Table C8-8 Estimation of Polar HSP by the Stefanis Panayiotou Group Contribution Method

Name

REF

SP

Group
1

No.

Group
2

Group
3

No.

1,4-Butane Diol

11.0

8.47

LCH2L

LOH

Benzyl Alcohol

6.3

7.16

AcH

AcCH2L

LOH

Diisobutyl Ketone

3.7

5.54

CH3L

LCH2L

LCH<

Ethyl Formate

8.4

7.36

CH3L

Ethylene Glycol
Monoethyl Ether

7.2

9.04

CH3L

LCH2L

HCOOL

1.6444  1

0.3877  1

1.7056  1

LCH2L

LOCH2CH2OL

1.6444  1

0.3877  1

3.3880  1

Ethylene Glycol
Monomethyl Ether
Acetate

5.5

6.38

LCH2L

CH3COOL

CH3OL

0.3877  2

0.6075  1

0.0089  1

Ethylene Glycol
Monomethyl Ether

7.2

9.04

CH3L

LOCH2CH2OL

1.6444  1

3.3880  1

Ethylene Glycol Mono

Isopropyl Ether

8.2

8.31

CH3L

LCH<

1.6444  2

0.6051  1

Ethylene Glycol

11.0

9.10

LCH2L

LOH

0.3877  2

1.0587  2

Hexylene Glycol

8.4

7.84

LCH2L

LOH

0.3877  6

1.0587  2

Isobutyl Acetate

3.7

4.00

CH3L

LCH2L

1.6444  2

0.3877  1

No.

LOCH2CH2OL

Group
4

LCH2COL

No.

Group
5

No.

LCH<

CH3COOL

Contri 1

Contri 2

Contri 3

0.3877  4

1.0587  2

0.5771  4

0.8019  1

1.0587  1

1.6444  3

0.3877  1

0.6051  2

Contri 4

Contri
5

3.6103  1

3.3880  1

0.6051  1 0.6075  1

Isopropyl Acetate

4.5

4.32

CH3L

LCH<

CH3COOL

1.6444  2

0.6051  1

0.6075  1

Methyl Isobutyl
Carbinol

3.3

4.63

CH3L

LCH2L

LCH<

LOH

1.6444  3

0.3877  1

0.6051  2

1.0587  1

Methyl Isobutyl Ketone

6.1

4.62

CH3L

LCH2L

LCH<

CH3OL

1.6444  2

0.3877  1

0.6051  1

0.0089  1

Methyl Isoamyl Ketone

5.7

4.81

CH3L

LCH2L

LCH<

CH3COL

1.6444  3

0.3877  2

0.6051  1

2.1567  1

Methyl Amyl Ketone

5.7

6.87

CH3L

LCH2L

CH3COL

1.6444  1

0.3877  4

2.1567  1

Methyl Propyl Ketone

7.6

7.49

CH3L

LCH2L

CH3COL

1.6444  1

0.3877  2

2.1567  1

n-Propyl Bromide

7.9

5.86

CH3L

LCH2L

LBr

1.6444  1

0.3877  2

0.5207  1
0.6075  1

n-Propyl Acetate

4.3

4.73

CH3L

LCH2L

CH3COOL

1.6444  1

0.3877  2

Propylene Glycol
Methyl Ether Acetate

5.6

5.66

CH3L

LCH2L

LCH<

CH3COOL

CH3OL

1.6444  1

0.3877  1

0.6051  1 0.6075  1 0.0089

1

Propylene Glycol
Monomethyl Ether

6.3

7.32

CH3L

LCH2L

LCH<

LOH

CH3OL

1.6444  1

0.3877  1

0.6051  1

Tetrahydrofuran

5.7

7.69

LCH2L

LCH2OL
(CYCLIC)

0.3877  2

0.1227  1

Cyclohexane

1.93

LCH2L

Toluene

1.4

1.33

AcH

0.1371  6
AcCH3

0.1930  5

0.4493  1

1.0587  1 0.0089
1