Академический Документы
Профессиональный Документы
Культура Документы
Objectives To Be discussed:
Objective 3:
Crude Oil
Objective 4:
Ammonia
Crude Oil
Separating the Components Of
Crude Oil
5. When the gas reaches a tray it passes up through it into a bubble cap, this is
a cover over the hole that pushes the gas down so that it has to bubble up
through the liquid that has already condensed onto that tray.
6. As the vapour condenses and vapourizes many times on the trays along the
column, the composition of the vapour becomes richer in the more volatile
component.
7. The more volatile components rise to the top of the column while less volatile
ones tend to condense on the trays at various levels along the column.
8. And so the crude oil is separated into different fractions, each boiling within a
particular temperature range.
Crude Oil
Uses of the Components of
Crude Oil
Gas Oil
Boiling temperature range: 275-350 degree celsius
This is about 15-20% of crude oil and is used as fuel in diesel engines and
industrial furnaces.
Kerosene
Boiling temperature range: 175-325 degree celsius
This is about 10-15% of crude oil and can be used as jet fuel and for domestic
heating.
Kerosene can also be broken down to make more gasoline.
Kerosene continued
As a derivative of petroleum, kerosene has many of he same chemical properties.
The chemical industry can use kerosene as a petroleum solvent or industry-grade
chemical lubricant.
It is also found in some pesticides and is helpful in removing head lice.
Refinery Gas
Boiling temperature range: < 20 degree celsius
This is about 1-2 % of crude oil and is mainly a mixture of alkanes containing
about 4 carbon atoms in a molecule. It is usually a gas at room temperature.
Refinery gas can be used as a gaseous fuel or it can be liquified under pressure to
produce liquified petroleum gas (LPG). It can also be used as feedstock for
making petrochemicals.
Petroleum
Boiling temperature range: < 20 degree celsius
The industry that uses petroluem to produce other chemicals is referred to as the
petrochemical industry. Petroleum is used in many industries such as:
agriculture
plastics
tyres
pharmaceuticals
dyes, detergents and fabrics
and many others.
Combustion
Crude Oil isnt necessarily pure, and when combusted may result in the evolution
of pollutants such as, SO2 , Oxides of nitrogen, CO, and BTEX compounds.
However, this method can be used to break down large hydrocarbon chains into
smaller ones to achieve the substance required. This is further explained in this
module under objective 9.6
Catalytic Cracking
This involves the use of a catalyst at lower temperatures to break the bonds of the
hydrocarbon molecules. The reaction is usually catalysed by a powdered mixture
of alumina and silica at approximately 500 degree celsius.
The C-C bond, undergoes heterolytic fission which results in a mechanism
involving carbocations. This tends to produce a large amount of branched chain
alkanes which are useful in gasoline.
Catalytic Cracking is used to crack the distilled fractions such as, diesel oil and
kerosene into smaller molecules.
The cracked compounds are important to produce more valuable fuel as well as
chemical feedstock for the petrochemical industry.
Reforming
This is a process which converts straight chain hydrocarbons into aromatic and
more highly branched hydrocarbons.
This process converts low value naphtha fractions into high grade gasoline
components.
Higher grade gasoline contains a higher proportion of branched alkanes and
aromatic hydrocarbons.
Products of reforming are also used as starting materials for the petrochemical
industry.
Did You
Know?
Reforming is the
effect of numerous
reactions such as
isomerization,
alkylation and
catalytic reforming.
Crude Oil
Impact of the Petroleum industry
on the Environment
Extraction
This involves the emissions of pollutants from the first seismic survey until the field
is shut down. Well drilling discharges oil into the surrounding soil and water. This
can damage fragile ecosystems by destroying habitats and killing organisms.
Transportation
Oil is usually transported through pipelines and in large ocean tankers. There is
always the possibility for leaks and spills which are detrimental to the
environment.
CO
This is toxic. It readily
combines with
heamoglobin to reduce its
ability to transport oxygen
in the body.
BTEX Compounds
These are possible
carcinogens which may
cause reproduction and
developmental problems or
aggravate respiratory
conditions
re made
a
t
a
h
t
s
t
Produc
oleum
from petr
e hard to
r
a
)
s
ic
t
s
(Pla
theyre
e
c
in
s
f
o
dispose
dable.
a
r
g
e
d
y
il
not read
Ammonia
CH4(g) + H2O(g)
CO(g) + H2O(g)
N2(g) + 3H2(g)
20 atm
800C
CO(g) + 3H2(g)
CO2(g) + H2(g)
2NH3(g)
Haber Process
NH3
storage
tank
Nitrogen from
fractional
distillation of
liquified air
Compressed
gas mixture
200-400 atm
Hydrogen
from steam
reforming
Reaction
chamber
500C, Fe,
Al2O3 catalyst
Unreacted
N2 and H2
recycled
Ammonia
Condenser
Uses Of Ammonia
Agricultural Uses:
As a source of Nitrogen, that is essential for plant growth
Ammonia is used in the production of liquid fertilizer solutions which
consist of ammonia, ammonium nitrate, urea and aqua ammonia. It is also
used by the fertilizer industry to produce ammonium and nitrate salts.
Ammonia and urea are used as a source of protein in livestock feeds for
ruminating animals such as cattle, sheep and goats.
Ammonia can also be used as a pre-harvest cotton defoliant, an antifungal agent on certain fruits and as preservative for the storage of
Ammonium and nitrate fertilizers are water soluble and are easily washed out farm
lands into the waterways. Excess fertlizers in rivers and streams can cause
eutrophication which leads the death of fish and other aquatic animals which rely
on oxygen for respiration.
Fertilizers can pollute drinking water since groundwater and surface water are
used as sources of domestic water supply.
Too much nitrates in drinking water is poisonous to infants. The nitrates are
converted to nitrites in infants which combine with heamoglobin more readily than
oxygen. This starves the body of oxygen and results in a bluish skin
discolouration.
This condition is called methaemoglobinaemia or blue baby syndrome.
END OF DISCUSSION
REVISION TIME!!!!!
Fractional Distillation
Naphtha
Kerosene
Diesel Oil
Residue
END OF
PRESENTATION