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Charisma Global Networks Limited

CGNL : MTS 002


June 2003

Materials of Construction
125
100

Cracking
Area

150

50

Cracking Reported
Above Curve

100

25

50
0

20
10
30
40
50
Sodium Hydroxide, wt. %

F
600
500

300

Corrosion Rates for Alloy 200


& Alloy 201

250

5 mpy

400

200

Boiling Point Curve


1 mpy

300

150

0.1 mpy

200

0.1 mpy

100

Melting Point
Curve

< 0.1 mpy

20

40

60

80

Sodium Hydroxide, wt. %

100
50

0
100

Corrosion Rates for Nickel Alloy 200 & Low Carbon


Nickel Alloy 201 in Sodium Hydroxide

Date: 28.06.2003

1-50
mpy

200

100

< 1 mpy

250

>30 mpy
150
30 mpy
1-30 mpy
1 mpy

200

60

300

100

Relation of Temperature & Concentration of Sodium


Hydroxide to cause Stress Corrosion Cracking of Carbon Steel

Temperature

400

75

Danger Zone

Apparent Stress Corrosion


Cracking Boundary
Atmospheric boiling
point curve >30 mpy

Melting
Point Curve

50
0

20
40
60
80
Sodium Hydroxide, wt. %

Isocorrosion chart for AISI 304 & 316 S.S. Steels in Sodium
Hydroxide, with stress cracking boundary superimposed

100

mpy
No Chlorates

mm/yr
Sodium Chlorates

50

0.05
0.025

2
1

0.5
0.2
0.1

2.5

0.5
0.25

20
10

Corrosion Rate

Temperature

200

500

200
904L
825
600

Severe Cracking

250

300

200
904L
825
600

Boiling Point Curve

F
600

C
150

Temperature

F
300

0.005
0.0025

Sodium Hydroxide, 50 wt. %, 300 F (150 C)

Typical comparative corrosion rates for several alloys in


sodium hydroxide in the presence of sodium chlorates

Drawn by: Arun S.

Checked by: N.K.Roy

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