0000
0.0000
0.0000
0.0000
971.2371

y j 1 z j

2.53E-03
1.93E-04
4.24E-02
5.82E-04
8.85E-05
1.33E-05
1.63E-05
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.0458

YjMj RESIDUE [lb/lbmol]

1.4726
0.3125
15.2091
0.1945
0.0295
0.0045
0.0052
0.0000
0.0000
0.0000

Factor

0.0000
17.2279