Академический Документы
Профессиональный Документы
Культура Документы
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
H
kJ
35.849
36.514
37.106
37.644
38.142
38.612
39.065
39.508
39.947
40.386
40.828
41.273
41.720
42.173
42.636
43.108
43.592
44.089
44.599
45.124
45.665
S
J/K
-11.291
-8.877
-6.765
-4.883
-3.170
-1.579
-0.073
1.376
2.790
4.182
5.559
6.926
8.279
9.628
10.985
12.353
13.733
15.129
16.543
17.979
19.439
G
kJ
38.933
38.983
39.022
39.051
39.071
39.083
39.087
39.084
39.073
39.056
39.032
39.000
38.962
38.918
38.866
38.808
38.743
38.670
38.591
38.505
38.411
K
3.583E-008
4.771E-008
6.320E-008
8.325E-008
1.090E-007
1.420E-007
1.839E-007
2.368E-007
3.033E-007
3.865E-007
4.901E-007
6.186E-007
7.773E-007
9.724E-007
1.211E-006
1.503E-006
1.858E-006
2.289E-006
2.810E-006
3.438E-006
4.194E-006
H
kJ
24.615
25.698
26.626
27.435
28.156
28.813
29.428
30.017
30.592
31.160
31.727
32.294
32.861
33.433
34.018
34.619
35.237
35.874
36.533
S
J/K
72.640
76.571
79.878
82.710
85.190
87.414
89.461
91.387
93.236
95.037
96.806
98.548
100.261
101.966
103.684
105.421
107.183
108.975
110.803
G
kJ
4.773
4.400
4.009
3.602
3.182
2.751
2.308
1.856
1.395
0.924
0.444
-0.044
-0.541
-1.047
-1.561
-2.084
-2.615
-3.155
-3.705
K
1.222E-001
1.492E-001
1.821E-001
2.223E-001
2.710E-001
3.297E-001
4.002E-001
4.845E-001
5.853E-001
7.052E-001
8.476E-001
1.016E+000
1.216E+000
1.451E+000
1.728E+000
2.054E+000
2.437E+000
2.886E+000
3.412E+000
95
100
37.217
37.927
112.672
114.590
-4.264
-4.832
4.027E+000
4.747E+000
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
H
kJ
-27.281
-20.430
-19.663
-18.954
-18.285
-17.644
-17.019
-16.403
-15.787
-15.170
-14.546
-13.917
-13.283
-12.639
-11.983
-11.313
-10.627
-9.924
-9.203
-8.462
-7.699
S
J/K
50.148
75.200
77.933
80.417
82.718
84.887
86.965
88.983
90.963
92.920
94.863
96.796
98.715
100.631
102.558
104.498
106.454
108.430
110.429
112.456
114.514
G
kJ
-40.979
-41.347
-41.730
-42.126
-42.534
-42.953
-43.383
-43.823
-44.272
-44.732
-45.202
-45.681
-46.170
-46.668
-47.176
-47.694
-48.221
-48.758
-49.305
-49.862
-50.430
K
6.871E+007
5.826E+007
4.999E+007
4.336E+007
3.798E+007
3.356E+007
2.990E+007
2.685E+007
2.429E+007
2.212E+007
2.028E+007
1.871E+007
1.736E+007
1.620E+007
1.520E+007
1.433E+007
1.358E+007
1.293E+007
1.237E+007
1.189E+007
1.148E+007
65
-82.258
196.245
-148.619
9.105E+022
70
-79.464
204.447
-149.620
5.988E+022
75
-76.646
212.601
-150.663
4.042E+022
80
-73.802
220.713
-151.746
2.797E+022
85
-70.930
228.786
-152.870
1.983E+022
90
95
100
-68.031
-65.102
-62.142
236.826
244.837
252.823
-154.034
-155.238
-156.482
1.438E+022
1.066E+022
8.067E+021
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
-103.218
-99.391
-95.562
-91.734
-87.894
-84.030
-80.140
-76.219
-72.265
326.553
338.490
350.248
361.825
373.266
384.608
395.863
407.045
418.164
-207.111
-208.774
-210.496
-212.276
-214.114
-216.008
-217.960
-219.967
-222.030
1.016E+034
5.616E+033
3.231E+033
1.930E+033
1.195E+033
7.651E+032
5.061E+032
3.453E+032
2.425E+032
90
-68.272
429.233
-224.148
1.753E+032
95
-64.239
440.264
-226.322
1.301E+032
100
-60.160
451.270
-228.551
9.906E+031
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
-126.298
-121.477
-116.620
-111.725
-106.787
-101.803
-96.768
-91.679
517.604
531.755
545.805
559.766
573.650
587.471
601.240
614.971
-301.325
-303.949
-306.643
-309.407
-312.240
-315.143
-318.115
-321.155
3.549E+046
1.867E+046
1.025E+046
5.866E+045
3.489E+045
2.154E+045
1.378E+045
9.120E+044
Log(K)
-7.446
-35.333
-7.199
-7.080
-6.962
-6.848
-6.736
-6.626
-6.518
-6.413
-6.310
-6.209
-6.109
-6.012
-5.917
-5.823
-5.731
-5.640
-5.551
-5.464
-5.377
Log(K)
-0.913
-0.826
-0.740
-0.653
-0.567
-0.482
-0.398
-0.315
-0.233
-0.152
-0.072
0.007
0.085
0.162
0.238
0.313
0.387
0.460
0.533
[H(+a)]
1.00E+00
3.16E-01
1.00E-01
3.16E-02
1.00E-02
3.16E-03
1.00E-03
3.16E-04
1.00E-04
3.16E-05
1.00E-05
3.16E-06
1.00E-06
3.16E-07
1.00E-07
3.16E-08
1.00E-08
3.16E-09
1.00E-09
3.16E-10
1.00E-10
3.16E-11
1.00E-11
3.16E-12
1.00E-12
3.16E-13
1.00E-13
3.16E-14
1.00E-14
3.16E-15
1.00E-15
3.16E-16
1.00E-16
3.16E-17
1.00E-17
3.16E-18
1.00E-18
3.16E-19
1.00E-19
3.16E-20
1.00E-20
pH
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
11.5
12.0
12.5
13.0
13.5
14.0
14.5
15.0
15.5
16.0
16.5
17.0
17.5
18.0
18.5
19.0
19.5
20.0
H2CO3(a)/HCO3(-a)/CO3(-2a)
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
Diagrama de
100%
95%
90%
85%
Diagrama de
100%
0.605
0.676
95%
90%
85%
Log(K)
7.837
7.765
7.699
7.637
7.580
7.526
7.476
7.429
7.385
7.345
7.307
7.272
7.240
7.209
7.182
7.156
7.133
7.112
7.093
7.075
7.060
80%
75%
70%
65%
60%
55%
50%
% Concentracin
45%
40%
35%
30%
25%
20%
15%
10%
5%
0%
0
3H2O
Log(K)
Diagrama d
26.679
26.279
25.903
25.549
25.215
24.900
24.603
24.324
24.061
23.813
23.579
23.360
23.153
22.959
22.777
22.607
0
0
-5
-10
-15
-20
-25
log[CuT]
-30
-35
-40
-45
10
log[CuT]
-30
-35
22.447
-40
22.297
22.158
22.028
21.907
-45
-50
H2O
-55
Log(K)
-60
37.304
36.831
36.389
35.976
35.591
35.230
34.893
34.577
34.282
pH
Diagrama
0
34.007
33.749
33.509
33.286
33.077
32.884
32.704
32.538
32.385
1.000E+001
32.244
1.000E-023
32.114
31.996
4H2O
Log(K)
1.000E-003
1.000E-007
1.000E-011
1.000E-015
1.000E-019
log[CuT]
1.000E-027
1.000E-031
1.000E-035
1.000E-039
52.423
51.778
51.175
50.609
50.078
49.579
49.111
48.671
48.259
47.871
47.508
47.167
46.849
1.000E-043
1.000E-047
1.000E-051
1.000E-055
1.000E-059
46.550
46.271
46.011
45.768
45.543
45.333
45.139
44.960
[Cu(+2a)]
7.043E+009
7.043E+008
7.043E+007
7.043E+006
7.043E+005
7.044E+004
7.046E+003
7.053E+002
7.073E+001
7.139E+000
7.346E-001
8.002E-002
1.008E-002
1.664E-003
3.738E-004
1.030E-004
3.104E-005
9.663E-006
3.040E-006
9.600E-007
3.034E-007
9.593E-008
3.033E-008
9.593E-009
3.033E-009
9.592E-010
3.033E-010
9.592E-011
3.033E-011
9.592E-012
3.033E-012
9.592E-013
3.033E-013
9.592E-014
3.033E-014
9.592E-015
