.

a,
.a\

]n

l<pflfrrnn

av.

.s

/.6

Jre\-I

lt.rnpTlns ! !<A\rutlr}I.l H.xprnEs!tr I

-/--.
-h.t4.iY
d1.*tV- =-a\\v3r-IAITJUIa

-.fr V

Several *xp*rim*.nt$ lryeie e*nrJu*ted at 3* ofi lrr Etudy the reartirirr berrreen trr,,c EuLrst&nfe$
:rn.{ 1fl
A.

1fl
aq gllu

2H{S} +

Yis} -v ?Z{s}

.:

j'i

Initiat *oncentration (mol dm4)

',

, {mol dnr* mtu.a}i

i.2ft

(ii

{ii}
{iii}

{h} ii}

iiii

{iii}

**tu,

mt* equntion f*r th* reaetion.

*n}.*ulat* ihe rste *{,ir$tfint f{ir tli* rea*tion.
whe* *xp*nment I vrns rereat*d et 8{,} oC, th* initirt r*te *f refiti$n was fi^2?
m*I dm*3 min-r= tr,trst is th* a*tiviltl*n *nergf f*r the rea*ti*n?
Expiai* h*ir th* rat* s*n.{ta&t is influ*rt*ed by arr irrcr**se in temFernture.
FxFt*i*. h**' anrl rrtr3'- thc pr*senr* *f a *at*tysr- nff**ts the rate *f a *hemieal
r***{isn"
S*sid*s t*mperature and *atn"l-+str stats twa rther factrrs that infln*nce the mte *f
a rh*mi*al rea*ti*rr"
rvfit*

Arhenius

eqQ

k.

ln!',
l(,

A-lI

* i :i

?.3

il.4*
Ea+ed *'n t}re *brvr.

x 1ff3
1.1 x l(l*
i"* x I*-3

il.sr]

il.s*

{ej

.-

.,',;Inltialrqte,,, ., i

Eq (J---L\

R \T. T,I

prcparcd by alextan5S@email.com

A"*

. k[xJ* [Y

a) (;,

tlre

k(t.x.o)o ( o.B'o)t
k (l.eo

b
)* (o.8o )

t z.zxtd'3

k ( t.8o)" (o.80 )b''. l.txto'r

,<

(t.ao)"

: l.8xlo-3 O

(O.+O

t.)o

)q

l.: xlD-3
l.lxl0-)

co.80 )b

(r.8o)" (o.80)b
.20 \a
,. 80

(o.ee )" : o'66

q =l

Oa
(o.so

)t

( r"ro )o ( o.,lo)u

7.2 y1g*9
r.8 xr0-?

:2'
Re+e = k [X

" k(t.ao)

7-zx1g'z

k*

9-

D,gO )t',

3lS-3 ry,ot-l

(iii)

303

fn

k:

drn6 s-'

lnA
Eq
Rtao31

Bo'c ,/

-"--o

gss r.

)t : o.z-1
k * o.35

r.ao) ( o.8O

E,
-T?

ln o.3s2

'

ln A -

Ee
--R-

_t

aQ=8.?

Eq

o.1s2

Eo=

6+

x,Os kJ rnot-r

3oa

,,

Re*eticn Kineiics i Revisi+n Exercise )

{x} Th* *}rfrnge in *rs rute s*fistaitt *f e rc*eti#ii, A{g} * B{g}
ternp*rature is

strnr,ry'n

r-i:)"arf*":*:1rY_i_i-_:"-:::_a-.-;

r ,__,tgryTture
--*__L

{-ig} with incrcsre ifl

beir:v*.
""_-_l

iK) t-*----*'*-*-:'^*-'--'*^*"*-"-1
i ry_tlu:o11l$[tji]| _
r

: I I ]------:"t::::"":*

"

s.23S
it**".---=_:{}* *_**_+---i
*-*."---.-*-{
*"3fi1
L*_ _ __i[r *_* ---1__

t+nnl
'--"._-l*nnl

i
j
I

----l**

5{]f!

-J

aq)

ihi

Pl*t * gruprlr cf lrr & *g*irtst l/It* d*t*rmine th* e*tivnt!fin snergy f*r th* rea{ti*fi.
Trarrsiti*ti metsls tllen mak* gr]*d *atalysts.
ti) It'hat are ttre gen*r*l pr*perties af cataly-sts?
{ii} Heiw dces a eatalyst rff*et the rate **t}sta$t of a $action?

*/

r/u

K"

lnk

3{)O

.5-orro-3

o. a36

-,.4i++

3oo

s.33x'0-3

o.3Ot

-t.20I

/LO O

:.sortO-3

o.340

-r.orj

500

2. oo X rg*3

o.366

^ t. ooS

600

l"6z xlO-3

o .3Bs

- o.ess

700

l.4gxrO-3

o.3gq

xl$S

o.4Dq

- o.9 tQ
* o.899-

60o

l.as

rrhsJ'I;us

Tk=Ae

,{!I preparcd

b-v

alextan5S@smail.com

-Eq
-ET +

MM SQUARE - 20 CM X 24 CM 40 S

- InA

Eor l
: -T(?

