DEACYTELATOR (J-1)

FEED
Composition
Glucan
Xylan
Acetyl Group
Lignin
Water
T (in)
T (out)

NaOH FEED
Composition
NaOH
Water
T (in)
T (out)
PRODUCT
Composition
Glucan
Xylan
Lignin
Alcohols
Sodium Acetate
NaOH
Water
T (in)
T (out)

Mass (kg)

Cp (kJ/kg-K)
1.21
1.0961
4.88
6.86
4.184
25 Total mCp
H (feed)

Mass (kg)

Cp (kJ/kg-K)
4.184

25 Total mCp
H (NaOH)

Mass (kg)

Cp (kJ/kg-K)
1.21
1.0961
6.86

4.184
25 Total mCp
80 H (pdt)

SODIUM ACETATE FORMATION

Composition
Mass (kg) MW (kg/kmol)
Acetyl Group
NaOH
40
Sodium Acetate
82
Alcohols
H pdt
H react
H TOTAL

HYDROLYZER (J-2)

#DIV/0!

mCp
0
0
0
0
0
0
#VALUE!

mCp
0
0
0
#VALUE!

mCp
0
0
0
0
0
0
0
0
0

mol
H
#DIV/0!
0
0
#DIV/0!
#DIV/0! H rxn
#DIV/0!

nH
#DIV/0!
0
0
#DIV/0!
#DIV/0!

FEED
Composition
Glucan
Xylan
Lignin
Sulfuric Acid
Water
T (in)
T (out)

PRODUCT
Composition
Glucose
Xylose
Lignin (lqd)
Glucan
Xylan
Lignin (solid)
Sulfuric Acid
Water
T (in)
T (out)

REACTION 1
Composition
Sulfuric Acid
Glucose
Glucan
Water

REACTION 2
Composition
Sulfuric Acid
Lignin (solid)
Lignin (lqd)

REACTION 3
Composition
Sulfuric Acid
Xylan

Mass (kg)

Cp (kJ/kg-K)
1.21
1.0961
6.86
0.8282
4.184
25 Total mCp
80 H (feed)

Mass (kg)

Cp (kJ/kg-K)
1.21
1.0961
6.86
1.21
1.0961
6.86
0.8282
4.184
25 Total mCp
220 H (pdt)

Mass (kg)

Mass (kg)

Mass (kg)

mCp
0
0
0
0
0
0
0

mCp
0
0
0
0
0
0
0
0
0
0

MW (kg/kmol)
98
180
162
18
H pdt
H react

mol

MW (kg/kmol)
98
150
150
H pdt
H react

mol

MW (kg/kmol)
98
132

mol

nH

0
0
-1273.3
0
-1273.3
0
-285.83
0 H rxn 1
0

0
0
0
0
0

nH

0
0
0
0 H rxn 2
0

H
0
0

-1057.8

0
0
0
0

nH
0
0

Xylose
Water

150
18

0
-1057.8
0
-285.83
0 H rxn 3
0

H pdt
H react

LIGNIN DISSOLUTION
Composition
Mass (kg)
Lignin Solubilized

MW (kg/kmol)
150

H TOTAL

MASS OF STEAM
H total
Latent Heat

mCp
0
0
0
0
0
0
0

#DIV/0!
Q

HEAT EXCHANGER (D-2)

Composition
Mass (kg)
Cp (kJ/kg-K)
Glucose
1.21
Xylose
1.0961
n-Lignin
6.86
Sulfuric Acid
0.8282
Water
4.184
T (in)
105 Total mCp
T (out)
35 H
cooling water
Q

0
0Q
1913

EVAPORATOR (D-1)
FEED
Composition
Mass (kg)
Cp (kJ/kg-K)
Glucose
1.21
Xylose
1.0961
n-Lignin
6.86
Sulfuric Acid
0.8282
Water
4.184
T (in)
Total mCp
T (out)
H (feed) or Fhf
STEAM
Hv
Vapor
Latent Heat(stm)

mol

#DIV/0!
0

#DIV/0!