3.033E-015
9.592E-016
3.033E-016
9.592E-017
3.033E-017
[CuOH(+a)]
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
2.980E-005
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
1.2587130E-022 2.63494657E-047
1.2587130E-021 2.63494657E-045
1.2587130E-020 2.63494657E-043
1.2587130E-019 2.63494657E-041
1.2587130E-018 2.63494657E-039
1.2587130E-017 2.63494657E-037
1.2587131E-016 2.63494657E-035
1.2587132E-015 2.63494657E-033
1.2587136E-014 2.63494657E-031
1.2587149E-013 2.63494657E-029
1.2587189E-012 2.63494657E-027
1.2587316E-011 2.63494657E-025
1.2587719E-010 2.63494657E-023
1.2588991E-009 2.63494657E-021
1.2593016E-008 2.63494657E-019
1.2605743E-007 2.63494657E-017
1.2645991E-006 2.63494657E-015
1.2773264E-005 2.63494657E-013
0.0001317574 2.63494657E-011
0.0014448465 2.63494657E-009
0.0184731867 2.63494657E-007
0.3120047533 2.63494657E-005
7.1447695854
0.0026349466
198.72058221
0.2634946575
6011.92787479 26.349465747
187392.165104 2634.946574696
5898643.70373 263494.6574696
186259323.393 26349465.74696
5887315286.63 2634946574.696
186146039222 263494657469.6
5886182444917 26349465746958
1.861347E+014 2.6349466E+015
5.886069E+015 2.6349466E+017
1.861336E+017 2.6349466E+019
5.886058E+018 2.6349466E+021
1.861335E+020 2.6349466E+023
5.886057E+021 2.6349466E+025
1.861335E+023 2.6349466E+027
5.886057E+024 2.6349466E+029
1.861335E+026 2.6349466E+031
5.886057E+027 2.6349466E+033
Diagrama de Predominancia
[CuT]
7.043E+009
7.043E+008
7.043E+007
7.043E+006
7.043E+005
7.044E+004
7.046E+003
7.053E+002
7.073E+001
7.139E+000
7.347E-001
8.005E-002
1.011E-002
1.693E-003
4.036E-004
1.329E-004
6.210E-005
5.223E-005
1.646E-004
1.476E-003
1.850E-002
3.121E-001
7.147E+000
1.990E+002
6.038E+003
1.900E+005
6.162E+006
2.126E+008
8.522E+009
4.496E+011
3.224E+013
2.821E+015
2.694E+017
2.654E+019
2.641E+021
2.637E+023
2.636E+025
2.635E+027
2.635E+029
2.635E+031
2.635E+033
Diagrama de Predominancia
[Cu(+2a)]/[CuT]
[CuOH(+a)]/[CuT]
[Cu(OH)3(-a)]/[CuT]
[Cu(OH)4(-2a)]/[CuT]
10 11 12 13 14 15 16 17 18 19 20
pH
Diagrama de Bjerrum
4
10
11
12
13
14
15
16
17
18
19
20
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
pH
Diagrama de Bjerrum
3
10
11
12
13
14
15
16
17
18
19
20
[Cu(+2a)]
[CuOH(+a)]
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
pH
[Cu(+2a)]/[CuT]
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
9.996E-001
9.971E-001
9.824E-001
9.261E-001
7.748E-001
4.998E-001
1.850E-001
1.847E-002
6.505E-004
1.640E-005
3.074E-007
4.244E-009
4.821E-011
5.024E-013
5.048E-015
4.923E-017
4.512E-019
3.559E-021
2.133E-023
9.410E-026
3.400E-028
1.126E-030
3.615E-033
1.149E-035
3.638E-038
1.151E-040
3.640E-043
1.151E-045
3.640E-048
1.151E-050
[CuOH(+a)]/[CuT]
4.231E-015
4.231E-014
4.231E-013
4.231E-012
4.231E-011
4.230E-010
4.229E-009
4.225E-008
4.213E-007
4.174E-006
4.056E-005
3.722E-004
2.948E-003
1.760E-002
7.383E-002
2.242E-001
4.798E-001
5.705E-001
1.810E-001
2.019E-002
1.610E-003
9.549E-005
4.169E-006
1.497E-007
4.935E-009
1.568E-010
4.836E-012
1.402E-013
3.496E-015
6.627E-017
9.244E-019
1.056E-020
1.106E-022
1.123E-024
1.128E-026
1.130E-028
1.131E-030
1.131E-032
1.131E-034
1.131E-036
1.131E-038
[Cu(OH)3(-a)]/[CuT]
1.787E-032
1.787E-030
1.787E-028
1.787E-026
1.787E-024
1.787E-022
1.786E-020
1.785E-018
1.780E-016
1.763E-014
1.713E-012
1.572E-010
1.246E-008
7.434E-007
3.120E-005
9.486E-004
2.036E-002
2.445E-001
8.005E-001
9.792E-001
9.984E-001
9.998E-001
9.996E-001
9.987E-001
9.956E-001
9.861E-001
9.572E-001
8.761E-001
6.908E-001
4.140E-001
1.826E-001
6.598E-002
2.185E-002
7.014E-003
2.229E-003
7.059E-004
2.233E-004
7.064E-005
2.234E-005
7.064E-006
2.234E-006
[Cu(OH)4(-2a)]/[CuT]
3.741E-057
3.741E-054
3.741E-051
3.741E-048
3.741E-045
3.741E-042
3.740E-039
3.736E-036
3.725E-033
3.691E-030
3.587E-027
3.292E-024
2.607E-021
1.556E-018
6.529E-016
1.983E-013
4.243E-011
5.045E-009
1.601E-007
1.786E-006
1.424E-005
8.444E-005
3.687E-004
1.324E-003
4.364E-003
1.387E-002
4.276E-002
1.239E-001
3.092E-001
5.860E-001
8.174E-001
9.340E-001
9.781E-001
9.930E-001
9.978E-001
9.993E-001
9.998E-001
9.999E-001
1.000E+000
1.000E+000
1.000E+000
Diagrama de So
0
40
35
30
10
11
12
Diagrama de So
0
10
11
12
40
35
30
25
20
15
10
5
[Cu(+2a)]/[CuT]
[CuOH(+a)]/[CuT]
[Cu(OH)3(-a)]/[CuT]
log[CuT]
[Cu(OH)4(-2a)]/[CuT]
-5
-10
-15
-20
-25
-30
-35
-40
-45
-50
-55
pH
Diagrama de So
0
35
30
25
20
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
log[CuT]
15
10
10
11
12
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[CuT]
log[Cu(OH)4(-2a)]
15
10
-5
-10
pH
Diagrama de So
20
-3
[Cu(+2a)]
[CuOH(+a)]
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
log[CuT]
-4
-5
pH
log[CuT]
9.8477527993
8.8477532038
7.8477544828
6.8477585274
5.8477713171
4.8478117595
3.847939626
2.8483437389
1.8496192997
0.8536296124
-0.1339161755
-1.0966307693
-1.9954153638
-2.7712561113
-3.3940698512
-3.8765024053
-4.2069026831
-4.2820466039
-3.7835815791
-2.8310293253
-1.7327449083
-0.505760509
0.8541501756
2.2988183897
3.7809130586
5.2788155674
6.7897314455
8.3275812141
9.9305548745
11.6528656121
13.5083364074
15.4504155999
17.4303665201
19.4238289009
21.4217408779
23.4210784927
25.4208688178
27.4208024916
29.4207815154
31.4207748819
33.4207727842
log[Cu(+2a)]
9.8477527993
8.8477532038
7.8477544828
6.8477585274
5.8477713171
4.8478117593
3.8479396241
2.8483437206
1.8496191168
0.8536277996
-0.133933791
-1.0967924585
-1.9966977751
-2.7789668004
-3.4273955088
-3.9872988938
-4.5081009758
-5.0148920815
-5.5170619076
-6.0177503292
-6.5179682545
-7.0180371913
-7.5180589933
-8.0180658879
-8.5180680682
-9.0180687577
-9.5180689757
-10.0180690446
-10.5180690665
-11.0180690733
-11.5180690755
-12.0180690762
-12.5180690764
-13.0180690765
-13.5180690765
-14.0180690765
-14.5180690765
-15.0180690765
-15.5180690765
-16.0180690765
-16.5180690765
log[CuOH(+a)]
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
