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Question1.
Considertheconversionofametalhalide

to

Identifycorrectstatement(s)foraboveconversion.
ismoreionicwhereas

[A]

ismorecovalent

[B]

Forthaliumhalide,

[C]
[D]

Forleadiodideforwardreactionisnotpossible
Inagroupofpblock,oxidizingpowerof

ismorestableand

islessstable
increasesonmovingdownthegroupinperiodictable

Question2.
Whichofthefollowingreactionproducetertbutylbenzene?
[A]

[B]

[C]

[D]

Question3.
Twoisomericoctahedralcomplexhastheempiricalformula

andconductancemeasurementindicatethat

therearetwoionsperformulaunit.Whichofthefollowingstatement(s)is(are)correctabouttheseisomericcomplexes?
[A]

Aqueoussolutionofbothcomplexesdonotformwhiteprecipitateof

[B]

OneoftheisomerformsapaleyellowprecipitateofAgBrwith

[C]
[D]

Inoneoftheisomercoordinationsphereisacation
Inoneoftheisomercoordinationsphereisananion

onreactionwith
solution

Question4.
Whichofthefollowingis(are)correct?
[A]
[B]

canshowscoordinationisomerism
canshowslinkageisomerism

[C]

canshowsionizationisomerism

[D]

canshowshydrateisomerism

Question5.
Whichofthefollowingatomicorbitalcanoverlapwithanatomicorbitalofthesametypeonanadjacentatom(bothatomslieonthexaxis)
togivea
bond?
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[A]
[B]
[C]
[D]

Question6.
Whichofthefollowingis(are)product(s)ofdehydrationofthecompoun

[A]

[B]

[C]

[D]

Question7.

[A]

[B]

[C]

[D]

Question8.
Inwhichofthefollowingreaction,productisusedasmonomerforsynthesisofpolymer?
[A]

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[B]

[C]
[D]

Question9.
Foranisothermalfreeexpansionofanidealgasintovacuum,whichofthefollowingis(are)correct?
[A]
[B]
[C]

w=0

[D]

Question10.
Considerthefollowingreactionsequence:

Identifythecorrectstatement(s)forabovereactionsequences.
[A]
[B]
[C]
[D]

Formationofonitrophenolandpnitrophenoliselectrophilicsubstitutionreaction
Hydroxygroupisorthoandparadirecting
Mixtureofonitrophenolandpnitrophenolcanbeseparatedbysteamdistillation
Theoverallyieldfortheformationofphydroxyacetanilide[X]andohydroxyacetanilidefromphenolisnearly57%and20%
respectively

Question11.
Inthegasphase,theratioofexcludedvolumetomolecularvolumeforasphericalmoleculeis________.

Question12.
ThepKavaluesof
0.1M

are2.12,7.30and12.67respectively.ThepHofaphosphatebuffercontaining0.2M

and

isnearly_________.[log2=0.30]

Question13.
Aquantitativemethodtodeterminephosphatelevelsinaqueoussolutioninvolvesaddingammoniummolybdate

,to

formaprecipitateofammoniummolybdophosphate.Thestructureofthissolidisbasedonacuboctahedron.Amolybdenumatomliesat
eachvertexofthecuboctahedronandthesearejoinedbyoxygenatomswitheveryedgeofthecuboctahedronbeingbridgedbyan
oxygenatom.Afurtheroxygenatomisjoinedtoeveryvertex.Asinglephosphateunitliesatthecentreofthestructurewitheachofits
fouroxygenatomscoordinatingtothreemolybdenumatoms.Whatisratioofnumberofmolybdenumionstothenumberofammonium
ionsinthesolid?
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Question14.
ThedeBroglie'swavelengthofHeatT1Kis500

andthatofNeatT2Kis100

.Thenumericalvalueof

is________.

[Atomicmass:He=4,Ne=20]

Question15.
Phosphoroustrichloridecanbepreparedbyreactionofwhitephosphorouswiththionylchloride.Howmanymolesof
withonemoleof

reacts

togivesphosphoroustrichloride?

Question16.
Howmanyisomericketonehavingmolecularmass100onreactionwithNaOHandI2formyellowprecipitateandalsoformracemic
mixtureonreductionwith
?

Question17.
Hexahydrocoronenehasacloseloopofdelocalizable(4n+2)

electrons.Whatisvalueofn?

