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By:
Animesh Jain
10BPE083
Harsh Shah
10BPE115
Kuldip Patel
10BPE206
Neema Agarwal
10BPE072
Pradeepika Chanana
10BPE197
Prashant Thawrani
10BPE234
Reila Chakraborty
10BPE009
Shamit Rathi
10BPE066
Ujjwal Kumar
10BPE103
Acknowledgements
The work of our B.Tech project titled Innovation in EOR Techniques in Cambay Region has
been a persistent endeavour from a lot of people and so we would like to thank all of them
for their support and guidance throughout the session.
First of all, we would like to thank Dr. Bijay K Behera, internal mentor of the project, who
guided the group throughout the project work and helped with the relevant data required
for the project. His guidance helped us to carry out the work smoothly and efficiently.
We also wish to thank Mr. R.K. Vij, GM-ONGC, external mentor for the project, for providing
us with technical assistance and valuable insights into the concepts of EOR.
Thanking all,
Animesh Jain
10BPE083
Harsh Shah
10BPE115
Kuldip Patel
10BPE206
Neema Agarwal
10BPE072
Pradeepika Chanana
10BPE197
Prashant Thawrani
10BPE234
Reila Chakraborty
10BPE009
Shamit Rathi
10BPE066
Ujjwal Kumar
10BPE103
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Table of Contents
Introduction ........................................................................................................................ 6
Oil Recovery ........................................................................................................................ 7
Primary recovery ......................................................................................................... 7
Secondary recovery ..................................................................................................... 7
Tertiary recovery (EOR) ............................................................................................... 7
IOR vs. EOR .................................................................................................................. 8
Enhanced Oil Recovery Techniques.................................................................................... 9
Gas Injection ................................................................................................................ 9
Miscible Gas Injection .......................................................................................... 9
Immiscible Gas Injection ...................................................................................... 9
Chemical Flooding ..................................................................................................... 10
Alkaline Flooding Wettability Alteration......................................................... 10
Micellar/Polymer Flooding ................................................................................ 12
Alkali, Surfactant, Polymer Flooding .................................................................. 13
Thermal Recovery Processes ..................................................................................... 14
Cyclic Steam Injection (Steam Stimulation, Steam Soak or Huff and Puff): ...... 14
Steam Flooding (Steam drive, Continuous Steam Injection): ............................ 15
In-Situ Combustion (Fire-flood): ........................................................................ 16
Microbial Enhanced Oil Recovery ............................................................................. 17
Huff and Puff Method ........................................................................................ 18
Microbial Flooding ............................................................................................. 19
Economics of the MEOR stimulation: ................................................................ 19
Advantages of MEOR: ........................................................................................ 19
Disadvantages of MEOR:.................................................................................... 19
Screening criteria .............................................................................................................. 20
Geology of the Cambay Basin ........................................................................................... 22
Geographic Location of the basin ............................................................................. 22
Tectonic history ......................................................................................................... 22
Evolution of Basin ...................................................................................................... 23
Generalized Stratigraphy........................................................................................... 24
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List of Figures
FIGURE 1 OIL RECOVERY CLASSIFICATIONS (LAKE, 1989) ......................................................................... 7
FIGURE 2 EFFECT OF FLOOD WATER SALINITY ON RECOVERY OF SYNTHETIC ACIDIC OIL BY ALKALINE
WATERFLOODING (C.E.COOKE, 1974)........................................................................................ 11
FIGURE 3 SCHEMATIC ILLUSTRATION OF POLYMER FLOODING SEQUENCE (DRAWING BY JOE LINDLEY, U.S.
DEPARTMENT OF ENERGY, BARTLESVILLE, OKLA.) (LAKE, 1989) ...................................................... 12
FIGURE 4 RESIDUAL OIL UNDER SEM (POLYMER FLOODING AND ASP FLOODING IN DAQING OILFIELD) ......... 13
FIGURE 5 STEAM INJECTION PROCESS (NIPER, OKLAHOMA) .................................................................. 14
FIGURE 6 STEAM FLOOD DISPLACING OIL FROM RESERVOIR (E&P MAGAZINE, AUG 29, 2007) .................... 15
FIGURE 7 IN-SITU COMBUSTION PROCESS (NIPER, OKLAHOMA) ............................................................ 16