-4.5258152172
grama de Solubilidad
10
11
12
13
14
15
16
17
18
19
20
log[Cu(OH)3(-a)]
-21.9000732783
-20.9000732783
-19.9000732781
-18.9000732777
-17.9000732763
-16.9000732719
-15.900073258
-14.9000732141
-13.9000730752
-12.9000726361
-11.9000712475
-10.9000668562
-9.9000529701
-8.9000090613
-7.8998702388
-6.8994315354
-5.8980471425
-4.8936981263
-3.8802251231
-2.8401783006
-1.7334581807
-0.5058387896
0.8539882276
2.2982428509
3.7790137617
5.272751429
6.7707521642
8.270118021
9.7699172944
11.2698537998
12.7698337191
14.2698273689
15.7698253607
17.2698247257
18.7698245249
20.2698244614
21.7698244413
23.2698244349
24.7698244329
26.2698244323
27.7698244321
log[Cu(OH)4(-2a)]
-46.579228186
-44.579228186
-42.579228186
-40.579228186
-38.579228186
-36.579228186
-34.579228186
-32.579228186
-30.579228186
-28.579228186
-26.579228186
-24.579228186
-22.579228186
-20.579228186
-18.579228186
-16.579228186
-14.579228186
-12.579228186
-10.579228186
-8.579228186
-6.579228186
-4.579228186
-2.579228186
-0.579228186
1.420771814
3.420771814
5.420771814
7.420771814
9.420771814
11.420771814
13.420771814
15.420771814
17.420771814
19.420771814
21.420771814
23.420771814
25.420771814
27.420771814
29.420771814
31.420771814
33.420771814
grama de Solubilidad
10
11
12
13
14
15
16
17
18
19
20
log[CuT]
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
ECA A1, A2 y A3
pH
grama de Solubilidad
7
10
11
12
13
14
15
16
17
18
19
20
log[CuT]
ECA A1, A2 y A3
log[CuT]
ECA A1, A2 y A3
pH
grama de Solubilidad
8
log[CuT]
ECA A1, A2 y A3
pH
log([Cu(+2a)]/[CuT])
-1.832222186451E-015
-1.837043823784E-014
-1.837525987518E-013
-1.837429554775E-012
-1.837371695162E-011
-1.837203902532E-010
-1.836662918318E-009
-1.834954772455E-008
-0.000000183
-1.812760335461E-006
-1.761546434202E-005
-0.0001616892
-0.0012824113
-0.0077106891
-0.0333256576
-0.1107964885
-0.3011982928
-0.7328454777
-1.7334803285
-3.1867210039
-4.7852233462
-6.5122766823
-8.3722091689
-10.3168842776
-12.2989811268
-14.2968843251
-16.3078004212
-18.3456502587
-20.448623941
-22.6709346854
-25.0264054829
-27.4684846761
-29.9484355965
-32.4418979774
-34.9398099544
-37.4391475693
-39.9389378943
-42.4388715682
-44.9388505919
-47.4388439584
-49.9388418607
log([CuOH(+a)]/[CuT])
-14.3735680166
-13.373568421
-12.3735697
-11.3735737446
-10.3735865343
-9.3736269767
-8.3737548432
-7.3741589561
-6.3754345169
-5.3794448296
-4.3918990417
-3.4291844479
-2.5303998534
-1.7545591059
-1.1317453661
-0.6493128119
-0.3189125341
-0.2437686134
-0.7422336381
-1.6947858919
-2.7930703089
-4.0200547082
-5.3799653928
-6.8246336069
-8.3067282758
-9.8046307846
-11.3155466627
-12.8533964313
-14.4563700917
-16.1786808293
-18.0341516246
-19.9762308171
-21.9561817373
-23.9496441181
-25.9475560951
-27.9468937099
-29.946684035
-31.9466177089
-33.9465967326
-35.9465900991
-37.9465880014
log([Cu(OH)3(-a)]/[CuT])
-31.7478260776
-29.7478264821
-27.7478277609
-25.747831805
-23.7478445934
-21.7478850314
-19.748012884
-17.748416953
-15.749692375
-13.7537022485
-11.766155072
-9.8034360869
-7.9046376063
-6.1287529501
-4.5058003877
-3.02292913
-1.6911444594
-0.6116515224
-0.0966435439
-0.0091489753
-0.0007132725
-7.82806227519245E-005
-0.000161948
-0.0005755388
-0.0018992969
-0.0060641384
-0.0189792813
-0.0574631931
-0.1606375801
-0.3830118122
-0.7385026883
-1.1805882311
-1.6605411593
-2.1540041752
-2.651916353
-3.1512540314
-3.6510443765
-4.1509780567
-4.6509570825
-5.1509504496
-5.6509483521
ECA Cu
A1
mg/L
mg/L
A2
A3
ECA Mn
mol/L
mol/L
A1
A2
A3
ECA Mn
log[mol/L]
log[mol/L]
A1
A2
A3
log([Cu(OH)4(-2a)]/[CuT])
-56.4269809853
-53.4269813898
-50.4269826688
-47.4269867133
-44.4269995031
-41.4270399455
-38.4271678119
-35.4275719249
-32.4288474857
-29.4328577983
-26.4453120105
-23.4825974166
-20.5838128221
-17.8079720747
-15.1851583348
-12.7027257807
-10.3723255029
-8.2971815821
-6.7956466069
-5.7481988607
-4.8464832777
-4.073467677
-3.4333783616
-2.8780465757
-2.3601412446
-1.8580437534
-1.3689596315
-0.9068094
-0.5097830605
-0.232093798
-0.0875645934
-0.0296437859
-0.009594706
-0.0030570869
-0.0009690639
-0.0003066787
-9.70037303678148E-005
-3.06776150350001E-005
-9.70134790919395E-006
-3.0678590016438E-006
-9.70144541045492E-007
2
2
3.15E-05
3.15E-05
3.15E-05
-4.50202
-4.50202
-4.50202
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
H
kJ
24.615
25.698
26.626
27.435
28.156
28.813
29.428
30.017
30.592
31.160
31.727
32.294
32.861
S
J/K
72.640
76.571
79.878
82.710
85.190
87.414
89.461
91.387
93.236
95.037
96.806
98.548
100.261
G
kJ
4.773
4.400
4.009
3.602
3.182
2.751
2.308
1.856
1.395
0.924
0.444
-0.044
-0.541
K
1.222E-001
1.492E-001
1.821E-001
2.223E-001
2.710E-001
3.297E-001
4.002E-001
4.845E-001
5.853E-001
7.052E-001
8.476E-001
1.016E+000
1.216E+000
65
70
75
80
85
90
95
100
33.433
34.018
34.619
35.237
35.874
36.533
37.217
37.927
101.966
103.684
105.421
107.183
108.975
110.803
112.672
114.590
-1.047
-1.561
-2.084
-2.615
-3.155
-3.705
-4.264
-4.832
1.451E+000
1.728E+000
2.054E+000
2.437E+000
2.886E+000
3.412E+000
4.027E+000
4.747E+000
T
C
0
5
10
15
H
kJ
-27.281
-20.430
-19.663
-18.954
-18.285
-17.644
-17.019
-16.403
-15.787
-15.170
-14.546
-13.917
-13.283
-12.639
-11.983
-11.313
-10.627
-9.924
-9.203
-8.462
-7.699
S
J/K
50.148
75.200
77.933
80.417
82.718
84.887
86.965
88.983
90.963
92.920
94.863
96.796
98.715
100.631
102.558
104.498
106.454
108.430
110.429
112.456
114.514
G
kJ
-40.979
-41.347
-41.730
-42.126
-42.534
-42.953
-43.383
-43.823
-44.272
-44.732
-45.202
-45.681
-46.170
-46.668
-47.176
-47.694
-48.221
-48.758
-49.305
-49.862
-50.430
K
6.871E+007
5.826E+007
4.999E+007
4.336E+007
3.798E+007
3.356E+007
2.990E+007
2.685E+007
2.429E+007
2.212E+007
2.028E+007
1.871E+007
1.736E+007
1.620E+007
1.520E+007
1.433E+007
1.358E+007
1.293E+007
1.237E+007
1.189E+007
1.148E+007
20
25
30
-106.635
-103.960
-101.289
