: ( ) 3ASS 2012

1
:

) H 2O2(aq

) (1)................2H 2O2(aq ) 2H 2O(l ) O2( g

)1 - .................................................................................................................................:
- ..................................................................................................................................:
- ..............................................................................................:
- ....................................................................................:
- ...................................................................................:
)2 :

) 2H 2O2(aq ) 2H 2O(l ) O2( g

........................
........................
) n 0 ( H 2O 2

.........................
........................
........................
n 0 (H 2O 2 ) ...... ........
........................
X max
)3
.
- ..............................................................................................................................:
- ............................................................................................
)4 ( )1 V 0 10,0mL C 0
V 1 85mL .
Co
10

....................................... H 2O 2

-
................................................................................................................................................
2/1

 t H 2O2 o V T

-
) x (t

...........................................................................................................................................
- ..................................................................
)5
V ' 10mL
) (K (aq ) M n (aq )O 4 C ' 2.102 mol / L V E
:
0
5
10
20
30
35
)t (min
14.60
10.50
8.40
4.70
2.42
) V E (mL
1.80

) H 2O 2 ( mmol / L

- ............................................
-
M nO 4 (aq ) / M naq2 )
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
- ' V E ,C ' ......................................................V
...................................................................................................................................................
- .Co
) H 2O2 f (t :
-
1cm 5mmol / L , 1cm 2,5min

- ..............................................................................................................
...................................................................................................................................................
- H 2O 2 t 0 :
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................

2/2