MSE 201: Thermodynamics and Phase Equilibria Quiz 1 Date: 16/08/2014 Time: 6:15pm to 7:15pm Role Number: Name: Qt | @ [Ast a4 [Qs [Q6 | Q7 | Total {100} R=8.314 Jimol-K Q.1 State True or False (Write full word only, do NOT write F/T) {10} No. _| Statement True/False_ 1. | For an irreversible cycle fa 0 Fils. 2. _ | Ina closed system, solidification of iron below its melting = point causes a decrease in the entropy of the iron True 3. | If an ideal gas expands against vacuum by 3cc, the total work done by the gas is zero The 4. [A reversible adiabatic process can also be called as isentropic process (i.e. no change in entropy during the Tue process) | 5. | Heat absorbed by a system during a reversible isobaric | Tue process is equal to the change in enthalpy of the system ial Q.2 (a) Draw a reversible Carnot cycle, which delivers some net work w. 5 (b) Indicate the work w on the diagram. a P ‘ 5 vy J92= Revesible itothermal Enparsion 2935 Pevensible adiubare expansion 324 Revenible ivotherimal Campretion Gl Reesible adiababic Comprestion ) We ana (s2341) Page 1 of 5Q. 3 Show by contradiction that the efficiency of a reversible Carnot cycle depends only on the temperatures of the two thermal reservoirs between which it operates 110) Lets agume, for the prot, that effideny of a pee BE _ Cannot ye. depends on other fades fro then temperahures (1X72) That means, we may have two Carnot yer operttiny henwear Same two thermal repenvaivs (Ty & 7) & haviey ditkrent efhundg, nN EN! Lee orune VON. 5 direch Now, ber's operale nl! in drwak Amin ret een Qe-& h Thy, Cumbined device a heat (QO) frm g them tiem & pects On equivalent amoun) of we without other effet. nd ( & wewr @-e This vislaes tHe & aw of HhumodynaiS Try wt cannot have Ni>omr- We wan Sienil pve thet we They, 1b: . . Efficienuy it dyed on he femperaiunes of He TwO cannot haw. U J>c>2 JOC = Peversible wobaric headin to Ie 2 Tee Tye 500k , foe Iber, 1000 KB. 4A SLO _ Glee m = Eee v Me Trios Mies [& 2 nglo(Ix) = irok 4295)2 10 (Soe) DSiac = 148645 TIF = 250K C32 = Pewnible vorbermal compres duc Sp Swe0 > SL= PAN > AScan= me Ni AScr az lowend3y Rn (EE) - 592.9 ~* DSi22=ASiae + Mco2= 909 TEQ7. A 100g alloy containing 50%Cu-40%Zn-10%Ni by weight has two phases viz. a and B, the weights of which are 80g and 20g respectively. The a -phase is the solid solution of Cu, Ni and Zn whereas f-phase consists of pure 3$y- Calculate the composition of the two phases in weight% as weil as in atom%, The atomic weights, of CU, Ni and Zn are 63.5, 58.6 and 65.4 respectively. {10} > phase. consists of pure 2n & itt weyhr is Bg: phase contisht of all of La, Ni & remoiniey ” : iid stg (a, 4oy 2 Ib) over) , The alley corral & In) Ni K cootairs Sty Gy Ayer Computition of % 19 ae fa So = 00605 or 62,5 wtih 20 9.25 or est a Con = Bo a Jo _ 4, oy 12.9 wt? A wth is & Composrion of p O YY oy will of 400 atern‘he} che wate Anew —=——— , 7 Compusition of &K in atom Je xX _fetles —_. 022. . ¢p.31 atom) 5 t ist a ~~ aq. a5 a es 579B Labi m7 Xan = ie = 13.5 atime Pare sors