118.925
127.973
136.858
-141.498
-142.115
-142.777
1.640E+025
7.945E+024
4.013E+024
35
-98.613
145.612
-143.484
2.109E+024
40
-95.928
154.257
-144.233
1.150E+024
45
-93.228
162.810
-145.026
6.497E+023
50
-90.512
171.281
-145.861
3.796E+023
55
-87.778
179.675
-146.739
2.289E+023
60
65
70
75
80
85
90
95
100
-85.028
-82.258
-79.464
-76.646
-73.802
-70.930
-68.031
-65.102
-62.142
187.992
196.245
204.447
212.601
220.713
228.786
236.826
244.837
252.823
-147.658
-148.619
-149.620
-150.663
-151.746
-152.870
-154.034
-155.238
-156.482
1.423E+023
9.105E+022
5.988E+022
4.042E+022
2.797E+022
1.983E+022
1.438E+022
1.066E+022
8.067E+021
T
C
0
5
10
15
20
25
30
35
40
45
50
-99.391
338.490
-208.774
5.616E+033
55
-95.562
350.248
-210.496
3.231E+033
60
65
70
75
80
85
90
95
-91.734
-87.894
-84.030
-80.140
-76.219
-72.265
-68.272
-64.239
361.825
373.266
384.608
395.863
407.045
418.164
429.233
440.264
-212.276
-214.114
-216.008
-217.960
-219.967
-222.030
-224.148
-226.322
1.930E+033
1.195E+033
7.651E+032
5.061E+032
3.453E+032
2.425E+032
1.753E+032
1.301E+032
100
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
-60.160
451.270
-228.551
9.906E+031
+a)
Log(K)
-7.446
-7.321
-7.199
-7.080
-6.962
-6.848
-6.736
-6.626
-6.518
-6.413
-6.310
-6.209
-6.109
-6.012
-5.917
-5.823
-5.731
-5.640
-5.551
-5.464
-5.377
a)
Log(K)
-0.913
-0.826
-0.740
-0.653
-0.567
-0.482
-0.398
-0.315
-0.233
-0.152
-0.072
0.007
0.085
[H(+a)]
1.00E+00
3.16E-01
1.00E-01
3.16E-02
1.00E-02
3.16E-03
1.00E-03
3.16E-04
1.00E-04
3.16E-05
1.00E-05
3.16E-06
1.00E-06
3.16E-07
1.00E-07
3.16E-08
1.00E-08
3.16E-09
1.00E-09
3.16E-10
1.00E-10
3.16E-11
1.00E-11
3.16E-12
1.00E-12
3.16E-13
1.00E-13
3.16E-14
1.00E-14
3.16E-15
1.00E-15
3.16E-16
1.00E-16
3.16E-17
1.00E-17
3.16E-18
1.00E-18
3.16E-19
1.00E-19
3.16E-20
1.00E-20
pH
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
11.5
12.0
12.5
13.0
13.5
14.0
14.5
15.0
15.5
16.0
16.5
17.0
17.5
18.0
18.5
19.0
19.5
20.0
0.162
0.238
0.313
0.387
0.460
0.533
0.605
0.676
Diagrama
100%
95%
90%
85%
2O
80%
Log(K)
7.837
7.765
7.699
7.637
7.580
7.526
7.476
7.429
7.385
7.345
7.307
7.272
7.240
7.209
7.182
7.156
7.133
7.112
7.093
7.075
7.060
75%
70%
65%
60%
55%
50%
% Concentracin
45%
40%
35%
30%
25%
20%
15%
10%
5%
0%
0
Diagr
+ 3H2O
Log(K)
0
26.679
26.279
25.903
25.549
0
-5
-10
-15
-20
0
-5
-10
25.215
24.900
24.603
-15
24.324
-20
24.061
-25
23.813
23.579
23.360
log[CuT]
-30
-35
23.153
22.959
22.777
22.607
22.447
22.297
22.158
22.028
21.907
-40
-45
-50
-55
-60
-65
+ 3H2O
Log(K)
37.304
36.831
36.389
35.976
35.591
35.230
34.893
34.577
34.282
34.007
Diagr
0
1.000E+001
1.000E-004
1.000E-009
33.749
1.000E-014
33.509
33.286
33.077
32.884
32.704
32.538
32.385
32.244
32.114
1.000E-019
1.000E-024
log[CuT]
1.000E-029
1.000E-034
1.000E-039
1.000E-044
1.000E-049
log[CuT]
1.000E-029
1.000E-034
31.996
1.000E-039
1.000E-044
1.000E-049
3 + 4H2O
Log(K)
1.000E-054
52.423
51.778
51.175
50.609
50.078
49.579
49.111
48.671
48.259
47.871
47.508
47.167
46.849
46.550
46.271
46.011
45.768
45.543
45.333
45.139
44.960
1.000E-059
1.000E-064
H2CO3(a)/HCO3(-a)/CO3(-2a)
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
[Cu(+2a)]
2.096E+010
2.096E+009
2.096E+008
2.096E+007
2.096E+006
2.096E+005
2.097E+004
2.098E+003
2.103E+002
2.117E+001
2.163E+000
2.308E-001
2.766E-002
4.216E-003
8.800E-004
2.330E-004
6.914E-005
2.141E-005
6.725E-006
2.122E-006
6.707E-007
2.120E-007
6.705E-008
2.120E-008
6.705E-009
2.120E-009
6.705E-010
2.120E-010
6.705E-011
2.120E-011
6.705E-012
2.120E-012
6.705E-013
2.120E-013
6.705E-014
2.120E-014
6.705E-015
2.120E-015
6.705E-016
2.120E-016
6.705E-017
[CuOH(+a)]
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
1.717E-005
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
5.2581099E-024 1.66583170E-049
5.2581099E-023 1.66583170E-047
5.2581099E-022 1.66583170E-045
5.2581099E-021 1.66583170E-043
5.2581099E-020 1.66583170E-041
5.2581099E-019 1.66583170E-039
5.2581100E-018 1.66583170E-037
5.2581103E-017 1.66583170E-035
5.2581114E-016 1.66583170E-033
5.2581145E-015 1.66583170E-031
5.2581246E-014 1.66583170E-029
5.2581566E-013 1.66583170E-027
5.2582576E-012 1.66583170E-025
5.2585771E-011 1.66583170E-023
5.2595872E-010 1.66583170E-021
5.2627817E-009 1.66583170E-019
5.2728836E-008 1.66583170E-017
5.3048286E-007 1.66583170E-015
5.4058475E-006 1.66583170E-013
0.000057253 1.66583170E-011
0.0006735486 1.66583170E-009
0.0099299828 1.66583170E-007
0.200318692 1.66583170E-005
5.1976838944
0.0016658317
152.995703124 0.1665831701
4724.45400578 16.658317011
148263.404238 1665.831701099
4677131.01692 166583.1701099
147790174.35 16658317.01099
4672398718.04 1665831701.099
147742851361 166583170109.9
4671925488150 16658317010990
1.477381E+014 1.6658317E+015
4.671878E+015 1.6658317E+017
1.477376E+017 1.6658317E+019
4.671873E+018 1.6658317E+021
1.477376E+020 1.6658317E+023
4.671873E+021 1.6658317E+025
1.477376E+023 1.6658317E+027
4.671873E+024 1.6658317E+029
1.477376E+026 1.6658317E+031
Diagrama de Predominancia
100%
95%
90%
85%
80%
75%
70%
65%
60%
[Cu(
55%
[CuO
50%
racin
[Cu(
45%
[Cu(
40%
35%
30%
25%
20%
15%
10%
5%
0%
0
10 11 12 13 14 15 16 17 18 19 20
pH
Diagrama de Bjerrum
0
0
-5
-10
-15
-20
10
11
12
13
14
15
16
17
18
19
20
0
-5
-10
-15
-20
-25
lo
lo
-30
lo
lo
-35
-40
-45
-50
-55
-60
-65
pH
Diagrama de Bjerrum
0
1.000E+001
1.000E-004
1.000E-009
1.000E-014
1.000E-019
1.000E-024
1.000E-029
1.000E-034
1.000E-039
1.000E-044
1.000E-049
10
11
12
13
14
15
16
17
18
19
20
1.000E-029
1.000E-034
1.000E-039
1.000E-044
1.000E-049
1.000E-054
1.000E-059
1.000E-064
pH
[CuT]
2.096E+010
2.096E+009
2.096E+008
2.096E+007
2.096E+006
2.096E+005
2.097E+004
2.098E+003
2.103E+002
2.117E+001
2.163E+000
2.308E-001
2.768E-002
4.233E-003
8.972E-004
2.501E-004
8.636E-005
3.911E-005
2.930E-005
7.654E-005
6.914E-004
9.948E-003
2.004E-001
5.199E+000
1.532E+002
4.741E+003
1.499E+005
4.844E+006
