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(B)
N = mg
N mr2
mg m.2sin 2
0.1 10
2 sin30
Sol.2.
Sol.3.
(AC)
(C)
g
2sin
1rad / s.
h2
1
1 2
2R
Solving 1 2
2
Sol.4.
(AC)
P = 0.5 W
E P t
E 0.5 5 2.5J
2.5
Sol.5.
(BC)
1
0.2 v 2
2
v 5m / s
2 R 5 R 7
X '7'
Sol.6.
(AC)
1
mv 2
2
3 7
B' 10t, 0
A 'B'
For smin
ds
0
dt
Solving this
20
5
2
2
16
4
X 2 5 2
4
4
X '5'
7
3
(C)
10 3
20
AC
=
... (i)
sin
sin(90 r ) cos(r )
3
sin r ... (ii)
2
60
A
90 + r
60
20
10 3
AC = 4.1 cm
t
Sol.8.
(BD)
(r )
B 2
AC
2.07 1010 s
C'
x v 0t r sin
v 0t
r
v 0t
r
Differentiating above equations
y r r cos
v t
v x v 0 1 cos 0
D
v0t
v t
v y v 0 sin 0
r
v v x2 v y2 2v 0 sin
v 0t
2r
(AC)
= 2 v 2 v1
2 3i j
tan
1
3
1
v a
Sol.11. (BD)
Sol.12. (AC)
Sol.13. (ABCD) Maximum elongation =
2F
F
and equilibrium is at x
k
k
2F F F
k
k k
By Center of Linear Momentum
Amplitude =
Sol.14. (ABC)
9 4 3 8 4 1 8V
V 2m / s
2 1
3
12
9 3
1
4
Ef
1
1
2
2
4 1 8 2
2
2
18
Ei
1
1
2
2
4 9 8 3
2
2
198
loss = Ef Ei 18 198
Sol.15. (ABD)
180 J
On differentiating
vdv
2ax b
dx
vdv
b
ax
dx
2
acceleration
0
at x
b
2a
If x = a sin (t + )
Then V =
dx
= acos (t + )
dt
dv
= a2sin (t + )
dt
a=
aT
= 2T = const.
x
(A)
a T + 4 v = a sin (t + ).
2
2 4
4 2
+ 4 a cos (t + )
2 2
= a 4 [sin (t + ) + cos (t + )]
2 2
= a 4 = const.
2 2
Sol.19. (B)
(P) The body is in pure rolling & there is no external force on it hence there is no friction
(A), (B), (C), (D).
(Q) There is no torque about P and collision is elastic.
(B), (C), (D)
(R) There is no torque about P and collision is inelastic.
Sol.20. (C)
(B)
(S) Force acting is Mg (conservative). It will have a torque about P.
(T) Gravitational force is conservative, the force between these particles is internal force.
(A), (C), (B).
For no emergence
A 2c
sinc
c A / 2
A 1
sin
2
2
For no emergence
A c c
sin A c sin c
sin A c
sin A c 1
x2
r2 min c
2NO + O2 2NO2
1
0.5
0
1.5
0.5
1
= 1.5
n = |1.5 2.5| = 1
Change in pressure
P =
Sol.22. (BD)
1
nRT
300
=1
atm = 4 atm
12 6.25
V
Balanced equation is
3I2(s) + 6 OH
5I + IO3 + 3H2O()
G = RT nk
172.5 =
25
300 2.3 103 log K
3
log K = 30
1030 =
[OH ]6
[OH ]6
[OH] = 106
pOH = 6
pH = 8
Sol.23. (B)
PSO3 2
PSO2 2
Sol.24. (AC)
Initial
At equ.
At eq.
22 1
1.0
AB2(g)
AB(g) +
100
0
100 x
x
P = 120
120 = 100 x + x + x
= 100 + x = 120
x = 20
xx
20 20
Kp =
=5
100 x 100 20
B(g)
0
x
CH3COOH + C2H5OH
Initially :
0.1 mol
KC
0.1 mol
x2
(0.02)2
1
1
2
2
2
16
(0.1 x)
(0.08)
4
= 32 KC = 32
Sol.26. (AC)
Sol.27. (C)
Sol.28. (AC)
1
=2
16
Anhydride formation
WA B = 10 J
WAB = PV ; WBC = 0
q = E W
E = 0
q = 5 = 0 W
W = 5J = WA B + WB C + W C A
or 5 J = 10 + 0 + W C A
WC A = 5 J
SECTION 2 : (One or More Than One Option Correct Type)
Sol.30. (C)
Sol.31. (AD)
Sol.32. (BC)
Sol.34. (AD)
Sol.35. (AC)
Sol.36. (BC)
Sol.29. (BC)
Sol.33. (AD)
Sol.37. (AB)
Sol.38. (ABC)
SECTION 3 : (Matrix Match Type)
Sol.40. (C)
Sol.39. (D)
f x x 1 x 2 x 3 x 4
x2 5x 4 x2 5x 6
min
1 for t 5
M 1 M 4 3.