Question18.
Howmanyofthefollowingonreactionwith
gashavingnonlabeledcarbon

havinglabeledcarbon

atomgivesbriskeffervescencedueto

atom?['*'Itindicatelabeledcarbonatom(C14)]

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Question19.
MATCHTHEFOLLOWINGLISTS:
Column1

Column2

A: Carbondioxide

1: Resonance

B: Ozone

2:

C: Borontrifluoride

3:

Oneofthecontributorshaspositiveformalchargeon
moreelectronegativeatom.
4:
bond
5: Oneofthecontributorhasdoublebond

D: Carbonmonoxide(CO)

Question20.
MATCHTHEFOLLOWINGLISTS:
Column1

Column2

A:

1: Aromaticproduct

B:

2: Freeradicalreaction

C:

3: Gaseousproduct

D:

4: Eliminationreaction

5: Ionicreaction

Question21.
ApendulumisconstructedfromtwoidenticaluniformthinrodsAandBeachoflengthLandmassm,connectedatrightanglestoforma
TbyjoiningthecentreofrodAtooneendofrodB.The'T'isthensuspendedfromthefreeendofrodBandthependulumswingsinthe
planeofthe'T'.

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[A]

Themomentofinertiaofthe'T'abouttheaxisofrotationis

[B]

Themomentofinertiaofthe'T'abouttheaxisofrotationis

[C]

Theperiodofsmallangularoscillationsof'T'is

[D]

Theangularfrequencyof'T'forsmallangularoscillationsis

Question22.
AlongstraightwirecarriesacurrentalongtheXaxis.ConsiderfourpointsP(0,1,0),Q(0,1,1),R(1,0,1)andS(1,1,1).Whichofthe
followingpairsofpointswillhavemagneticfieldsofthesamemagnitude?
[A]
[B]
[C]
[D]

PandQ
PandR
QandR
QandS

Question23.
Achargedparticleofunitmassandunitchargemoveswithvelocity

inamagneticfieldof

Choosethecorrectalternative(s).
[A]

Thepathoftheparticlemaybe

[B]

Thepathoftheparticlemaybe

[C]

Thepathoftheparticlemaybe

[D]

Thetimeperiodoftheparticlewillbe3.14s

Question24.
AtunnelisdugalongachordoftheearthataperpendiculardistanceR/2fromtheearthscentre.Thewallofthetunnelmaybeassumed
tobefrictionless.Aparticleisreleasedfromoneendofthetunnel.Thepressingforcebytheparticleonthewallandtheaccelerationof
theparticlevarieswithx(distanceoftheparticlefromthecentreoftheearth)accordingto:

[A]

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[B]

[C]

[D]

Question25.
Astudentperformedtheexperimenttomeasurethefocallengthofconvex(converging)lensbylensdisplacementmethod.(Firstan
approximateestimateofthefocallengthwasobtainedbydistantobjectmethodinwhichadistantobjectwasfocusedonthescreenusing
thelensandthedistancebetweenlensandscreennotedas'f',thefocallengthofthelens).Thedistancebetweentheobjectandscreen
isadjustedtobeavalue'l'.Nowthelens,wasmovedfromtheobjecttothescreenandclearimagesareobtainedfortwopositionsofthe
lens,thefirstpositionL1,whichisclosertoobjectand2ndpositionL2whichisclosertoscreen.Thedistancebetweenthetwoposition
i.e.

(say).Letthefocallengthobtainedbe

[A]

Thevaluesof

[B]
[C]
[D]

TheimageforpositionL1oflensisdiminishedandthatforpositionL2oflensismagnified
Aslisincreased(formorenumberoftrials),'d'alsoincreases

usedare>4f

Question26.
OneendofanidealspringisfixedatpointOandotherendisattachedtoasmalldiscofmassmwhichisgivenaninitialvelocityv 0
perpendiculartoitslengthonasmoothhorizontalsurface.Ifthemaximumelongationofthespringis

then(l0=naturallength,k=

stiffnessofthespring)

[A]

Velocityatmaximumelongationis

[B]

Velocityatmaximumelongationis

[C]

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[D]

Question27.
AthinconductingrodABisintroducedinbetweenthetwocharges

asshowninfigure.Forthissituationmarkthe

correctstatement(s):

[A]

Thetotalforceexperiencedbyq1isvectorsumofelectricforcedueto

andduetoinducedchargesonrod.