1.644E+008
6.338E+009
3.143E+011
2.133E+013
1.814E+015
1.713E+017
1.681E+019
1.671E+021
1.667E+023
1.666E+025
1.666E+027
1.666E+029
1.666E+031
[Cu(+2a)]/[CuT]
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
9.999E-001
9.994E-001
9.959E-001
9.809E-001
9.314E-001
8.006E-001
5.475E-001
2.296E-001
2.773E-002
9.700E-004
2.132E-005
3.346E-007
4.078E-009
4.377E-011
4.472E-013
4.472E-015
4.377E-017
4.077E-019
3.345E-021
2.133E-023
9.940E-026
3.697E-028
1.238E-030
3.989E-033
1.269E-035
4.021E-038
1.272E-040
4.024E-043
1.273E-045
4.025E-048
[CuOH(+a)]/[CuT]
8.190E-016
8.190E-015
8.190E-014
8.190E-013
8.190E-012
8.189E-011
8.187E-010
8.182E-009
8.164E-008
8.108E-007
7.936E-006
7.437E-005
6.201E-004
4.055E-003
1.913E-002
6.862E-002
1.988E-001
4.389E-001
5.859E-001
2.243E-001
2.483E-002
1.726E-003
8.567E-005
3.301E-006
1.121E-007
3.620E-009
1.145E-010
3.544E-012
1.044E-013
2.708E-015
5.461E-017
8.047E-019
9.465E-021
1.002E-022
1.021E-024
1.028E-026
1.030E-028
1.030E-030
1.030E-032
1.030E-034
1.030E-036
[Cu(OH)3(-a)]/[CuT]
2.509E-034
2.509E-032
2.509E-030
2.509E-028
2.509E-026
2.509E-024
2.508E-022
2.506E-020
2.501E-018
2.484E-016
2.431E-014
2.278E-012
1.900E-010
1.242E-008
5.862E-007
2.104E-005
6.106E-004
1.356E-002
1.845E-001
7.480E-001
9.742E-001
9.982E-001
9.998E-001
9.997E-001
9.989E-001
9.965E-001
9.889E-001
9.656E-001
8.987E-001
7.372E-001
4.700E-001
2.190E-001
8.146E-002
2.728E-002
8.791E-003
2.797E-003
8.861E-004
2.804E-004
8.868E-005
2.804E-005
8.869E-006
Diagram
0
35
30
25
20
15
10
5
[Cu(+2a)]/[CuT]
[CuOH(+a)]/[CuT]
[Cu(OH)3(-a)]/[CuT]
[Cu(OH)4(-2a)]/[CuT]
log[CuT]
-5
-10
-15
-20
-25
-30
-35
-40
-45
-50
8 19 20
18
40
-55
Diagrama
19
20
0
35
30
25
35
30
25
20
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[CuT]
15
log[Cu(OH)4(-2a)]
10
-5
-10
Diagrama
18
19
20
8
-3
[Cu(+2a)]
[CuOH(+a)]
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
log[CuT]
-4
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
log[CuT]
-4
-5
[Cu(OH)4(-2a)]/[CuT]
7.948E-060
7.948E-057
7.948E-054
7.948E-051
7.948E-048
7.947E-045
7.946E-042
7.940E-039
7.923E-036
7.869E-033
7.702E-030
7.218E-027
6.018E-024
3.935E-021
1.857E-018
6.659E-016
1.929E-013
4.260E-011
5.686E-009
2.176E-007
2.409E-006
1.675E-005
8.315E-005
3.204E-004
1.088E-003
3.514E-003
1.111E-002
3.439E-002
1.013E-001
2.628E-001
5.300E-001
7.810E-001
9.185E-001
9.727E-001
9.912E-001
9.972E-001
9.991E-001
9.997E-001
9.999E-001
1.000E+000
1.000E+000
log[CuT]
10.3213619556
9.321362256
8.3213632059
7.3213662099
6.3213757092
5.3214057474
4.3215007228
3.3218009272
2.3227489152
1.3257333871
0.3350404855
-0.6367557489
-1.5578298408
-2.3733335476
-3.0471092352
-3.6018091741
-4.0636928405
-4.4077480235
-4.533184492
-4.1161092709
-3.1602793751
-2.0022848925
-0.6982050552
0.7159504661
2.1851518892
3.675880246
5.1758863278
6.6851785088
8.2160298936
9.8019680234
11.4973803356
13.3289957929
15.25853428
17.2336433825
19.2254657716
21.2228474093
23.2220161145
25.2217529046
27.2216696371
29.2216433023
31.2216349741
log[Cu(+2a)]
10.3213619556
9.321362256
8.3213632059
7.3213662099
6.3213757092
5.3214057473
4.3215007225
3.3218009237
2.3227488798
1.325733035
0.3350370388
-0.636788049
-1.5580992404
-2.3750981591
-3.0554988655
-3.6326925455
-4.1602642133
-4.6693604549
-5.1722770458
-5.6732034441
-6.1734968087
-6.67358962
-7.1736189737
-7.6736282565
-8.1736311921
-8.6736321204
-9.1736324139
-9.6736325067
-10.1736325361
-10.6736325454
-11.1736325483
-11.6736325492
-12.1736325495
-12.6736325496
-13.1736325497
-13.6736325497
-14.1736325497
-14.6736325497
-15.1736325497
-15.6736325497
-16.1736325497
log[CuOH(+a)]
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
-4.7653520957
log[Cu(OH)3(-a)]
-23.2791703431
-22.2791703431
-21.279170343
-20.2791703427
-19.2791703419
-18.2791703393
-17.2791703309
-16.2791703045
-15.2791702211
-14.2791699573
-13.2791691229
-12.2791664844
-11.2791581409
-10.2791317574
-9.2790483362
-8.2787846403
-7.277951813
-6.2753286435
-5.2671362127
-4.2422019669
-3.1716310747
-2.0030515046
-0.6982785243
0.7158098636
2.1846792339
3.6743516253
5.1710339676
6.6699795356
8.1696455615
9.6695398961
11.1695064764
12.6694959077
14.1694925655
15.6694915086
17.1694911744
18.6694910687
20.1694910352
21.6694910247
23.1694910213
24.6694910203
26.1694910199
Diagrama de Solubilidad
1
10
11
12
13
14
15
16
17
18
19
20
log[CuT]
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)
log[Cu(OH)4(-2a
ECA A1, A2 y A3
pH
Diagrama de Solubilidad
1
10
11
12
13
14
15
16
17
18
19
20
log[CuT]
ECA A1, A2 y A
pH
Diagrama de Solubilidad
9
10
log[CuT]
ECA A1, A2 y A
ECA A1, A2 y A
pH
log[Cu(OH)4(-2a)]
-48.7783688775
-46.7783688775
-44.7783688775
-42.7783688775
-40.7783688775
-38.7783688775
-36.7783688775
-34.7783688775
-32.7783688775
-30.7783688775
-28.7783688775
-26.7783688775
-24.7783688775
-22.7783688775
-20.7783688775
-18.7783688775
-16.7783688775
-14.7783688775
-12.7783688775
-10.7783688775
-8.7783688775
-6.7783688775
-4.7783688775
-2.7783688775
-0.7783688775
1.2216311225
3.2216311225
5.2216311225
7.2216311225
9.2216311225
11.2216311225
13.2216311225
15.2216311225
17.2216311225
19.2216311225
21.2216311225
23.2216311225
25.2216311225
27.2216311225
29.2216311225
31.2216311225
log([Cu(+2a)]/[CuT])
-3.375146132937E-016
-3.568011626247E-015
-3.558368351582E-014
-3.556921860383E-013
-3.556777211276E-012
-3.556526486266E-011
-3.555752614784E-010
-3.553295183965E-009
-3.545547584241E-008
-3.521267388317E-007
-3.446620404280E-006
-3.230011940039E-005
-0.0002693996
-0.0017646115
-0.0083896302
-0.0308833715
-0.0965713728
-0.2616124314
-0.6390925538
-1.5570941732
-3.0132174336
-4.6713047275
-6.4754139185
-8.3895787226
-10.3587830813
-12.3495123663
-14.3495187417
-16.3588110156
-18.3896624297
-20.4756005688
-22.6710128839
-25.0026283421
-27.4321668296
-29.9072759322
-32.3990983213
-34.8964799589