dy dx
1 1
x 2 y 2 2 2 x 2 y3 dy 0
x
y x
y
1 1
d
x y
1 1
1 1
d y dy 0
ydy
1
1
x y
y x
x y
ln
Sol.43. (A)
1 1 y2
c k 2.
x y
2
f 2x 2y
f 2x 2y
sin x y
sin x y
f
f
sin
sin
2
2
f x k sin
x
2
4f ' x f x 0.
Sol.44. (AD)
Since sin2
x
x
cos lies between 1 and 2 for x 2, 2
4
4
x
x
sin2 cos 1
4
4
Thus the problem reduces to finding the area bounded by x2 y2 4, y x2 x 1 and line
y=1
2
0
2 1
k 6.
3 6
Sol.45. (D)
/2
2
1
f x sin x
/2
sinx l1 l2 l3 l4
/ 2
Where, l1
sin x
sin tdt 0
k / 2
/ 2
l2
2sin x
4sin x
cos tdt
k / 2
k
l3
cos x
2cos x
t sintdt
k / 2
k
/ 2
/ 2
l4
2cos x
t cos tdt 0
k / 2
t cos t is odd
k
k
k
k
Sol.46. (D)
1
4
1 k 3.
k
k
3
f x tan1 tan x cos1 cos x for x ,
2 2
when
x x x 0
2
2
2
x 0
2
3
3
x
0 x
2
2
2
When x x
0 x
and x 2 x
f x x 2 x
area 2
Sol.47. (B)
2 32
.
4
4
tanx 0, tanx 1
log 3 3
log 3 3
log 3 tan x
1
log 3 tan x
log 3 3
t2 3 1
t
2
1
t
t 1and t
3t 2 2t 1 0
1
(not possible)
3
log 3 tan x 1
tan x
1
3
only in 0, .
6
2 x 1
x 2e ,
0 x 1
f x
ab 1
2
acos
2x
bx
,
1
2 x 1
2 x 1
2 x 2e , 0 x 1
2xe
f 'x
b2
2bx 2a sin 2x 2 , 1 x 2
Let f ' x 0
1 1 1 1 3 3
f , f , f
2 2 4 4 4 4
and so on
f x x
Let f ' x 0
1 1 1 3 3 1
f , f , f
2 2 4 4 4 4
And so on
f x 1 x
Sol.50. (AD)
esin x ecos x
cos x
sin x
f 'x
f g x x
g' 0
Sol.51. (BC)
f ' g x g' x 1
f ' g 0
dy
dy
6 x 12
dx
dx
y2 4
dy
2x
dx
dx
dy
2x
y 4
dy
6 x
3 y 4
dx
Here,
1
f ' g x
g' x
1
e1/ 2
2
5
f '
4
dx
0
dy
2x
0 y 2
But y 2 gives 8 3x 2 24 3x 2 16
y 2 3 x 2 12 2 8 16 x 2
16
3
, 2
Required point is
3
Sol.52. (AD)
A x 4 x 3 1 Bx C 4x 3 3x 2 4x 4 2x 3 3x 2 4
A 4, B 2, C 1
f x 4
x 4 x3 1
dx
x x 1
4
2x 1 4 x 3 3 x 2
x3 1
2 2x 1
x 1
3
1/2
3/2
4dx
x 1
3
1/2
2 2x 1
x3 1
1/2
f 1 6
Sol.53. (AB)
f x
1 x2
1
0
f 2 t
1 t2
dt
1 x f ' x 2xf x f x
1 x
1 x
2
dy 2x
dx 1 x 2
Let
2
y y
1
t
y
dt 2x
dx 1 x 2
1
x3
xc
solution
is
t
y
3
But f 0 1 c 1 y f x
3 1 x 2
x 3x 3
3
f 1 6
Sol.54. (ABC)
Sol.55. (BD)
Area =
ax5 bx 4 cx3 dx 2 ex f mx n dx x 1 x 2 x 3 dx
1
t 2 t 1 t 1 dt t 2 t 2 1 dt 2 t 2 t 4 1 2t 2 dt
1
1 1 2
15 35 42 16
= 2 2
105
105
7 3 5
f x 2y f x
y 0
f ' x lim
2y
y 0
2y
f ' x f x lim
y 0
2y
2y
lim
f 2y f 0
y 0
2y
x 2 lim
y 0
2y
2x
2y
f ' x f x ex f ' 0 x2 2x
e x f ' x e x f x f ' 0 2xe x x2e x
e x f ' x e x f x 1 2xe x x2e x
d x
d
e f x
x x 2 e x
dx
dx
e x f x x x 2 e x c
f x xex x2
Sol.57. (AC)
Sol.58. (ABC)
f 0 0 c 0
g x x and h x e x .