FIGURE 8 HUFF AND PUFF METHOD (M. M. SCHUMCHER, 1980): .................................................... 18
FIGURE 9 MICROBIAL FLOODING (M. M. SCHUMCHER, 1980) .......................................................... 19
FIGURE 10 GEOGRAPHY OF THE CAMBAY BASIN (DGH) .......................................................................... 22
FIGURE 11 SCHEMATIC OF TECTONIC BLOCKS OF CAMBAY RIFT BASIN SEPERATED BY TRANSFER FAULTS (MADAN
MOHAN, 1995) ..................................................................................................................... 22
FIGURE 12 GEOLOGICAL CROSS SECTION ALONG CAMBAY RIFT BASIN (MADAN MOHAN, 1995) .................. 23
FIGURE 13 GENERALIZED STRATIGRAPHY OF THE CAMBAY BASIN ............................................................ 25
FIGURE 14 TOTAL ORGANIC CARBON (TOC) CONTOUR IN CAMBAY SHALE ............................................... 27
FIGURE 15 BALOL AND SANTHAL FIELDS IN CAMBAY BASIN (G.K PANCHANAN, 2006) ............................... 29
FIGURE 16 CROSS PLOT OF AIR RATE & OIL PRODUCTION RATE IN PHASE I (HAR SHARAD DAYAL ET.AL, 2010)31
FIGURE 17 CROSS PLOT OF AIR RATE & OIL PRODUCTION RATE IN PHASE II (HAR SHARAD DAYAL
ET.AL, 2010). ...................................................................................................................... 31
FIGURE 18 TECTONIC MAP OF CAMBAY BASIN (DEBASHIS ET AL., 2008).................................................. 33
FIGURE 19 SCHEMATIC MAP OF JHALORA ASP PILOT AREA (JAIN, DHAWAN, & MISHRA, 2012) ................. 35
FIGURE 20 COMBINED PERFORMANCE OF SIX JHALORA ASP PILOT PRODUCERS (JAIN, DHAWAN, & MISHRA,
2012).................................................................................................................................. 36
FIGURE 21 LOCATION MAP OF SANAND FIELD (CHANCHAL DASS, 2008). ............................................... 37
FIGURE 22 PILOT WELLS AND EXPANDED PILOT PHASE WELLS (MAHENDRA PRATAP, 1997)........................ 38
FIGURE 23 WELLS IN COMMERCIALISATION AREA (MAHENDRA PRATAP, 1997). ...................................... 38
FIGURE 24 PERFORMANCE OF EXPANDED POLYMER PILOT (MAHENDRA PRATAP, 1997)............................ 39
FIGURE 25 PERFORMANCE OF SANAND POLYMER FLOOD PROJECT (CHANCHAL DASS, 2008). .................... 40
FIGURE 26 ASP PILOT LOCATION IN VIRAJ FIELD ................................................................................. 41
FIGURE 27 JJ TABER EOR SCREENING CRITERIA .................................................................................. 51
List Of Tables
TABLE 1 BIO-PRODUCTS AND THEIR APPLICATIONS TO ENHANCED OIL RECOVERY (JANSHEKAR, 1985): .......... 17
TABLE 2 RESERVOIR PARAMETERS OF JHALORA K-IV SAND (JAIN, DHAWAN, & MISHRA, 2012) ................... 34
TABLE 3 RESERVOIR DESCRIPTION OF VIRAJ FIELD:............................................................................... 42
TABLE 4 CRUDE OIL PROPERTIES IN VIRAJ: ......................................................................................... 42
TABLE 5 CHARACTERISTICS OF SURFACTANT USED IN VIRAJ: ................................................................... 42
TABLE 6 PARAMETERS MONITORED DURING IMPLEMENTATION: ............................................................ 43
Innovation in EOR techniques
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Introduction
In todays time, Enhanced Oil Recovery (EOR) has become one of the sought after research
arenas in the oil and gas industry. The industry average of 35% recovery efficiency for
conventional crude oil results in a large amount of identified oil left behind, despite existing
production infrastructure. Many EOR techniques are already in practice around the world
but the global energy demands are ever-increasing. This propels innovations in the existing
EOR schemes as even a meagre increase in production of oil is highly valued in the industry.
This project deals with developing an economically feasible innovation in any existing EOR
scheme for the petroliferous basin in Gujarat i.e. the Cambay Basin. The focus is on major
fields in the Cambay Basin, namely Balol & Santhal, Viraj, Sanand & Jhalora. This report
entails a detailed study of the fields and the current EOR schemes in use. An innovation in
EOR technique can only be designed with proper background knowledge of the ongoing
process and its limitations.
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Oil Recovery
There are three phases of recovering as below and in figure 1:
Primary recovery
Primary Recovery Mechanism occurs when wells produce because of natural energy from
expansion of gas and water within the producing formation, which pushes fluids into the
well bore and lifts them to the surface.
Secondary recovery
It occurs as artificial energy is applied to inject fluids into the well bore and lift fluids to the
well bore. This may be accomplished by injecting gas down a hole, installing a subsurface
pump, or injecting gas or water into the formation itself. Secondary recovery is done when
well, reservoir, facility, and economic conditions permit.
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Chemical Flooding
Chemical enhanced oil recovery (EOR) includes processes in which chemicals are injected to
improve oil recovery. The primary goal is to recover more oil or to improve the sweep
efficiency of the injected fluid by either one or a combination of the following processes:
(1) Mobility control by adding polymers to reduce the mobility of the injected water, and
(2) Interfacial tension (IFT) reduction by using surfactants, and/or alkalis.
Chemical EOR faces significant challenges, especially in light oil reservoirs. One of the
reasons is the availability, or lack of, compatible chemicals in high temperature and high
salinity environments.
There are three general methods in chemical flooding technology.