-37.3956486642
-39.8953854543
-42.3953021868
-44.8952758519
-47.3952675238
log([CuOH(+a)]/[CuT])
-15.0867140513
-14.0867143517
-13.0867153016
-12.0867183056
-11.0867278049
-10.0867578431
-9.0868528186
-8.0871530229
-7.0881010109
-6.0910854829
-5.1003925812
-4.1285963468
-3.2075222549
-2.3920185481
-1.7182428605
-1.1635429217
-0.7016592552
-0.3576040722
-0.2321676037
-0.6492428248
-1.6050727206
-2.7630672032
-4.0671470405
-5.4813025618
-6.950503985
-8.4412323417
-9.9412384235
-11.4505306045
-12.9813819894
-14.5673201191
-16.2627324313
-18.0943478886
-20.0238863758
-21.9989954783
-23.9908178673
-25.988199505
-27.9873682103
-29.9871050003
-31.9870217328
-33.986995398
-35.9869870699
ECA Cu
mg/L
mg/L
ECA Mn
mol/L
mol/L
ECA Mn
log[mol/L]
log[mol/L]
log[CuT]
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
ECA A1, A2 y A3
log[CuT]
ECA A1, A2 y A3
log[CuT]
ECA A1, A2 y A3
ECA A1, A2 y A3
log([Cu(OH)3(-a)]/[CuT])
log([Cu(OH)4(-2a)]/[CuT])
-33.6005322987
-31.6005325991
-29.6005335489
-27.6005365527
-25.6005460511
-23.6005760866
-21.6006710538
-19.6009712317
-17.6019191363
-15.6049033444
-13.6142096084
-11.6424107355
-9.7213283001
-7.9057982098
-6.2319391009
-4.6769754662
-3.2142589725
-1.8675806199
-0.7339517207
-0.126092696
-0.0113516996
-0.0007666121
-0.000073469
-0.0001406025
-0.0004726554
-0.0015286206
-0.0048523602
-0.0151989732
-0.0463843322
-0.1324281273
-0.3278738591
-0.6594998852
-1.0890417146
-1.564151874
-2.0559745973
-2.5533563406
-3.0525250793
-3.5522618799
-4.0521786158
-4.552152282
-5.0521439542
-59.099730833
-56.0997311334
-53.0997320834
-50.0997350874
-47.0997445867
-44.0997746248
-41.0998696003
-38.1001698047
-35.1011177927
-32.1041022646
-29.1134093629
-26.1416131286
-23.2205390366
-20.4050353299
-17.7312596422
-15.1765597034
-12.714676037
-10.3706208539
-8.2451843855
-6.6622596065
-5.6180895023
-4.7760839849
-4.0801638223
-3.4943193436
-2.9635207667
-2.4542491234
-1.9542552053
-1.4635473863
-0.9943987711
-0.5803369009
-0.275749213
-0.1073646703
-0.0369031575
-0.01201226
-0.0038346491
-0.0012162867
-0.000384992
-0.0001217821
-3.85145610582428E-005
-1.21797428494638E-005
-3.85160979859869E-006
A1
A2
A3
2
2
2
A1
A2
A3
3.15E-05
3.15E-05
3.15E-05
A1
A2
A3
-4.50202
-4.50202
-4.50202
dado de
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
H
kJ
24.615
25.698
26.626
27.435
28.156
28.813
29.428
30.017
30.592
31.160
31.727
32.294
32.861
S
J/K
72.640
76.571
79.878
82.710
85.190
87.414
89.461
91.387
93.236
95.037
96.806
98.548
100.261
G
kJ
4.773
4.400
4.009
3.602
3.182
2.751
2.308
1.856
1.395
0.924
0.444
-0.044
-0.541
K
1.222E-001
1.492E-001
1.821E-001
2.223E-001
2.710E-001
3.297E-001
4.002E-001
4.845E-001
5.853E-001
7.052E-001
8.476E-001
1.016E+000
1.216E+000
65
70
75
80
85
90
95
100
33.433
34.018
34.619
35.237
35.874
36.533
37.217
37.927
101.966
103.684
105.421
107.183
108.975
110.803
112.672
114.590
-1.047
-1.561
-2.084
-2.615
-3.155
-3.705
-4.264
-4.832
1.451E+000
1.728E+000
2.054E+000
2.437E+000
2.886E+000
3.412E+000
4.027E+000
4.747E+000
T
C
0
5
10
15
H
kJ
-27.281
-20.430
-19.663
-18.954
-18.285
-17.644
-17.019
-16.403
-15.787
-15.170
-14.546
-13.917
-13.283
-12.639
-11.983
-11.313
-10.627
-9.924
-9.203
-8.462
-7.699
S
J/K
50.148
75.200
77.933
80.417
82.718
84.887
86.965
88.983
90.963
92.920
94.863
96.796
98.715
100.631
102.558
104.498
106.454
108.430
110.429
112.456
114.514
G
kJ
-40.979
-41.347
-41.730
-42.126
-42.534
-42.953
-43.383
-43.823
-44.272
-44.732
-45.202
-45.681
-46.170
-46.668
-47.176
-47.694
-48.221
-48.758
-49.305
-49.862
-50.430
K
6.871E+007
5.826E+007
4.999E+007
4.336E+007
3.798E+007
3.356E+007
2.990E+007
2.685E+007
2.429E+007
2.212E+007
2.028E+007
1.871E+007
1.736E+007
1.620E+007
1.520E+007
1.433E+007
1.358E+007
1.293E+007
1.237E+007
1.189E+007
1.148E+007
20
25
30
-106.635
-103.960
-101.289
118.925
127.973
136.858
-141.498
-142.115
-142.777
1.640E+025
7.945E+024
4.013E+024
35
-98.613
145.612
-143.484
2.109E+024
40
-95.928
154.257
-144.233
1.150E+024
45
-93.228
162.810
-145.026
6.497E+023
50
-90.512
171.281
-145.861
3.796E+023
55
-87.778
179.675
-146.739
2.289E+023
60
-85.028
187.992
-147.658
1.423E+023
65
70
75
80
-82.258
-79.464
-76.646
-73.802
196.245
204.447
212.601
220.713
-148.619
-149.620
-150.663
-151.746
9.105E+022
5.988E+022
4.042E+022
2.797E+022
85
90
95
100
-70.930
-68.031
-65.102
-62.142
228.786
236.826
244.837
252.823
-152.870
-154.034
-155.238
-156.482
1.983E+022
1.438E+022
1.066E+022
8.067E+021
T
C
0
5
10
15
20
25
30
35
40
45
50
-99.391
338.490
-208.774
5.616E+033
55
-95.562
350.248
-210.496
3.231E+033
60
65
70
75
80
85
90
95
-91.734
-87.894
-84.030
-80.140
-76.219
-72.265
-68.272
-64.239
361.825
373.266
384.608
395.863
407.045
418.164
429.233
440.264
-212.276
-214.114
-216.008
-217.960
-219.967
-222.030
-224.148
-226.322
1.930E+033
1.195E+033
7.651E+032
5.061E+032
3.453E+032
2.425E+032
1.753E+032
1.301E+032
100
T
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
-60.160
451.270
-228.551
9.906E+031
+a)
Log(K)
-7.446
-7.321
-7.199
-7.080
-6.962
-6.848
-6.736
-6.626
-6.518
-6.413
-6.310
-6.209
-6.109
-6.012
-5.917
-5.823
-5.731
-5.640
-5.551
-5.464
-5.377
a)
Log(K)
-0.913
-0.826
-0.740
-0.653
-0.567
-0.482
-0.398
-0.315
-0.233
-0.152
-0.072
0.007
0.085
[H(+a)]
1.00E+00
3.16E-01
1.00E-01
3.16E-02
1.00E-02
3.16E-03
1.00E-03
3.16E-04
1.00E-04
3.16E-05
1.00E-05
3.16E-06
1.00E-06
3.16E-07
1.00E-07
3.16E-08
1.00E-08
3.16E-09
1.00E-09
3.16E-10
1.00E-10
3.16E-11
1.00E-11
3.16E-12
1.00E-12
3.16E-13
1.00E-13
3.16E-14
1.00E-14
3.16E-15
1.00E-15
3.16E-16
1.00E-16
3.16E-17
1.00E-17
3.16E-18
1.00E-18
3.16E-19
1.00E-19
3.16E-20
1.00E-20
pH
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
11.5
12.0
12.5
13.0
13.5
14.0
14.5
15.0
15.5
16.0
16.5
17.0
17.5
18.0
18.5
19.0
19.5
20.0
0.162
0.238
0.313
0.387
0.460
0.533
0.605
0.676
Diagram
100%
95%
90%
85%
2O
80%
Log(K)