+ lnA
Ea
: --r

_ - r. +t++ 5.ooxd3

Eo --

(-o.9ss

t.67rro

,+6.8 x (9.3r )
,2.t

q.g

t I.f2xig" kI rnol*l

Reaetion Kinetim ( Revision Exercise )

$q-Ft in Figure I shrrr* thaehnnge in,the e$n*efitrati*ii *f H1S; ss it dec*rnpCIser inte N*? ani,
*s ar3?S K.

P-

ngur*t

(ni From the gruph,

[t rr,.edrsl

{ii} *aleulate rherfite **nstsnt, *,

(b)

f-'alculate the half-lif*

*f

I,{sO5 at 328

[3 mar&sl

tt

ineffiasq defir*ilserx temain q*rstant? Expl*ia why.

[?mar.lml

Arrh'c,;us eqn

- -Eo

k=AzF
-

All prepared by alextan5S@email.com

n.artrst

tJ]o=

bt

is,

: -kt + ln [w.O

NuOs

*+.dr8 - c-+.t )

36o -

rao

: i.s83x to*3 s-'

(5)

lna.
l.Sgsx

16;-3

= 432.81

(c)

k [N>O

r i.ss3xlo-3 [

lhe
Bx

**o

o$ tn [rur0s

becorrse

ln I

fruO

rel <orSlqn*

,Sa

Reaction Ki*eties ( Revision Exercise

5 ia) !{H,NC:{; in sululicn rgsrf,sng*$

ts p,rsdu.fg ar*a" {NH3}2{***l

HH*NC*{aq}

=+

{Flit,irC*{sqi

Thisrgneti*rrise.@ittak*s1i,shriurt.fc'rthe*fil?**ntrBti*n*fNFLNC*te
Detsr:Bi**

{i; the rats E*rr$t*ng, &, f*r rh* r*acti*n"'

{ii} th* tirfie eakeir fl*r ihe de**mp*siii*n

{ii*

*f *$ffi *f S"25** M HHrHC*,

the ffifrctisn rai* r*'h*n ths Esnrcrmti*n tl.'f }'lH+N{--t} t* t}.fi}P L{.

{F} ilne scnr'*rsifin cf *yelopm-mne ts prspefis in the ga.s phnxe is a flfsqordet

' *e*+taat *f G,? x i*d r-i *t 5{X} o*.

[$

**aEqqq

ma*r]

xith a rat*

--**

H.*:*H_CH,

ti) If th* initinl snnscmEati*n *f *y*l*pmp*ne l+as *,';5 F{, wh*t i* it* e*nerntrntim nfter
E.S min?
T.TIJ

Her***
Ll,

iiiii

I]

Iong
,lH

*'iit it tak* f*r thr *onr:entrati*n *f

Harrr lnng

will ittals* t* *unv*lt

?4*fr ef tire

th Sc<."nd ords rxo

T

lAl+

ry.elopr*pflne to decrease frsrr fi.25

IlI tp

r'

:kt

+ tAl.

Frst order rx!

in [A11

-kt + ln [Al"

AiI prcparcd by alextan5$@qmail.com

*y*l*prnp*n* ta pmpene?

[S markel

MPM R*r;ri*", So"l-

[Al.
o.:soo

o.o64l

t-

L+

un;r Itt

,oo

IAJt

rAl *
o.2S()s

corr<,s*

qrrit

!t

(bl

6-7xl6P-+

rAl : o.35M
,n lAlt

: -t$ +

In

[A]"

t t 8'8 rrrin

- g.g x&cr
: 5:.8 s
[Al

fA-l

"

o-as

[nl + "
-'.

o"t'16 rnor drn-i

*$ter 8.8 rnin

corrcorr*tcrfion of

ln

[A]t : -kt + ln [Al"

o.t5
o.zS
-- ? G4.43 s

= ta"1 "rrinu*s

,ef

[Al.t:

fAlu: tooz

It = -kt

roo"fl

+ ln [A]"

3C
loD

t : 2oto.5(5
:

33. S minuts.,

*7af

is

o.l?6 mot d.n-3

Reaction Kineiics i Revision Exercise

lF

A and F. Thr d*c*mp*siti*n *f e*mp**n*4 ir a Er.qt

The halElires for^,{ and #
*rrle"^r re*r,rinn bur *rtmpumd;fltlecompssss by
are ?5.1i mi* *nd I3,*S nein, respectively. If brth.{ and I havc the same initial *onflsni*ttion mf
*.lft I!.t" *3et*rmin+ thp ratir $f [he final x*ris*ntralir]ns qf *1 tei $ after Sfi"fi
[t* marks]

ia) A flask csntninr a mixtur* *f *ermpou***

min.