Alkaline Flooding
Micellar/Polymer Flooding
Alkali, Surfactant, Polymer(ASP) Flooding
The compatibility of a given alkali is of utmost importance. The reaction of the alkali with the
high molecular weight acids is required for altering the wettability. Acidic gases, such as H2S
and CO2, are tolerable only at lower concentrations, because their reaction products (Na 2S
and Na2CO3) with excess NaOH may still be sufficiently alkaline. Bivalent ions present in
Page | 10
F IGURE 2 EFFECT OF FLOOD WATER SALINITY ON RECOVERY OF SYNTHETIC ACIDIC OIL BY ALKALINE WATERFLOODING
(C.E.C OOKE , 1974)
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Micellar/Polymer Flooding
Micellar-polymer flooding is based on the injection of a chemical mixture that contains the
following components: water, surfactant, co-surfactant (which may be an alcohol or another
surfactant), electrolytes (salts), and possible a hydrocarbon (oil). Micellar-polymer flooding is
also known as Micellar, micro emulsion, surfactant, low-tension, soluble-oil, and chemical
flooding. The differences are in the chemical composition and the volume of the primary
slug injected. For instance, for a high surfactant concentration system, the size of the slug is
often 5%-15% pore volumes (PV), and for low surfactant concentrations, the slug size ranges
from 15%-50% PV. The surfactant slug is followed by polymer-thickened water. The
concentration of polymer ranges from 500 mg/L to 2,000 mg/L. The volume of the polymer
solution injected may be 50% PV, depending on the process design. Some of the main
surfactant requirements for a successful displacement process are as follows:
The injected surfactant slug must achieve ultralow IFT (IFT in the range of 0.001 to 0.01
mN/m) to mobilize residual oil and create an oil bank where both oil and water flows as
continuous phases.
It must maintain ultralow IFT at the moving displacement front to prevent mobilized oil from
being trapped by capillary forces.
Long-term surfactant stability at reservoir conditions (temperature, brine salinity and
hardness). (Romero-Zern)
F IGURE 3 S CHEMATIC ILLUSTRATION OF POLYMER FLOODING SEQUENCE ( DRAWING BY JOE LINDLEY , U.S. DEPARTMENT OF
E NERGY , BARTLESVILLE , OKLA .) (L AKE , 1989)
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F IGURE 4 R ESIDUAL OIL UNDER SEM (P OLYMER FLOODING AND ASP FLOODING IN DAQING OILFIELD )
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Cyclic Steam Injection (Steam Stimulation, Steam Soak or Huff and Puff):
In this process, steam is injected down a producing well to heat up the area around the
well bore and increase recovery of the oil immediately adjacent to the well. After injection
of short period, the well is placed back on production. This is essentially a well bore
stimulation technique, each well responding independently. (Kok, 2008)
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F IGURE 6 STEAM FLOOD DISPLACING OIL FROM RESERVOIR (E&P MAGAZINE , AUG 29, 2007)
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Bio-product
Acids
Effects
Modification of reservoir rock
Improvement of porosity and permeability
Biomass
Gases
Desulfurization of oil
Reservoir re pressurization
Oil swelling
Viscosity reduction
Increase of permeability due to
of carbonate rocks by CO2
solubilisation
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Emulsification
Mobility control
Selective plugging
Page | 18
Microbial Flooding
Advantages of MEOR:
Easy application.
Low energy input requirement for microbes to produce MEOR agents.
More efficient than other EOR methods when applied to carbonate oil reservoirs.
Microbial activity increases with microbial growth. This is opposite to the case of
other EOR additives in time and distance.
Cellular
products
are
biodegradable
and
therefore
can
be
considered environmentally friendly.
Disadvantages of MEOR:
The oxygen deployed in aerobic MEOR can act as corrosive agent on non-resistant
topside equipment and down-hole piping
Anaerobic MEOR requires large amounts of sugar limiting its applicability in offshore
platforms due to logistical problems
Exogenous microbes require facilities for their cultivation.
Indigenous microbes need a standardized framework for evaluating microbial
activity, e.g. specialized coring and sampling techniques.
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Screening criteria
Success of a particular EOR project depends on a large number of variables that are
associated with a given oil reservoir, for instance, pressure and temperature, crude oil type
and viscosity, and the nature of the rock matrix and connate water. Not every type of EOR
process can be applied to every reservoir. The choice of which EOR method to apply to a
particular reservoir thus, becomes challenging. It is best done based on a detailed study of
each specific field. Evaluation is carried out at each stage to increase the chances of an EOR
technique achieving technical and economic success. (Terry, 2001)
The application of EOR processes are both reservoir-specific and reservoir fluid-specific. This
literally means that each EOR process must be specifically evaluated before it can be applied
to a reservoir. The evaluation process is typically extensive and may include laboratory work,
geologic and reservoir modeling, economic analyses, and in many cases field trial in the form
of a pilot test. The different selection criteria presented are meant to serve as the first-pass
screening procedures that compare the candidate reservoir with other reservoirs that have
been produced with an EOR process. They cannot replace the rigorous evaluation procedure
that each EOR process must undergo before it is actually implemented in the field.
The first step in the evaluation procedure is to gather as much data about the reservoir as
possible. The data set can be used to match with the screening criteria for various recovery
methods. These criteria are usually based on the past field successes and failures to provide
a positive match for an EOR technique.
Once the possible number of feasible EOR techniques which could be applied has been
narrowed, the next step in the procedure is laboratory analysis. Physical properties of the
fluids and combinations of fluids, including that of crude oil and formation water needs to be
studied for the chosen technique. After the field history is evaluated, updated static and
dynamic reservoir models can be developed for analyzing the EOR potential of the reservoir.
The task of screening an EOR method has become easier and more efficient because of the
increase in the no. of iterations that can be done. A number of models, correlations and
computer models are available in the market for this purpose.
Operators compare expected supply costs and project economics to the scenario when the
production is continued without any EOR technique. When a field has more than one
reservoir, each reservoir should be evaluated individually by a screening guide, and a
complete study of the reservoir should be performed. If the simulation study indicates that
the project is meeting companys technical and financial requirements, then it can be
applied to the field.