mCp
0
0
0
0
0
0
0

H
6.3139

0
0
0

nH
0

FERMENTER (J-3)
FEED
Composition
Glucose
Xylose
n-Lignin
Sulfuric Acid
Water
T (in)
T (out)

PRODUCT
Composition
L-malic
Glucose
Xylose
n-Lignin
Mycelia
Sulfuric Acid
MgCO3
Mg Itaconate
Water
T (in)
T (out)

AIR
Composition
Oxygen
Nitrogen
T (in)
T (out)

NUTRIENTS
Composition
Ammonium Nitrate

MgSO4-7H2O
KH2PO4
T (in)
T (out)

CARBON DIOXIDE
Composition
CO2
T (in)

Mass (kg)

Cp (kJ/kg-K)
1.21
1.0961
6.86
0.8282
4.184
35 Total mCp
25 H (feed)

Mass (kg)

Cp (kJ/kg-K)

mCp
0
0
0
0
0
0
0

mCp
0
0
0
0
0
0
0
0
0
0
0

1.21
1.0961
6.86
1.3382
0.8282

4.184
25 Total mCp
35 H (pdt)

mass
Mass (kg)

Cp (kJ/kg-K)
0
0.8246
0
1.017
35 Total mCp
25 H

Mass (kg)

Cp (kJ/kg-K)
1.66
1.5143
0.871
35 Total mCp
25 H (pdt)

Mass (kg)

Cp (kJ/kg-K)
0.8601
25 Total mCp

mCp
0
0
0
0

mCp
0
0
0
0
0

mCp
0
0

T (out)

ANTIFOAM
Composition
Octadecanol
Ethanol
T (in)
T (out)

35 H

Mass (kg)

Cp (kJ/kg-K)
2.6119

REACTION 1
Composition
Glucose
Itaconic Acid
Carbon Dioxide

REACTION 2
Composition
Glucose
L-malic Acid
Carbon Dioxide

REACTION 3
Composition
Itaconic Acid
MgCO3
Mg Itaconate

0
0
0
0

35 Total mCp
25 H (pdt)

MAGNESIUM CARBONATE
Composition
Mass (kg)
Cp (kJ/kg-K)
MgCO3
0.8956
T (in)
35 Total mCp
T (out)
25 H (pdt)

CULTURE
Composition
A. Terreus
T (in)
T (out)

mCp

Mass (kg)

Cp (kJ/kg-K)

mCp
0
0
0

mCp
0
0
0

35 Total mCp
25 H (pdt)

Mass (kg)

Mass (kg)

Mass (kg)

MW (kg/kmol)
180
130
44
H pdt
H react

mol

MW (kg/kmol)
180
134
44
H pdt
H react

mol

MW (kg/kmol)
130
84.3
152.3
H pdt
H react

mol

H
-1274

nH

H
-1274
-1325.9
-393.6829
H rxn 3

nH

nH

0
0
0 -393.6829
0 H rxn 3
0

0
0
0
0
0

0
0
-1095.8
0
0 H rxn 3
0

0
0
0
0

0
0
0
0

0
0
0
0

H TOTAL

ACIDULATOR (J-4)
FEED
Composition
Mass (kg)
Cp (kJ/kg-K)
Glucose
1.21
Sulfuric Acid
0.8282
Mg Itaconate
Xylose
1.0961
L-malic
n-Lignin
6.86
Water
4.184
T (in)
75 Total mCp
T (out)
35 H (feed)

PRODUCT
Composition
Mg Sulfate
Itaconic Acid
Sulfuric Acid
Xylose
L-malic
n-Lignin
Glucose
Water
T (in)
T (out)

SULFURIC ACID
Composition
Sulfuric Acid
Water
T (in)
T (out)

