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IITJEE CHEMISTRY SAMPLE PAPER IV

SOLUTIONS
SECTION I
Straight Objective Type
1.

(c)

As the size of F is very small compared to that of Cl, bond length dominates over
electro-negativity difference. Hence, dipole moment of CH3Cl > CH3F.
As F is more electro-negative than Cl, in CH3F C is more electron deficient than
that of the carbon is CH3Cl. So shared pairs of CH bond are staying more closer to
C in case of CH3F and more bond pair-bond pair electron repulsion and more will be
the HCH bond angle.

2.

(b)

Lassaignes test for nitrogen fails if the nitrogen containing compound does not
contain carbon.

Br

OCH3
3.

(b)

CH2CH2

CH3OH

CH2CH2

Br

Br

CH2CH2
Br

Br

O
4.

(c)

The compound (A) is CH3CCH(OCH3)2 because it contains CH3C group which

responds to iodoform test. It does not react with Tollens reagent, because it does not
contain CHO group.
O
On hydrolysis, it converts to CH3CCH2CHO , which can react with Tollens
reagent. The compound (a) is not possible because hemiacetals can give Tollens
reagent test.

5.

(d)

CaCO 3

CaO CO 2

(X)

CaO H 2 O
Ca (OH) 2

CaCO 3
6.

(c)

1.6 10

=
7.

(b)

X(s)
Y(s)

Ca (OH) 2
(Y)

CO 2

CO 2
19

10 4

CaCO 3

H 2O

H 2O

Ca (HCO 3 ) 2
( Z)

1
mv 2
2

h
0.123
mv

A(g) + 2B(g)
p1
(2p1 + 2p2)
2B(g) + C(g)

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Since

(2p1 + 2p2)
Kp
p
1

KP

p2

p1
4.5

8.

(a)

p2

2p 2

103 = p2.4(3p2)2 = 36 p23

4.5
1
p23
10 3
10 3
36
8
p2 = 0.05 atm
P1 = 2 .05 = 0.10 atm
p t p1 2p1 2p 2 p 2 3(p1

p 2 ) = 3(0.10 + 0.05) = 0.45 atm.

A
D C

D A

SECTION II
Reasoning Type
9.

(d)

[Cu(NH3)4]+2 has square planar geometry.

10.

(c)

CH3CH2CH2CH3 + Cl2

hv

*
CH3CH2CHCH3
Cl

11.

(c)
CH3
CH3CH2CHOCH3 + H+

CH3CH2CHOCH3
CH3 H

12.

(d)

ln

k2
k1

Ea 1
R T2

Ea 1
R T1

CH3Br + CH3CH2CHCH3
OH

1
T1

1
T2

Higher the value of Ea, greater is the

in rate.

Br

k2
ratio and hence, greater will be the increase
k1

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SECTION III
Linked Comprehension Type
PassageI
15.

(d)

16.

(b)

The feasible reaction is Cu (s) 2Ag (aq)

E 0cell

0.8 0.34

Cu (aq) 2Ag (s) as

ve

17.

(d)

18.

(d)

19.

(b)

20.

(b)

1.

(A) 2 ; (B) 3 ; (C) 2, 3 ; (D) 1, 4

2.

(A) 2, 4 ; (B) 1, 2, 3, 4 ; (C) 1, 3, 4 ; (D) 3

PassageII
NaNO2/conc. HCl at 05C results in diazonium salt formation which forms 1, 2, 3tribromobenzene with H3PO2.
SECTION IV
Matrix Match Type

SECTION V
Subjective or Numerical Type
1.

1.86 = Kf(1)
0.02046 = (1 + ) 1.86 0.01
0.02046
1
1.1
0.0186
= 0.1
[H+] = C = 0.01 0.1 = 103
pH = 3.

2.

x
m

log

1
n
kP

x
m

log k

Now, tan

1
log P
n
1
1
n
n

n=1
Intercept = log k
k 2
x
2(2) 4 .
m

tan 45
log 2