These screening criteria (attached in Appendix) are only guidelines. If a particular reservoir
crude oil application appears to be on a borderline between two different processes, it may
be necessary to consider both processes. Once the number of processes has been reduced
to one or two, a detailed economic analysis will have to be conducted.
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OF THE CAMBAY
Tectonic history
The Cambay Basin rifting took place around 65 Ma,
concomitant with the eruption of Deccan volcano
during rift-drift transition phase of the Indian plate.
The rift initiation is characterized by basin bounding
extensional fault (listric / planar normal fault)
facilitating the initial basin subsidence with the upliftment of the basin margin of rift shoulders. The
basin is divided into different tectonic blocks linked
with each other by transfer fault system (figure 11).
The five tectonic blocks in the basin are:
1.
2.
3.
4.
5.
SanchorPatan
MehsanaAhmedabad
TarapurCambay
JambusarBroach
Narmada Tapti
F IGURE 11 S CHEMATIC OF TECTONIC BLOCKS
OF C AMBAY RIFT BASIN SEPERATED BY
TRANSFER FAULTS ( MADAN MOHAN , 1995)
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Evolution of Basin
The structural evolution of the basin can be categorized in three phases:
1. Syn-rift phase
2. Post-rift phase
3. Late post-rift phase
During the syn-rift phase, the basin tends to be of asymmetric nature and it characterized by
inter basinal highs and lows (figure 12). Reactivation of oblique faults and basinal uplifts
resulted in Devla-Malpur uplift (Broah-Jambusar block), Kalol uplift, Nawagam-Dholka high
(Ahmedabad block), Sanand-Jhalora uplift (Mehsana block) and Wayad and Wansa highs in
F IGURE 12 GEOLOGICAL CROSS SECTION ALONG CAMBAY RIFT BASIN (MADAN M OHAN , 1995)
Patan block. The basin subsidence continued along the extensional faults (Mohan M, 1995).
The trappean fault activity ceases to a greater extent during post rift phase (Thermal
Subsidence stage) and the subsidence continued due to rapid crustal cooling and
sedimentary load deposited by principal fluvial systems.
Late post-rift phase is characterized by reverse separation along fault plane resulting in
structural inversion within the basin. It may be mentioned that this type of structural
readjustment within rift tectonics can be attributed to thermal contraction and isostatic
compensation of the sediments.
The Narmada geofracture was reactivated during post-Miocene time down throwing BroahJambusar block considerably. The phases of basin evolution through syn-rift, post-rift and
Page | 23
Generalized Stratigraphy
The formation of the Cambay Basin began following the extensive outpour of Deccan basalts
(Deccan Trap) during late Cretaceous covering large tracts of western and central India. The NW-SE
Dharwarian tectonic trends got rejuvenated creating a narrow rift graben extending from the
Arabian Sea south of Hazira to beyond Tharad in the north. Gradually, the rift valley expanded with
time.
During Paleocene, the basin continued to remain as a shallow depression, receiving deposition of
fanglomerate, trap conglomerate, trapwacke and claystone facies, especially, at the basin margin
under a fluvioswampy regime. The end of deposition of the Olpad Formation is marked by a
prominent unconformity. At places a gradational contact with the overlying Cambay Shale has also
been noticed.
During Early Eocene, a conspicuous and widespread transgression resulted in the deposition of a
thick, dark grey, fissile pyritiferous shale sequence, known as the Cambay Shale. This shale sequence
has been divided into Older and Younger Cambay Shale with an unconformity in between. In the
following period, relative subsidence of the basin continued leading to the accumulation of the
Younger Cambay Shale. The end of Cambay Shale deposition is again marked by the development of
a widespread unconformity that is present throughout the basin.
Subsequently, there was a strong tectonic activity that resulted in the development of the Mehsana
Horst and other structural highs associated with basement faults.
Middle Eocene is marked by a regressive phase in the basin and this led to the development of the
Kalol/ Vaso delta system in the north and the Hazad delta system in the south. Hazad and Kalol/
Vaso deltaic sands are holding large accumulations of oil.
Major transgression during Late Eocene-Early Oligocene was responsible for the deposition of the
Tarapur Shale over large area in the North Cambay Basin. The end of this sequence is marked by a
regressive phase leading to deposition of claystone, sandstone, and shale alternations and a
limestone unit of the Dadhar Formation.
The end of the Palaeogene witnessed a major tectonic activity in the basin resulting in the
development of a widespread unconformity.
During Miocene the depocenters continued to subside resulting in the deposition of enormous
thickness of Miocene sediments as the Babaguru, Kand and Jhagadia formations.
Pliocene was a period of both low and high strands of the sea level, allowing the deposition of sand
and shale.
During Pleistocene to Recent, the sedimentation was mainly of fluvial type represented by
characteristic deposits of coarse sands, gravel, clays and kankar followed by finer sands and clays,
comprising Gujarat Alluvium.
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Petroleum System
Source Rock:
Thick Cambay Shale has been the main hydrocarbon source rock in the Cambay Basin. In the
northern part of the Ahmedabad-Mehsana Block, coal, which is well developed within the
deltaic sequence in Kalol, Sobhasan and Mehsana fields, is also inferred to be an important
hydrocarbon source rock. The total organic carbon and maturation studies suggest that
shales of the Ankleshwar/Kalol formations also are organically rich, thermally mature and
have generated oil and gas in commercial quantities. The same is true for the Tarapur Shale.