7.837
7.765
7.699
7.637
7.580
7.526
7.476
7.429
7.385
7.345
7.307
7.272
7.240
7.209
7.182
7.156
7.133
7.112
7.093
7.075
7.060
75%
70%
65%
60%
55%
% Concentracin
50%
45%
40%
35%
30%
25%
20%
15%
10%
5%
0%
0
Diag
+ 3H2O
Log(K)
0
26.679
26.279
25.903
25.549
0
-5
-10
-15
0
-5
-10
25.215
24.900
24.603
-15
24.324
-20
24.061
23.813
23.579
23.360
-25
log[CuT]
23.153
-30
-35
22.959
22.777
22.607
22.447
-40
-45
22.297
22.158
22.028
21.907
-50
-55
-60
+ 3H2O
Log(K)
37.304
36.831
36.389
35.976
35.591
35.230
34.893
34.577
34.282
34.007
Diag
0
1.000E+001
1.000E-003
1.000E-007
33.749
1.000E-011
33.509
33.286
33.077
32.884
32.704
32.538
32.385
32.244
32.114
1.000E-015
1.000E-019
1.000E-023
log[CuT]
1.000E-027
1.000E-031
1.000E-035
1.000E-039
1.000E-043
log[CuT]
1.000E-027
1.000E-031
31.996
1.000E-035
1.000E-039
1.000E-043
1.000E-047
+ 2H2O
Log(K)
54.414
53.723
53.073
52.461
51.882
51.334
50.816
50.324
49.857
49.414
48.993
48.593
48.214
47.853
47.511
47.185
46.876
46.583
46.305
46.041
45.791
1.000E-051
1.000E-055
1.000E-059
H2CO3(a)/HCO3(-a)/CO3(-2a)
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
[Cu(+2a)]
2.909E+008
2.909E+007
2.909E+006
2.909E+005
2.909E+004
2.909E+003
2.911E+002
2.917E+001
2.933E+000
2.987E-001
3.157E-002
3.694E-003
5.392E-004
1.076E-004
2.774E-005
8.144E-006
2.512E-006
7.882E-007
2.486E-007
7.856E-008
2.484E-008
7.853E-009
2.483E-009
7.853E-010
2.483E-010
7.853E-011
2.483E-011
7.853E-012
2.483E-012
7.853E-013
2.483E-013
7.853E-014
2.483E-014
7.853E-015
2.483E-015
7.853E-016
2.483E-016
7.853E-017
2.483E-017
7.853E-018
2.483E-018
[CuOH(+a)]
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
8.409E-005
[Cu(OH)3(-a)]
[CuO2(-2a)]
9.3827861E-020 9.102232E-044
9.3827861E-019 9.102232E-042
9.3827861E-018 9.102232E-040
9.3827861E-017 9.102232E-038
9.3827862E-016 9.102232E-036
9.3827863E-015 9.102232E-034
9.3827869E-014 9.102232E-032
9.3827885E-013 9.102232E-030
9.3827938E-012 9.102232E-028
9.3828104E-011 9.102232E-026
9.3828630E-010 9.102232E-024
9.3830292E-009 9.102232E-022
9.3835549E-008 9.102232E-020
9.3852172E-007 9.102232E-018
9.3904740E-006 9.102232E-016
0.000094071 9.102232E-014
0.0009459665 9.102232E-012
0.0096258984 9.102232E-010
0.1015157484 0.000000091
1.1813909543 9.102232E-006
17.0706734488 0.0009102232
336.940205134 0.0910223209
8626.1659573 9.1022320922
252495.130219 910.223209224
7781715.20815 91022.3209224
244050622.728 9102232.09224
7697270133.24 910223209.224
243206171978 91022320922
7688825625748 9102232092236
2.431217E+014 9.102232E+014
7.687981E+015 9.102232E+016
2.431133E+017 9.102232E+018
7.687897E+018 9.102232E+020
2.431124E+020 9.102232E+022
7.687888E+021 9.102232E+024
2.431124E+023 9.102232E+026
7.687887E+024 9.102232E+028
2.431123E+026 9.102232E+030
7.687887E+027 9.102232E+032
2.431123E+029 9.102232E+034
7.687887E+030 9.102232E+036
Diagrama de Predominancia
100%
95%
90%
85%
80%
75%
70%
65%
60%
55%
ntracin
50%
45%
40%
35%
30%
25%
20%
15%
10%
5%
0%
0
10
11
12
13
14
15
16
17
18
19
20
pH
Diagrama de Bjerrum
0
0
-5
-10
-15
10
11
12
13
14
15
16
17
18
19
20
0
-5
-10
-15
-20
-25
-30
-35
-40
-45
-50
-55
-60
pH
Diagrama de Bjerrum
0
1.000E+001
1.000E-003
1.000E-007
1.000E-011
1.000E-015
1.000E-019
1.000E-023
1.000E-027
1.000E-031
1.000E-035
1.000E-039
1.000E-043
10
11
12
13
14
15
16
17
18
19
20
1.000E-027
1.000E-031
1.000E-035
1.000E-039
1.000E-043
1.000E-047
1.000E-051
1.000E-055
1.000E-059
pH
[CuT]
2.909E+008
2.909E+007
2.909E+006
2.909E+005
2.909E+004
2.909E+003
2.911E+002
2.917E+001
2.934E+000
2.988E-001
3.165E-002
3.778E-003
6.234E-004
1.926E-004
1.212E-004
1.863E-004
1.033E-003
9.711E-003
1.016E-001
1.181E+000
1.707E+001
3.370E+002
8.635E+003
2.534E+005
7.873E+006
2.532E+008
8.607E+009
3.342E+011
1.679E+013
1.153E+015
9.871E+016
9.345E+018
9.179E+020
9.127E+022
9.110E+024
9.105E+026
9.103E+028
9.102E+030
9.102E+032
9.102E+034
9.102E+036
[Cu(+2a)]/[CuT]
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
1.000E+000
9.997E-001
9.973E-001
9.777E-001
8.650E-001
5.586E-001
2.289E-001
4.371E-002
2.433E-003
8.117E-005
2.447E-006
6.649E-008
1.455E-009
2.330E-011
2.876E-013
3.099E-015
3.154E-017
3.102E-019
2.885E-021
2.349E-023
1.479E-025
6.809E-028
2.516E-030
8.403E-033
2.705E-035
8.604E-038
2.726E-040
8.625E-043
2.728E-045
8.627E-048
2.728E-050
8.627E-053
2.728E-055
[CuOH(+a)]/[CuT]
2.891E-013
2.891E-012
2.891E-011
2.891E-010
2.891E-009
2.890E-008
2.888E-007
2.883E-006
2.866E-005
2.814E-004
2.656E-003
2.226E-002
1.349E-001
4.365E-001
6.937E-001
4.513E-001
8.143E-002
8.659E-003
8.276E-004
7.117E-005
4.925E-006
2.495E-007
9.738E-009
3.318E-010
1.068E-011
3.322E-013
9.769E-015
2.516E-016
5.008E-018
7.291E-020
8.519E-022
8.998E-024
9.161E-026
9.213E-028
9.230E-030
9.236E-032
9.237E-034
9.238E-036
9.238E-038
9.238E-040
9.238E-042
[Cu(OH)3(-a)]/[CuT]
3.226E-028
3.226E-026
3.226E-024
3.226E-022
3.226E-020
3.225E-018
3.223E-016
3.217E-014
3.198E-012
3.140E-010
2.964E-008
2.484E-006
1.505E-004
4.872E-003
7.747E-002
5.049E-001
9.161E-001
9.913E-001
9.992E-001
9.999E-001
9.999E-001
9.997E-001
9.989E-001
9.964E-001
9.884E-001
9.640E-001
8.943E-001
7.277E-001
4.579E-001
2.108E-001
7.788E-002
2.601E-002
8.375E-003
2.664E-003
8.439E-004
2.670E-004
8.445E-005
2.671E-005
8.446E-006
2.671E-006
8.446E-007
Diagrama
0
45
40
35
30
25
20
15
10
[Cu(+2a)]/[CuT]
[CuOH(+a)]/[CuT]
[Cu(OH)3(-a)]/[CuT]
[CuO2(-2a)]/[CuT]
log[CuT]
0
-5
-10
-15
-20
-25
-30
-35
-40
-45
17
18
19
-50
20
Diagrama
17
18
19
20
0
40
35
30
25
16
40
35
30
25
20
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[CuT]
log[CuO2(-2a)]
15
10
-5
-10
Diagrama
17
18
19
20
-3
[Cu(+2a)]
[CuOH(+a)]
[Cu(OH)3(-a)]
[CuO2(-2a)]
log[CuT]
-4
[Cu(OH)3(-a)]
[CuO2(-2a)]
log[CuT]
-4
-5
[CuO2(-2a)]/[CuT]
3.129E-052
3.129E-049
3.129E-046
3.129E-043
3.129E-040
3.129E-037
3.127E-034
3.121E-031
3.103E-028
3.046E-025
2.876E-022
2.409E-019
1.460E-016
