Flue Gas

1
312
4

25

FC

FT

PC

4.2

4.1

FC

LIC

FC

FT

PT TT

TC

FT

1
PC

H2O2

PT

PC

200

PT
7

P-202-A/B
1

H2O1

TC

P-203-A/B

R2O1

R2O2

14.6

200

25

TT

PC

S2O1

200

2
AC

AT

FC

LIC

PT TT

TC

FT

200

AT

5.2

342

39.5

5.1

342

39.5

P-201-A/B
AC

Cooling water
1
S2O2

H2O3

25

200
10
6

FC
H204
FT

Air Fuel
gas

FC

FT

Cooling Water

Figure 1. P&ID for Production of Ultra-Low Sulfur Diesel

Process Flow Diagram

<6>
Reactor Products

<7>
Off Gas 1
58,944.62 kg off gas/day
13.80 wt% (3.18 vol%) n-Dodecane/day
4.38E-03 wt% (9.31E-04 vol%) Dibenzothiophene/day
2.80 wt % (7.19 vol%)Biphenyl/day
2.39E-03 wt% (1.18E-03 vol%) Pyridine/day
1.25E-02 wt% (6.77E-03 vol%) Pentane/day
2.39E-02 wt% (0.46 vol%) H2/day
83.32 wt% (95.63 vol%)H2S/day
3.27E-03 wt% (7.50E-03 vol%) NH3/day

H203
T = 200C
P = 1 atm
5,099,816.39 kg reactor products/day
88.73 wt% n-Dodecane/day
0.03 wt% Dibenzothiophene/day
2.01 wt% H2S/day
8.97 wt% Biphenyl/day
0.01 wt% Pyridine/day
0.02 wt% NH3/day
0.08 wt% Pentane/day
0.15 wt% H2/day

<1>
Hydrogen
T = 25C
P = 1 atm
13,962.89 kg H2/day

H201
T = 200C
P= 1 atm

<2>
Diesel Fuel
T = 25C
P = 1 atm
5,085,853.50 kg Diesel Feed/day
88.97 wt% n-Dodecane/day
10.92 wt% Dibenzothiophene/day
0.11 wt% Pyridine/day

<3>
Hydrogen-Diesel
Mixture

<8>
Liquid Stream
H202
T = 312C
P = 1 atm

T = 200C
P = 1 atm
5,099,816.39 kg mixture/day
88.73 wt% n-Dodecane/day
10.89 wt% Dibenzothiophene/day
0.11 wt% Pyridine/day
0.27 wt% H2/day

<4>
Gasified Mixture
T = 312C
P = 1 atm
5,099,816.39 kg gasified mixture/day
88.73 wt% n-Dodecane/day
10.89 wt% Dibenzothiophene/day
0.11 wt% Pyridine/day
0.27 wt% H2/day

Total In: 5,099,816.39 kg/day

Legend:
H201: Preheater

S201: High-Pressure Gas-Liquid Separator

H202: Fired Heater

S202: Low-Pressure Gas-Liquid Separator

H204: Condenser
R201&R202: Fixed-bed Reactor

R201 & R202

T = 342C
P = 39.5 atm

<9>
Off Gas 2
54,336.38 kg off gas/day
1.66 wt% (3.85 vol%) n-Dodecane/day
5.27E-04 wt% (1.13E-03 vol%) Dibenzothiophene/day
0.17 wt % (0.43 vol%) Biphenyl/day
2.88E-04 wt% (1.43E-03 vol%) Pyridine/day
1.5E-03 wt% (8.19E-03 vol%) Pentane/day
2.83E-03 wt% (0.55 vol%) H2/day
98.20 wt% (99.43 vol%) H2S/day
3.93E-04 wt% (9.10E-03 vol%) NH3/day

5,040,871.77 kg liquid/day
89.60 wt% n-Dodecane/day
2.84E-02 wt% Dibenzothiophene/day
9.04 wt % Biphenyl/day
1.55E-02 wt% Pyridine/day
S202
8.08E-02 wt% Pentane/day
T=200C
0.15 wt% H2/day
P = 3.4 atm
1.06 wt% H2S/day
(344.64 kPa)
2.12E-02 wt% NH3/day

<5>
Reactor Products
T = 342C
P = 39.5 atm
5,099,816.39 kg reactor products/day
88.73 wt% n-Dodecane/day
0.03 wt% Dibenzothiophene/day
2.01 wt% H2S/day
8.97 wt% Biphenyl/day
0.01 wt% Pyridine/day
0.02 wt% NH3/day
0.08 wt% Pentane/day
0.15 wt% H2/day

H203: Condenser

S201
T = 200C
P = 14.6 atm
(1480 kPa)

<10>
Ultra-Low Sulfur Diesel
4,986,535.39 kg ULSD/day
H204
T = 25C
P = 1 atm

90.60 wt% n-Dodecane/day

2.87E-02 wt% Dibenzothiophene/day
9.14 wt % Biphenyl/day
1.57E-02 wt% Pyridine/day
8.17E-02 wt% Pentane/day
0.15 wt% H2/day
2.14E-05 wt% H2S/day
2.14E-02 wt% NH3/day

Total Out: 5,099,816.39 kg/day

Process Flowsheet Diagram

Flue Gas

1
312
1
4

4.2

4.1

25

200
H2O2

H2O1

P-203-A/B

R2O1

R2O2

200

25

P-202-A/B

S2O1

200

200

5.2

342

39.5

5.1

39.5

P-201-A/B

342

14.6

Cooling water
1

200

S2O2

H2O3

25

6
10
H204

Air

Fuel
gas

Process Equipment Summary

Cooling Water

Designers

H201: Preheater

S201: High Pressure Gas-Liquid Separator

H202: Fired Heater

S202: Low Pressure Gas-Liquid Separator

Bhatia, Rajesh Jr. E.

H203: Condenser

P-201-A/B: Pump 1

Jainar, Stephanie C.

H204: Condenser

P-202-A/B: Pump 2

Portula, Katherine C.

R201: Fixed-bed Reactor

P-203-A/B Pump 3

Rubio, Kevin Alfie R.

Process Flow Scheme

Project: Production of Ultra Low Sulfur Diesel Fuel
Proj. ID Number: PED2016
Completion Date: October 20, 2016

Stream Number
R202: Fixed-bed Reactor

Temp (C)

Pressure (atm)