Shales within the Miocene section in the Broach depression might have also acted as source
rocks.
Reservoir Rock:
There are a number of the reservoirs within the trapwacke sequence of the Olpad
Formation. These consist of sand size basalt fragments. Besides this, localized sandstone
reservoirs within the Cambay Shale as in the Unawa, Linch, Mandhali, Mehsana, Sobhasan,
fields, etc are also present.
Trap Rock:
The most significant factor that controlled the accumulation of hydrocarbons in the Olpad
Formation is the favorable lithological change with structural support and short distance
migration. The lithological heterogeneity gave rise to permeability barriers, which facilitated
entrapment of hydrocarbons. The associated unconformity also helped in the development
of secondary porosity.
Cap Rock:
Transgressive shales within deltaic sequences provided a good cap rock.
Timing of migration & Trap formation:
The peak of oil generation and migration is understood to have taken place during Early to
Middle Miocene. (DGH)
Thermal History
The thermal history of the basin is characterized by initial high heat flow followed by cooling
as the rift aborted. The average heat flow is of the order of 2.07 HFW. The normal
geothermal gradient is of the order by 34-40 C/km and at places it goes upto 50-60 C/km.
Very high thermal anomaly is observed around Cambay-Kathana area in Cambay-Tarapur
tectonic block. In general, in rift tectonics, the high heat flow zone can be attributed to
lithospheric thinning. Interestingly, this part of the basin is characterized by high gravity
anomalies, Bouger anomaly +37 mgals. (Madan Mohan, 1995).
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Source Potential
Favorable thermal history with high
heat flows followed by cooling effect
has facilitated for generation and
preservation of hydrocarbon in the
Cambay Basin. The syn-rift organic
rich Cambay Shale constitute the
principle source facies of kerogen
type II/III and total organic carbon
(TOC) is higher in the northern basin
(figure 14), whereas maturity level is
higher in the south.
Early oil generation and expulsion
took place in the northern part of the
basin, isotope and biomarker studies
indicate subsequent entrapment
close to the source facies thus
undergoing short distance migration.
At places, low maturity (VRo =0.4-0.5)
oil in Mehsana sub-block is attributed
to oil generation from coal. The
source potential towards the
northern part of the basin, i.e. in
Tharad and Sanchor appears to be
deposited in lacustrine environment.
In the southern part, the oil
generation took place since Middle
Eocene and basin wide oil migration FIGURE 14 TOTAL ORGANIC CARBON (TOC) CONTOUR IN CAMBAY
S HALE
took place in Early Miocene time.
(Madan Mohan, 1995).
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Petroleum plays
Structural Highs and fault closures & Stratigraphic traps (pinchouts / wedgeouts, lenticular
sands, oolitic sands, weathered trap) in Paleocene to Miocene sequences have been proved
as important plays of Cambay Basin.
4. Miocene Play:
Formations: Deodar: Formation (LR. Miocene), Dhima Formation (Mid Miocene), Antrol
Formation (Upper Miocene)
The Mahi River delta sequence extends further westward to Cambay area where
Miocene rocks are hydrocarbon bearing. (DGH)
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Background
Balol field was discovered in 1970 and put on production in 1985 through conventional
cased vertical wells drilled at 22 acre spacing.
Artificial lifts like Sucker rod pumps and screw pumps were used for cold production in Balol
and Santhal. However, the primary recovery was low, of the order of 13% due to adverse
mobility contrast between oil and water. (Har Sharad Dayal et.al, 2010)
Steam injection and ISC were the two options considered. But, steam injection could not be
implemented owing to depth of 1000m, presence of strong water drive and a pay thickness
of 5m. This left ISC as the choice for pilot testing.
Geology
The Balol field is about 13 km in length forming N-S trending homocline dipping 3-5. Oil is
distributed in four oil bearing sands i.e. U, K-1 & K-II sands in Kalol formation and Lower Pay
formation from top to bottom. These pay sands were deposited during the early and middle
Eocene period and represent the characteristic regressive cycle intervening between two
major transgressive shale deposits. Kalol formation accounts for 95% of the field OOIP.
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ISC implementation
In Balol field, the process was tested in the laboratory and in the field on a pilot & semicommercial scale prior to commercialization in 1997. The commercialization process was
done in two phases- Phase I and Phase II and it was based on the Nelson & Mc Neil
approach.
In Santhal field, the ISC process was executed in KS-1 reservoir adopting an inverted 5 spot
injection-production pattern in the north western part. But, during commercial application,
it was changed to up-dip line drive (S.K Chattopadhyay et.al, 2004).
ISC process
Both in Balol and Santhal fields artificial ignition was carried out using Gas Burner as
opposed to spontaneous combustion. This is because with artificial ignition, high vertical
sweep can be achieved. Also, the chances of oil saturation close to the wellbore become
less. So, if there is unplanned stoppage of air injection, the chances of backflow of flue gases
into the injection wells is minimised.
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Production performance
Balol field: In phase 1 of the ISC implementation, pre-initiation cold oil production was about
60 m3/d with water cut of 80%. With air injection, the oil production increased to 260 m3/d
with reduction of average water cut from 82% to about 40% (Figure 16).