[B]

TheendAwillbecomenegativelycharged

[C]

Thetotalmagnitudeofforceactingon

willbegreaterthanascomparedtothecasewithoutrod

[D]

Thetotalmagnitudeofforceactingon

willbegreaterthanascomparedtothecasewithoutrod

Question28.
AcapacitorofcapacitanceCwithupperplateMandlowerplateNisconnectedtotwoparallel,horizontalrailsofgoodconductor.A
metallicrodPQisacteduponbyaconstanthorizontalforceF,sothattherodcanslidesmoothlyontherails.Auniformverticalmagnetic
field
actsintotheplaneoftherails.Duringthemotionoftherod,

[A]
[B]
[C]
[D]

ThechargeonplateMispositiveandthechargevaluekeeponincreasing
ThechargeonplateMispositiveandthechargevalueremainsconstant
ThechargeonplateNisnegativeandthechargevaluekeeponincreasing
Thecurrentflowingthroughtherodremainsconstant

Question29.
Aslaboftransparentmaterialsismadeasshowninthefigure.Monochromaticparallelbeamsoflightarenormallyincidentontheslabs.
ThethicknessofCistwicethethicknessofB.ThenumberofwavesinA=thenumberofwavesinthecombinationofBandC.The
refractiveindexofmaterialAis

[A]
[B]
[C]
[D]

andthatofCis

TherefractiveindexofBis1.6
ThefrequencyoflightinBistwotimesthefrequencyoflightinC
TherefractiveindexofBis1.7
ThefrequencyoflightinBisthesameasthefrequencyoflightinC

Question30.
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Oneendofalongcylindricalbariskeptat

andtheotherendismaintainedat

.Inthesteadystatethegraphof

temperatureofbaragainstdistancefromhotendisshownhere.Fromthegraphwhichofthefollowingstatementscanbeconcluded
correct?

[A]
[B]
[C]
[D]

Thequantityofheatenteringthehotendpersecondisequaltothatleavingtheotherendpersecond
Thequantityofheatenteringthehotendpersecondisgreaterthanthatreachingtheotherendpersecond
Noheatisabsorbedbyanypartofthebar
Heatislostfromthecurvedsurfaceofthebar

Question31.
Averticalcapillarywithinnerdiameter0.50mmissubmergedintowatersothatthelengthofitspartprotrudingoverthewatersurfacein
25mm.Theradiusofcurvatureofthemeniscusis
.Findxtonearestinteger.(Surfacetensionofwater
)

Question32.
InthecircuitshownintheadjacentdiagraminitiallyswitchK1isclosedandswitchK2isopen.Afterlongtime,K2isalsoclosed.The
currentthroughthecellofemfEimmediatelyafterK2isclosedis

.Findx.

Question33.
Auniformrodisrotatingaboutoneofitsendwithaconstantangularvelocity
halvesis

.Thenfindthevalueof

ingravityfreespace.Theradiostrainproducedintwo

Question34.
InthefigureshownablockBofmassmcanslideonafixedhorizontalsmoothplane.AsolidsphereAofradiusrofthesamemassrolls
withoutslidingontheblockB.Theangularaccelerationofthesphereis

,findthevalueof'n'.

Question35.
Thereadingofaspringbalancewhenablockissuspendedfromitinairis60N.Thisreadingischangedto40Nwhentheblockis
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submergedinwater.Findthespecificgravityoftheblock.

Question36.
Uniformrodmass(2m),lengthL,islyingonasmoothhorizontalsurface.Twoinsectofmassmeachmovinghorizontallyand
perpendiculartorodhitstherodandstickit.Afterhittingtherod,insectstartswalkingalongtherodawayfromcenterwithconstant
speedv,relativetorod.Thetotalanglerotatedbytherod,tilltheinsectreachestheendsofrodis

.Thevalueofxis

_______.

Question37.
Aliftismovingupwithaconstantretardationof2m/s 2.Whenitsupwardvelocityis5m/s,aboyinthelifttossesacoin,impartingitan
upwardvelocityof3m/s,w.r.t.himself.Hisfingersatthemomentoftossaremidwaybetweenthefloorandceiling,whosetotalheightis
2m.Displacementofcoinwhenitshitsthegroundisxmetre(inearthframe).Thevalueofxis________.(g=10m/s 2)

Question38.
Atadistanceof20mfromapointsource,theloudnessis30dB.Afteraminimumdistanceof

meterthesoundis

inaudible.Thevalueofxis________.

Question39.
BlockAslidesdownthewedgeofsamemass.Allsurfacesaresmooth.Theangleofinclinationofwedgeis
thecolumns.

