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Types of Bonds

Seitz in 1940 classified solids into five types according to the bonding
of atoms, which has become a generally adapted classification

The atoms of different types come closer and join together during chemical reaction
and usually these
bonds are referred to as chemical bonds. There are basically two groups which
classify common bonds on the basis of strength, directionality of bonding forces,
cohesive forces (chemical bonds) and the character of any solid material: These are
(i) Primary Bonds: These are inter-atomic bonds in which electrostatic
force holds the atoms together. Relatively large atomic forces develop in
these bonds, making them more stable and imparting high strength. They
have bond strength varying from 1-1.5 eV. these bonds are also known as attractive
bonds. The inter-atomic distance is usually 1-2r. Following three types of primary
bonds are found in different materials
(i) Ionic or electrostatic bonds
(ii) Covalent, atomic or homopolar bonds
(iii) Metallic bonds.
The principal types of bonding is shown

ii) Secondary Bonds: A secondary bond is an intermolecular bond and weaker and
less stable than primary bond. In this type of bonds, the forces hold the
molecules together. These secondary bonds result from intermolecular or
dipole attractions. Asymmetrical electron distribution in molecules and
atoms creates dipoles. Due to dipoles the molecules are attracted
towards other molecules having opposite dipoles. Similar asymmetric electron
distribution in atoms causes dipole to exist in them. We must note that the atomic
dipolar bonds are weaker than molecular dipole bonds and moreover atomic dipolar
bonds keep on fluctuating as electron distribution in atomic outer shells keeps
changing. Common examples of secondary bonds are Vander Waals bonds and
hydrogen bonds.

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