In Phase II oil production rate increased up to 500 m3/d. Air injection peaked in 2004 at the
rate of 0.5 MM S m3/d. Meanwhile, the oil production has shown a linear increase with air
injection rate (Figure 17). Up to 2010, 960 MM Sm3 of air has been injected, yielding 0.63
MM m3 of incremental oil (Har Sharad Dayal et.al, 2010).
F IGURE 17 CROSS PLOT OF AIR RATE & OIL PRODUCTION RATE IN PHASE II (HAR SHARAD DAYAL ET.AL,
2010).
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Issues
Rupture of Downhole-equipment at high temperature and high pressure: 2 incidents of
bursting of 3rd stage air compressors had taken place in Santhal field.
Flow back of flue gases: Breakthrough of flue gases along with air have been noticed in
the Balol field in 2006, due to annular leakage in one injector well. Drilling of new
injector wells with right casing policy, cementation and metallurgy for tubing is
required.
Highly costly technique. Combustion started at the injector results in hot produced
fluids that often contain unreacted oxygen. These conditions require special, high-cost
tubular to protect against high temperatures and corrosion. More oxygen is required to
propagate the front compared to forward combustion, thus increasing the major cost
of operating an in situ combustion project.
Page | 32
Reservoir Characteristics
KIV sand of Jhalora oil field is heterogeneous in character. There is also large variation in
viscosity of the reservoir oil (ranging from 30 to 50 cP at reservoir temperature) with
adverse mobility ratio are the reasons for high water cut/production behavior of the wells.
The build-up studies indicate wide variation in the permeability. Core collected during
laboratory studies confirms the same. The permeability data obtained through build-up
studies varies between 1.9 to 8.7 Darcy. The sand K-IV mainly consists of sandstone which is
medium to dark gray, compact in nature. The major framework mineral for the unit is
quartz. Pyrite is present in traces. Crude oil is acidic in nature which helps in in-situ
Page | 33
S.No. Parameters
Value
1265
7-9
Temperature, OC
82
140
99
58 - 73
Porosity, %
28 - 32
1.9 8.7
10
30 - 50
11
0.9201
12
11291
The mature stage of the field with heterogeneous reservoir and unfavorable fluid
characteristics makes it an ideal choice for application of chemical process an EOR technique
to enhance recovery. Based on properties of the K-IV sand and screening criteria (attached in
Appendix) in the table above, ASP was chosen as the EOR technique to be applied in the
field.
Before Field implementation, Extensive lab and Simulation studies were done by Institute of
Reservoir Studies (IRS)-ONGC, Ahmedabad. Results of these studies are summarized in the
following points:
envisage incremental displacement efficiency of about 23% of OIIP
Pilot design envisage injection of 0.3 Pore Volume (PV) ASP slug (2.5 wt% Sodium
Carbonate, 0.25 wt% surfactant and 1500 ppm of polymer) 0.3 PV graded polymer
buffer (three slugs of 0.1 PV each with polymer concentrations 1200, 800 and 400
ppm) followed by 0.4 PV chase water
ASP injection rate of 150m3 /day was recommended
Inverted 5-spot pattern pilot was designed
Page | 34
Field Implementation
In view of heterogeneous reservoir and unfavorable fluid characteristics, polymer gel based
profile modification job was carried in the ASP pilot injection well JH #I prior to
commissioning of ASP pilot. After that pre-flush of 2% NaCl was injected followed by 16 m3
of tracer (Ammonium Thiocyanate) injection. ASP pilot project started functioning from 07th
February 2010.
F IGURE 19 SCHEMATIC MAP OF JHALORA ASP P ILOT AREA (JAIN , D HAWAN , & MISHRA , 2012)
Where,
Page | 35
F IGURE 20 C OMBINED PERFORMANCE OF SIX J HALORA ASP P ILOT PRODUCERS (JAIN , D HAWAN , & MISHRA , 2012)
Page | 36
General Geology
Sanand field is located at the western margin
in the southern part of the Ahmedabad
Mehsana tectonic block of Cambay basin.
Structure consists of an elongated doubly
plunging anticline NNW-SSE. Sanand is a
multi-layered reservoir in Kalol sands but KSIII is the main reservoir, which belongs to
Kalol formation of Eocene age (Deepti
Tiwari, 2008). The structure is dissected by a
number of faults dividing it into many sub
blocks. The faults have limited throw in the
range of 5-15 m but due to thin reservoir
interval interbeded within shales, these
faults appear locally as effective permeability
barriers. The section is dominated by
interbeded sands, silts, shales and coals,
interpreted as a combination of marine,
coastal marsh and deltaic flood plain FIGURE 21 LOCATION MAP OF SANAND FIELD (C HANCHAL
D ASS , 2008).
environment (S.K.Sharma, 1997).
Page | 37
Page | 38
Performance Monitoring
The main objective of polymer injection is to improve oil recovery from the field with
reduced water cut. So maintenance of injection polymer quality and quantity is vital for the
success of polymer flood project. The parameters that were selected for the monitoring
purpose included salinity determination of the produced water, tracer concentration; water
cut data and polymer concentration. PLT study, Pressure Fall Off study and Pressure Build-up
tests, Temperature survey and Flow meter survey are also carried out regularly. The
production and the injection data are continuously collected and monitored for the
identification of the various problems and implementation of the corrective measures.