,Fanaru-t' 1g 6h.is Fear, ae ar*+ur]* *f 5.S x l0-? H *m-' *f ir:s***i*i** ltad heen t**h*d int*
q laks. Th* r*t* *s*stsnt for the d**amp*siti** *f this ins*cticid* *s 1..i5 yesrr, Bt 25 "C.
"= ' ' Hli tire *v*rage lalw temp*ratirre i* 15 ue, what worrld b* tlt* e****n*,,natitn *f the
,+.B$UIII!mS ''at
*fr? [* markcl
inseericlde nn Jan*ar3 !.st nr*t year1l lfu"hat is the half=life ofthis inse*tisid* at 25

ib) *ri

* .Harf rife (Rrcqj I ll t )

(A) .tst ord* rxg

+L+- rn2
K
CB

) )nd

1L lntAl*

: -kt .l'tAl.]

order rxO

t+=

#,

AiI prcparcd b:f alextan5S@smail.com

*or* =

kt +

*t}

6 (o)

ln

[A]t = -kt + lo IAl"

tAlt:

t -

o,OG3 rnol drn 3

ktAl.
p (o,ro)

: o.-lfL

tAlt

rnol-'

[Al"

[a: *
EAI+

o "(o

: o. o2l7 nrol

o. o:.f

-' ,"45

b ls* o.der rxl

ln [A]t . - ( l,+s) (t ) + ln ( s"o xto'?

rAl * t"l?3xld?

rnol {rn-}

o. el"? 8

l. t'I3

xldr rnol drn-}

E<errrlnn ira!tlElpgto I/ n]<partsrrlEl E]{.Yprntsp

fix*sttem

ES

*t*ned

t*#6

Explaki iire e{t'eet *f t*rnperat*r* #ri the rat* +f r***u*n

hr u * rr g Me-v-'crell-Eclltum *$n di * r"i.hu ti+n fi -lrrre.
[S m*rxs.;

* Reolt ll!

B*E*Eis*
Nrr.mli*r

r=f

mri*cult*

L*w trrnperature

f
I

,."4- "'r'

i
I
I

-Fiigh

/
\-.rr\
\i \-r
1i\n

efctit
(MPrta qus*ions e )

rgqrrireynerrhs Sor.

trsllFrrcttu'E

/"

l- 4

ln
I

coll;slms

Tte,molecr4es hus+ Possess

q clr*ain eaQrgg ,lhcl equal or
gt@fr +han Eo for' 4o e$fc'tive

collisioo {o oecln'

4
*.

M*lr.qular ernsrie eftergy ar

o Ma.*u.rell-Bo$zfiranO dis*ribtfioo u)-rve Sho-S

tvrolecnles +ho+

'

4he-

nuJDbr o{

hovLlg_o P.rf;g4o.r e/teryq @

A+ h;gner +errrpercrturt , 'lh qyer.asq

w;ll inlxe0ses

The mdecrrles ft.ttrs+ collidc

of

rnolgOut 95

Jhe nqmber oS rnolegdps fhol harr;ng *he rnO

tnimum
9qqu frr",+ qguol or gr&fr fhan E" ,bgeose.O

'

The

{<q'*or,3 o+ @

' The B*

*itl iocttqses O

oF .oo'.+,o, will jncreoses_, @

Ali Frepar*d bi. alextan5S@smail.com

veiuci-t3'

Reaction Kinetics ( Revisien Exercise

Question

2'l

Ciond 2007

lVritc the Arrhrnius equatit:n. Explain the r*laticrrship

hetr.vr:rn thr rate r:onstant and t*rnpcraftlre *f a ehtmii:al
rriicti*n usirrg Arrhrnius rquati*n.
[5 marks]

{rrhenius eqr.rntion
toherg

^ -Eo
Rr
ls. Ag

k= rale(oostunf

A = Artl,errius onSlunf

t . dctivotion nergg
R : go.s tonslan* / ^oto, gas <oos*qn+
T .- qbsolrrt +ernpem{rrre

'

furn Arrhenius egu5rh'on r the rc+e

fhe +ernperor-ere.

coas-lonr {gpge& on

'

Thg rate

'l'h;s is becouse +he o^/ercsrg

kinetic

con-strarr|

.-ill irrggleslej

increasGq os rcnopro+ul

"

The

'

Os .rcrrrpeftrlure, incleoses .

oF mdsdes

incrc-oSe<. O

nr 8. ol rnofecules Jfrc* hu.v;ng rninirnr.r,rn r,erys

iha* eryat or 3rU*ef 'thqn Eo w;ll

Ali Frepared by alextanS8@smail.com

incraSe-S