REACTION 1
Composition
Mg Itaconate
Sulfuric Acid
Mg Sulfate
Itaconic Acid

Mass (kg)

Cp (kJ/kg-K)

mCp
0
0
0
0
0
0
0
0
0

mCp
0
0
0
0
0
0
0
0
0
0

0.8282
1.0961
6.86
1.21
4.184
35 Total mCp
75 H (feed)

Mass (kg)

Cp (kJ/kg-K)
0.8282
4.184
75 Total mCp
35 H (pdt)

Mass (kg)

H total
EVAPORATOR (D-3)

MW (kg/kmol)
152.3
98
120.3
130
H pdt
H react
0

mCp
0
0
0
0

mol

H
0
0
-909.27
0
0
0 H rxn
0

nH
0
0
0
0
0

FEED
Composition
Itaconic Acid
Xylose
L-malic
n-Lignin
Sulfuric Acid
Glucose
T (in)
T (out)
STEAM
Hv
Vapor
Latent Heat(stm)

Mass (kg)

Cp (kJ/kg-K)

0
0
0
0
0
0
0
0

1.0961
6.86
0.8282
1.21
40 Total mCp
25 H (feed)
#DIV/0!
Q

#DIV/0!

CRYSTALLIZER (K-7)
FEED
Composition
Mass (kg)
Cp (kJ/kg-K)
Itaconic Acid
Xylose
1.0961
L-malic
n-Lignin
6.86
Sulfuric Acid
0.8282
Glucose
1.21
Water
4.184
T (in)
25 Total mCp
T (out)
40 H (feed)
CRYSTALLIZATION OF IA
Composition
Mass (kg) H Cryst (kJ/kg)
IA Crystals
IA Liquid
Xylose
-7.052
L-malic
-9.895
n-lignin
Sulfuric Acid
0
Glucose
-7.074
Water
-15.8794
H cryst
H total
0

DRYER (D-4)
PRODUCT
Composition
Itaconic Acid

mCp

Mass (kg)

Cp (kJ/kg-K)

mCp
0
0
0
0
0
0
0
0
0

mH (kJ)
0
0
0
0
0
0
0
0
0

mCp
0

Xylose
L-malic
n-Lignin
Sulfuric Acid
Glucose
Water
T (in)
T (out)

1.0961

0
0
0
0
0
0
0
0

6.86
0.8282
1.21
4.184
25 Total mCp
60 H (pdt)

WATER REMOVED
Composition
Mass (kg)
Cp (kJ/kg-K)
Water
4.184
T (in)
60 Total mCp
T (out)
25 H (pdt)
H total
0

mCp
0
0
0

Di ba natin pwede kunin ung cp through H = m cp dT ?

L - malic acid
Itaconic acid

@298K (kcal/mol)
Hc
Hf
-317.37
-263.78
-474.14
-201.06

@298K (kJ/kg)
Hc
Hf
-9901.19161084 -8230.86673319
-15248.4012944 -6466.11457429

Source
Selected Values of Heats of Combustion and Heats of Formation of Organbic
Selected Values of Heats of Combustion and Heats of Formation of Organbic

MW
-317.31
-263.78
-474.14
-201.06

kcal
mol
kcal
mol
kcal
mol
kcal
mol

1
134.0874
1
134.0874
1
130.099
1
130.099

mol
g
mol
g
mol
g
mol
g

1000
1
1000
1
1000
1
1000
1

g
kg
g
kg
g
kg
g
kg

4.184
1
4.184
1
4.184
1
4.184
1

rmation of Organbic Compounds Containing the Elements C, H, N, O, P and S

rmation of Organbic Compounds Containing the Elements C, H, N, O, P and S

kJ
kJ
-9901.192
kcal
kg
kJ
kJ
-8230.867
kcal
kg
kJ
kJ
-15248.4
kcal
kg
kJ
kJ
-6466.115
kcal
kg