Echometer surveys are conducted periodically to measure fluid level and reservoir pressure
(Mahendra Pratap, 1997). Monitoring also includes checking quality of injected water for
chemical, mechanical and bacteriological degradation by measuring turbidity, dissolved
oxygen, iron content, salinity and pH factor both at polymer tank and injection lines. Physical
cleaning and disinfection of polymer tanks and flowlines, proper removal of dissolved
oxygen by oxygen scavengers, biocide dosing to reduce bacterial effect are some of the steps
taken from time to time. Injectivity tests are conducted in polymer/chase water injectors
from time to time and corrective measures are taken (Deepti Tiwari, 2008).
Production Performance
The results before and during the polymer injection of the pilot phase are shown in figure. It
is evident that there is profile improvement as a result of polymer injection which indicates
that polymer had a beneficial effect on injection well. Change in resistance factor (ratio of
mobility of water to mobility of polymer) was also observed with the help of PFO tests and it
was found that RF increases with increase in polymer concentration. Production response to
polymer injection during EPP was also encouraging (Mahendra Pratap, 1997). In April 2008,
the sand has produced oil at rate of 232m3/d with 68% water cut from 44 producers. A total
of 508 m3/d of polymer solution had
been injected through 9 wells along
with 683 m3/d of chase water through
9 wells (Deepti Tiwari, 2008).
Page | 39
Field Review
Performance review, using reservoir simulation, has been carried out from time to time and
exploitation strategy has been planned /modified accordingly. Simulation study of 1984
predicted depletion recovery of 14%. After initiation of polymer injection, simulation studies
were carried out in a Black oil simulator with polymer option. Again review was carried out
in 2007 to identify areas of by-passed oil, suggest in-fill locations and to assess requirement
and effect of polymer injection. Recovery of 35% is predicted by 2020. Polymer injection is
extended up to 2013 based on 25% of total pore volume injection (Deepti Tiwari, 2008).
Page | 40
Field history
Viraj field was discovered in 1977 with drilling of an exploratory well-Viraj-1. A technological
scheme was prepared in 1981. Simulation studies carried out in 1985 indicated a recovery of
24.6% of OIIP by the year 2001. Main problems encountered in the field during the course of
production were high water cut, sand-cut and frequent down-hole chocking of perforations
and tubing due to asphaltic nature of the crude oil. The field has been developed with a
close spacing of 200-250 metres and there is little scope for infill drilling to increase the
ultimate recovery. In view of the Petrophysical properties of reservoir and characteristics of
crude oil, ASP flooding emerged as most suitable EOR process for achieving maximum
recovery.
Reservoir Description
The presence of oil and gas in Viraj field was established in Kalol equivalent pay zones VIII,
IX+X, Chhatral member of Kadi formation and C+D. Pay zone IX+X, the main producing
horizon, is subdivided into two layers viz. L1 and L2 separated by coal shale band of 4-5 mts.
The structure of the field is a doubly plunging anticline trending NNE-SSW. The southern
flank of the structure is dissected by a fault forming the western limit (Figure 26).
Lithologically, rock is composed of brownish grey, coarse to medium grained, moderate to
Page | 41
RESERVOIR DESCRIPTION
Lithology
Sandstone
Avg. Depth (mts.)
1300
Avg. Pay thickness (mts.)
19
Porosity (%)
30
Permeability Range (Darcy) (Build-up) 4.5 to 9.9
Reservoir Temp. (O C)
81
Initial Res. Pressure (Kg/Cm2)
136
Current Res. Pressure (Kg/Cm2)
126
Drive Mechanism
Active acquirer
Area weighted average porosity is 30% and permeability determined by pressure
transient tests ranges from 4.5 to 9.9 Darcies (Table 3). The gravity of the oil averaged 18.9
degree API and the viscosity at reservoir conditions of 136 kg/cm2 and 81o c was 50 cp. The
pour point is 15oCand salinity is 13.25 mg/lit. The crude oil is having 4.48 % asphaltenes,
5.67 % wax content and 18% resin by weight. The Viraj crude is acidic in nature, having acidic
component 1.8520 mg KOH/gm. of crude oil (Table 4). The initial reservoir pressure i.e. 136
kg/cm2 has marginally declined to 126 kg/cm2 after a cumulative oil production of 18.9 % of
OIIP. It shows that reservoir is operating under active water drive.
T ABLE 4 CRUDE OIL P ROPERTIES IN VIRAJ:
CHARACTERISTICS OF SURFACTANT
Name
Petroleum Sulphonate (HLA)
Nature
Anionic
Activity
60%
Thermal Stability
Stable at 81oC
Solubility
Soluble in water & Oil phase
CMC value
0.20 wt%
IFT between Viraj crude oil & tube
well water having 0.20 wt% 0.61 mill dynes / cm
Surfactant & 1.5 wt% Sod. carbonate
Page | 42
Field implementation:
Surface Facilities and Operation. Surface facilities were created for storage of tube well
water, storage of Alkali Surfactant and Polymer Solutions mixing the chemicals, injection of
different on-line doses and injection of prepared slugs to injectors. Facilities for handling the
produced fluids were already existing in Viraj field. The injection plant was designed to
minimize the manpower requirement. Plant design parameters included facilities to inject
liquid @ 800 m3/d.
Data Acquisition
With a view to closely monitor the performance of the pilot, a comprehensive data
acquisition strategy was formulated. The data acquisition programme included:
Injection details viz. the actual injection rate, volume and stabilized injection
pressure for each injector separately.
