Unit 3.

Air and Water

Syllabus Ref. 11.1

A reversible reaction of hydrated copper(II) sulfate

Class practical
Students remove the water of crystallisation from hydrated copper(II) sulfateby heating. Condensing the vapour produced in a
second test-tube collects the water. The white anhydrous copper(II) sulfate is then rehydrated and the blue colour returns.

Lesson organisation
This experiment can be carried out in pairs by students. It should take no more than 30 - 40 minutes.

Apparatus

Chemicals

Each group
will require:
Eye
protection
Test-tubes, 2
Delivery tube
(right-angled)
Beaker, 250
cm3
Bunsen
burner
Clamp and
stand

Copper(II) sulfate(VI)-5-water (powdered),

(HARMFUL, DANGEROUS FOR THE
ENVIRONMENT), about 5 g
Refer to Health & Safety and Technical
notes section below for additional
information.

Health & Safety and Technical notes

Read our standard health & safety guidance
Wear eye protection.
Copper(II) sulfate(VI)-5-water, CuSO4.5H2O(s), (HARMFUL, DANGEROUS FOR THE ENVIRONMENT) - see CLEAPSS
Hazcard.

Procedure

a Set up the apparatus as shown (but without water in the recieving tube this is to be collected during the experiment), placing
about 5 g of powdered hydrated copper(II) sulfate in the test-tube. Make sure that the tube is clamped near the bung as shown.
b Heat the blue copper(II) sulfate until it has turned white. Move the flame along the length of the test-tube from time-to-time
(avoiding the clamp) to prevent water condensing on the cooler regions and then running down on to the hot solid, possibly
cracking the test-tube.
c Act quickly to prevent suck-back if the level of water collecting in the test-tube reaches the end of the delivery tube. Lift the
clamp stand so that the delivery tube does not reach into the water in the test-tube.
d Allow the anhydrous copper(II) sulfate to cool back to room temperature.
e Holding the test-tube containing anhydrous copper(II) sulfate in one hand, pour the
collected water very slowly on to the white powder. What observations can you make?
f Record any observations made during the heating process and when the water was poured back onto the anhydrous copper(II)
sulfate.

Teaching notes
Ensure that the students have clamped the test-tube at the end nearest the bung before they start the experiment, otherwise
they will be heating the clamp as well as the test-tube.
Warn about and watch for suck-back. Demonstrate how to lift the entire clamp stand and apparatus.
The reaction involved is:
CuSO4.5H2O(s) (pale blue solid) CuSO4(s) ('dirty' white solid) + 5H2O(l)
Students should observe the colour change from pale blue to white and the change back to blue when water is added. The
colour change on adding water to anhydrous copper(II) sulfate has been used as a test for the presence of water in a liquid.
The more observant should notice that the addition of water to anhydrous copper(II) sulfate is exothermic, as the tube becomes
noticeably hot if the water is added very slowly. They should therefore conclude that the same quantity of energy is absorbed
when the endothermic thermal decomposition takes place.
Perhaps in subsequent class discussion students could be asked why anhydrous copper(II) sulfate would not be a feasible fuel
for the future.
More able and older students might be asked to calculate the enthalpy change occurring during this process. They will need to
find out from a Data Book the standard enthalpies of formation for anhydrous and hydrated copper(II) sulfate, as well as that for
water.
Health & Safety checked, September 2014

Credits
This Practical Chemistry resource was developed by the Nuffield Foundation and the Royal Society of Chemistry.

 Nuffield Foundation and the Royal Society of Chemistry

Website
Wikipedia - this link gives information about the sources, uses and some reactions of copper(II) sulfate.

Page last updated October 2015