4.725E-014
7.509E-012
4.886E-010
8.815E-009
9.373E-008
8.959E-007
7.704E-006
5.332E-005
2.701E-004
1.054E-003
3.592E-003
1.156E-002
3.596E-002
1.057E-001
2.723E-001
5.421E-001
7.892E-001
9.221E-001
9.740E-001
9.916E-001
9.973E-001
9.992E-001
9.997E-001
9.999E-001
1.000E+000
1.000E+000
1.000E+000
1.000E+000
log[CuT]
8.463693953
7.4636947547
6.4636972899
5.463705307
4.4637306592
3.4638108276
2.4640643223
1.4648657412
0.4673980218
-0.5246147968
-1.4995719417
-2.4227349717
-3.2052542157
-3.7152574282
-3.9164332965
-3.7297849551
-2.986082492
-2.0127461548
-0.9931055464
0.0724279261
1.2322759507
2.5276702504
3.9362758344
5.4038157857
6.8961257726
8.4033828293
9.9348766955
11.5240434706
13.2250780545
15.0619592132
16.994362481
18.9705953562
20.9628006245
22.9603063203
24.9595145622
26.9592638857
28.9591845848
30.9591595046
32.9591515732
34.9591490651
36.9591482719
log[Cu(+2a)]
8.463693953
7.4636947547
6.4636972899
5.4637053069
4.4637306579
3.4638108151
2.4640641969
1.4648644891
0.4673855732
-0.5247370293
-1.5007271612
-2.4325112291
-3.2682585177
-3.9681339807
-4.5568782108
-5.0891870875
-5.5999253624
-6.1033771133
-6.6044743871
-7.1048219532
-7.6049319212
-8.104966702
-8.6049777012
-9.1049811795
-9.6049822794
-10.1049826273
-10.6049827373
-11.104982772
-11.604982783
-12.1049827865
-12.6049827876
-13.104982788
-13.6049827881
-14.1049827881
-14.6049827881
-15.1049827881
-15.6049827881
-16.1049827881
-16.6049827881
-17.1049827881
-17.6049827881
log[CuOH(+a)]
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
-4.0752740753
log[Cu(OH)3(-a)]
-19.0276681841
-18.027668184
-17.0276681838
-16.027668183
-15.0276681806
-14.0276681729
-13.0276681485
-12.0276680716
-11.0276678283
-10.0276670589
-9.0276646257
-8.0276569315
-7.0276326012
-6.027555671
-5.0273124859
-4.0265443623
-3.0241242444
-2.0165587245
-0.9934665795
0.0723936412
1.2322506546
2.5275528359
3.9358178092
5.4022530065
6.8910753326
8.3874799202
9.8863367283
11.3859745921
12.8858600117
14.3858237719
15.8858123112
17.385808687
18.8858075409
20.3858071785
21.8858070639
23.3858070276
24.8858070162
26.3858070125
27.8858070114
29.385807011
30.8858070109
Diagrama de Solubilidad
1
10
11
12
13
14
15
16
17
18
19
20
log[CuT]
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[CuO2(-2a)]
ECA A1, A2 y A3
pH
Diagrama de Solubilidad
1
10
11
12
13
14
15
16
17
18
19
20
log[CuT
]
pH
Diagrama de Solubilidad
7
log[CuT
log[CuT
pH
log[CuO2(-2a)]
-43.0408520949
-41.0408520949
-39.0408520949
-37.0408520949
-35.0408520949
-33.0408520949
-31.0408520949
-29.0408520949
-27.0408520949
-25.0408520949
-23.0408520949
-21.0408520949
-19.0408520949
-17.0408520949
-15.0408520949
-13.0408520949
-11.0408520949
-9.0408520949
-7.0408520949
-5.0408520949
-3.0408520949
-1.0408520949
0.9591479051
2.9591479051
4.9591479051
6.9591479051
8.9591479051
10.9591479051
12.9591479051
14.9591479051
16.9591479051
18.9591479051
20.9591479051
22.9591479051
24.9591479051
26.9591479051
28.9591479051
30.9591479051
32.9591479051
34.9591479051
36.9591479051
log([Cu(+2a)]/[CuT])
-1.255554361453E-013
-1.255506145081E-012
-1.255486858548E-011
-1.255466125671E-010
-1.255392597334E-009
-1.255160933984E-008
-1.254428686926E-007
-1.252117616215E-006
-1.244854194431E-005
-0.0001222325
-0.0011552195
-0.0097762574
-0.063004302
-0.2528765525
-0.6404449143
-1.3594021324
-2.6138428704
-4.0906309585
-5.6113688406
-7.1772498793
-8.837207872
-10.6326369524
-12.5412535356
-14.5087969651
-16.5011080521
-18.5083654566
-20.5398594327
-22.6290262427
-24.8300608375
-27.1669419997
-29.5993452687
-32.0755781441
-34.5677834126
-37.0652891084
-39.5644973504
-42.0642466739
-44.5641673729
-47.0641422927
-49.5641343613
-52.0641318532
-54.5641310601
log([CuOH(+a)]/[CuT])
-12.5389680282
-11.53896883
-10.5389713652
-9.5389793823
-8.5390047344
-7.5390849029
-6.5393383976
-5.5401398165
-4.5426720971
-3.5506592785
-2.5757021335
-1.6525391036
-0.8700198596
-0.360016647
-0.1588407788
-0.3454891201
-1.0891915833
-2.0625279205
-3.0821685288
-4.1477020014
-5.307550026
-6.6029443257
-8.0115499097
-9.4790898609
-10.9713998479
-12.4786569046
-14.0101507707
-15.5993175459
-17.3003521298
-19.1372332884
-21.0696365563
-23.0458694314
-25.0380746998
-27.0355803956
-29.0347886375
-31.034537961
-33.03445866
-35.0344335798
-37.0344256485
-39.0344231403
-41.0344223472
log([Cu(OH)3(-a)]/[CuT])
-27.4913621371
-25.4913629387
-23.4913654737
-21.49137349
-19.4913988397
-17.4914790005
-15.4917324709
-13.4925338128
-11.4950658501
-9.503052262
-7.528092684
-5.6049219598
-3.8223783855
-2.3122982428
-1.1108791895
-0.2967594071
-0.0380417524
-0.0038125697
-0.000361033
-3.42848740954274E-005
-2.5296096332801E-005
-0.0001174145
-0.0004580252
-0.0015627792
-0.00505044
-0.0159029092
-0.0485399672
-0.1380688786
-0.3392180428
-0.6761354413
-1.1085501698
-1.5847866692
-2.0769930836
-2.5744991418
-3.0737074984
-3.5734568581
-4.0733775686
-4.573352492
-5.0733445618
-5.573342054
-6.073341261
20
log[CuT]
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[CuO2(-2a)]
ECA A1, A2 y A3
ECA Cu
mg/L
mg/L
A1
A2
A3
ECA Mn
mol/L
mol/L
A1
A2
A3
ECA Mn
log[mol/L]
log[mol/L]
A1
A2
A3
log[CuT
]
log[CuT]
log[CuT]
log([CuO2(-2a)]/[CuT])
-51.5045460479
-48.5045468496
-45.5045493848
-42.5045574019
-39.504582754
-36.5046629225
-33.5049164172
-30.5057178361
-27.5082501167
-24.5162372981
-21.5412801531
-18.6181171232
-15.8355978792
-13.3255946667
-11.1244187984
-9.3110671397
-8.0547696029
-7.0281059401
-6.0477465484
-5.113280021
-4.2731280456
-3.5685223453
-2.9771279293
-2.4446678806
-1.9369778675
-1.4442349242
-0.9757287903
-0.5648955655
-0.2659301494
-0.102811308
-0.0352145759
-0.0114474511
-0.0036527194
-0.0011584152
-0.0003666571
-0.0001159806
-3.6679641507542E-005
-1.1599455923682E-005
-3.6681035185931E-006
-0.00000116
-3.6681174565666E-007
2
2
2
3.15E-05
3.15E-05
3.15E-05
-4.50202
-4.50202
-4.50202