Parameters of the injected fluid like concentration, Turbidity, PH etc. for Pre-flush,
ASP slug and mobility buffer prepared in each tank.
Continuous recording of production details including production rate, water cut etc.
for each producer separately.
Record of consumption of each chemical on daily basis with a view to plan the action
for procurement of Chemicals in time.
As all the wells of the pilot are operating on SRP, echo meter studies are carried out
under both dynamic and static conditions at regular intervals.
Production logging was planned for all the injection wells periodically to get
information regarding injection profile near the well bore and also to detect the
presence of high permeability streaks, if any.
In order to understand the pattern of fluid flow through the matrix, the presence of
tracer is being monitored in the samples collection from all the pilot and offset
producers.
Samples from both production and injectors are also analysed at regular interval for
bacterial presence and suitable biocide treatment would be given in case of high
bacterial counts.
T ABLE 6 PARAMETERS M ONITORED DURING IMPLEMENTATION :
PARAMETERS MONITORED
ASP Slug Mobility Buffer Chase Water
Parameters
Concentration
Alkali (Wt %)
Surfactant, ppm
Polymer, ppm
Turbidity, NTU
Dissolved O2 ,ppm
Iron, ppm
Salinity gm/lit
pH
1.5 0.01
2000 40
800 20
< 10
< 1.2
< 1.5
5
10-11.5
+ 20
< 10
< 1.2
< 1.5
<3
7.7- 9.0
< 10
< 1.2
< 1.5
<3
7- 8.5
Page | 43
Results
Performance of the pilot area wells just prior to the commencement of ASP pilot on 10th
August 2002 indicated that 9 wells were producing oil @ 24.4 m3/d with an average water
cut of 83.5%. Performance of these wells during the first phase i.e. ASP injection is
encouraging as there is improvement in oil rate from 24.4 m3/d to 98.23 m3/d. Average
water cut has also reduced from 83.5% to 71.4 %.
Conclusion
ASP (Alkaline-Surfactant-Polymer) flooding has shown encouraging results improving
recovery over water flood during laboratory studies. Pilot is under way to test the efficacy of
the process under actual field conditions and also to fine tune the process parameters.
Significant conclusions of the efforts made so far may be summarized as follows:
Reservoir rock and fluid properties were studies in detail before ASP flooding was
identified as potential EOR technique to improve recovery efficiency in Viraj field.
Suitable chemicals identified for successfully implementing ASP pilot in Viraj are:
o Sodium Carbonate as alkali.
o Petroleum Sulphonate as surfactant, and
o Partially hydrolyzed Poly acrylamide (PHAA) as Polymer.
Laboratory tests were conducted to:
o Optimize ASP concentrations
o Formulate Injection Strategies
o ASP slug design
o Defining mobility buffer sequence.
Performance evaluation during the first phase of the pilot shows encouraging results in
terms of both improvement in oil rate and reduction in Water cut.
Indication of in-situ emulsion formation shows the efficacy of ASP flooding during this
phase of the pilot.
Polymer / Tracer break through needs close monitoring in producing wells to
understand the preferential flood-front movement.
Successful field implementation requires continuous efforts and close field monitoring
of the pilot to test the efficiency and effectiveness of ASP flooding as potential EOR
technique.
Page | 44
Equipment expenditures
Well, lease, and field production equipment: Install equipment necessary to
operate new production wells.
Injection equipment: Install equipment necessary to operate new injection wells.
Separation and compression equipment: Install sufficient equipment to produce
maximum yearly requirement for recycle indicants.
Page | 45
Page | 46
Page | 47
Page | 48
Page | 49
Page | 50
Alkaline
Flooding
>20ft
high porosity
sandstone
>40%
not critical
<5000cP
<200000
>10
>8
Combustion
Steam
>10ft
high porosity
sandstone
>50%
some asphaltic
components
<200cP
>20
not critical
not critical
above
sandstone
waterflood
residual
Thermal Methods
>50%
>10ft
preferably sandstone
not critical
<150cP, better
if 10<cP <100cP
>15
Polymer
flooding
>30%
>200md
>50md
>20md
>10md
<4500ft
<11500ft
<9000ft
<9000ft
not critical
<100*F
<200*F
200*F
<200*F
>25
Surfactant
Flooding
Enhanced Waterflooding
<8000ft
not critical
>1800ft
not critical
not critical
not critical
>35%
not critical
<600cP
>12
Immisible gases
>20md
not critical
>2500ft
not critical
wide range
sandstone or carbonate
>20%
<10cP
>22
CO2
not critical
>4000ft
not critical
>30%
high % of C2-C7
<10cP
>35
HC miscible
<30cP
not critical
>6000ft
Depth Temperature
Average
Permeability
>40%
Net Thickness
high % of C1-C7
Formation Type
<0.4cP
Oil Saturation
(% Pore Vol)
>35
Composition
Viscosity (cP)
Gravity
{API}
EOR Technique
Appendix
Page | 51
<200
<35
<150
<35
12.9
Taber et al (1997a,b)
Proposed by
0.3
>0.45
>0.35
473
>100
>50
> 10
50,000
7993
178
1000
Sandstone
Sandstone
52
<20,000 if Tr<60oC
<93.3
<50,000 if Tr>60oC
<70
<93.3
Low
Low
Clay
No
Aquifer
No
Gas cap
Well
Spacing
(ft)
Page | 52
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