Column1

Column2

A: Relativeaccelerationofblock'A'w.r.t.wedge

1:

B: AbsoluteaccelerationofblockA

2: Zero

C:

withhorizontal.Match

Accelerationofcentreofmassofblockandwedgein
3:
horizontaldirection

D: Accelerationofcentreofmassofsystem

4:

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Question40.
Refractiveindexoflensesis3/2.Thenthefinalpositionoftheimagefromthepoleis:
Column1

Column2

A:

1: 40/7cm,lefttoP

B:

2: 40/9cm,righttoP

C:

3: 40/3cm,righttoP

D:

4: 40cm,lefttoP

5: 20/3cm,lefttoP

Question41.
If

beindependenteventssuchthat

eventsoccursin

[A]

andprobabilitythatnoneofthe

,then:

isoftheform

[B]
[C]
[D]

has32divisors
has502zerosattheend

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Question42.
Ifgraphof

is:

Thenwhichofthefollowingcanbetruefor
[A]

pointofinflectionatx=1andx=2

[B]

concavedownin

[C]

pointoflocalmaximaatx=3

[D]

decreasingininterval

Question43.
Theequationwhoserootsarenthpoweroftherootsoftheequation,

,isgivenby:

[A]
[B]
[C]
[D]

Question44.
Atthepoint

onthegraphof

,anormalisdrawntointersecttheyaxisatpoint(0,b)andif

,then:

[A]

I=0if

[B]

if

[C]

I=2ifn>2
ifn=2

[D]

Question45.
If

hasrealroots

and

,then:

[A]
[B]
[C]

For

[D]

For

Question46.
Takingyasthedependentandxastheindependentvariable,whichofthefollowingordinarydifferentialequationsarenotlinear?
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[A]
[B]
[C]
[D]

Question47.
Let

hasboththerootsequal,then:

areinAP

[A]

[B]

[C]

pq,rq,rp,areinAP
areinA.P.

[D]

Question48.
Aplanewhichisperpendiculartotwoplanes

and

[A]

Distanceoftheplanefromthepoint(1,2,2)is

[B]

Distanceoftheplanefromthepoint(1,2,2)is

[C]
[D]

Imageofthepoint(1,2,2)abouttheplaneis(3,2,2)
Footoftheperpendicularof(1,2,2)ontheplaneis(1,0,2)

andpassesthrough

,then:

Question49.
isequalto:
[A]
[B]
[C]
[D]

Question50.
Whichofthefollowingis(are)true?
[A]

No.ofsolutionoftheequation

[B]

Solutionsetoftheequation

isone

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[C]

isequalto
isequalto

[D]

Question51.
If

thenminimumvalueof

is__________.

Question52.
IfcurveCbetheimageof

C,then

abouttheline

and

belengthoftheinterceptof

madebycurve

is________.

Question53.
Let

({.}denotesfractionalpart),thenremainderobtainedondividingy+y 2+y 3by31is

__________.

Question54.
Forauniquevalueof
infinitelymanysolutionsthen

,thesystemofequationsgivenbyx+y+z=6,x+2y+3z=14,

has

is__________.

Question55.
ThreedistinctnonzerorealnumbersformanA.P.andsquaresofthesenumberstakeninsameorderformaG.P.,ifpossiblecommon
ratioofG.P.are

thennis___________.

Question56.
Thenumbers

arefirstthreetermsofanA.P.thensumofdigitsofitsfifthtermis____.

Question57.
Thevalueof

is

thenPis__________.

Question58.
If

hasatleastonerealroot,theleastinteger

justgreaterthanthemaximumvalueofais______________.
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Question59.
MATCHTHECOLUMN:
Column1

Column2

,nisoddinteger,

A:

1:

cannotsatisfy
,where[.]
B: denotesgreatestintegerlessthanorequaltox,then
f(x)cannotsatisfy
,thenf(x)cannot

C:

2:

3:

satisfy
cannotsatisfy

D:

4: Periodicfunctiondefinition
5:

Question60.
MATCHTHECOLUMN:
Column1

If
A:

Column2

then

1: 2

islessthan
B:

If
function),and
If

,denotesthegreatestinteger

2: 3

,thentherangeoff(x)contains
,thenh(x)=0forx=____

C:

3: 1
(where[.]denotesgreatestintegerfunction)
Ifthecircle
thecircles

D:

cutseachof
,
and

4: 0

attheextremitiesoftheir
diameter,then

isgreaterthan
5: 1

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