Equality is true if f(t) g(h(t)) = f(h(t)) g(t) or f(t).g(h(t)) = f(h(a + b t)) g(a + b t)
x 3 2 x 2 x 1 ,
x 3
x 3 2 x 2 x 1 , 3 x 2
Hence, f x
2 x 1
x 3 2 x 2 x 1 ,
x 3 2 x 2 x 1 ,
x 1
x 3
2,
2x 8, 3 x 2
2 x 1
i.e. f x 2x,
2,
x 1
m2 3m 4 or 2
i.e. if m2 3m 4 0 or m2 3m 2 0
i.e. if m 4 m 1 0 or m 2m 1 0
i.e. if m 4 or m 1 or 2 m 1
Sol.59. (C)
2 sin
4
minimum value = 2 .
y ' 0
6
1
(B) y acos x cos3x
3
a sin sin 0
2
6
a 2.
f ' x 0 cos x
5
x ,
3 3
a b 2.
Sol.60. (B)
1
2
1
2
equation of tangent y 1
1
x 0
2
x y
1 p q 3.
2 1
cosec x 3
f ' x 0 x R
6x2 2bx 4 0 x R
3x2 bx 2 0
b2 24 0
b 0, 1, 2, 3, 4
24 b 24
1
(C) If sin
then 0 / 2.
0 sin x 1
C3
sin x 0
C4
sin x 1
2x
L lim e
x
2x 1 2 1
x x
2
x
lim e
x
e2
(AC)
I1 I 2
I1 I 2
49
9
Solve we get
I1
I2
Sol.2.
(AC)
Sol.3.
(AB)
I1 25
I2
4
5
2
T mg cos
2
IP w osc
mgx
25
4
4
4 25
I
5
5
5 4
ml2 2
w osc mgR
12
cos 1
12gR
l2
2
2l
l
w
12gR
3gR
12
12
T
4
Sol.4.
Sol.5.
(AC)
(BD)
Image is real
v
7
u
Sol.6.
(B)
mg
7
7
7u
1 7 u
1 7 u
u8
1
2
100
1 v
100
1 2 1
kx mv 2
2
2
Sol.7.
(AC)
v 1/ ms
Particle is released at x 2
max at umin.
TEi TEf
1
10 15 mv 2
2
5 m/s
Sol.8.
(B)
V 15 10
v 30
25
1
2 2
2
30
15
v ' 10 10
v' 5
m2
5
10
Total magnification
m m1m2
30 5
15 10
m 1
Image is real & inverted.
Sol.9.
(CD)
v 2 A2 w 2 cos2 wt
cos2 wt
v2
A2w2
(1)
a2 A2 w 4 sin2 wt
a2
A2 w 4
Add equation (1) and (2)
sin2 wt
. (2)
v2
a2
1
A2 w2 A2 w 4
(A) v 2 y
ax
y
x2
1
A2 w2 A2 w 4
(B) v 2 y
a2 x
y
x
1
A2 w2 A2 w 4
(C) v y
ax
y2
x2
1
A2 w2 A2 w 4
(D) v y
(Parabola)
(Straight line)
(Ellipse)
a2 x
y2
x
2 4 1
2 2
A w
A w
(Parabola)
n mg 20 0
N mg 20
N 50 20
N 30
fmax N
0.4 30
12
30
f2
2
10
10 10
Sol.12. (ABC)
Sol.13. (ABC)
1 1 1
f v u
1 1 1
v f u
f constant
1
1
k
v
u
1
1
versus is linear
v
u
1 1 1
f v u
u u
1
f v
u u
u
1
ku 1 straight line.
v f
v
There is no external force acting on the system
a0
p 0
T 40N
a 10 m / s2
KE 40J
constant
Sol.14. (BD)
Sol.15. (ABD)
1
2 v 2 40
2
v 2 40
v a 2as
40 0 2 10 s
1
mv 2 40
2
40
Wmg Mg h
2 10 2
40 J
s 2m
2 kg
WT 40 2
80 J
20
Sol.16. (ABCD)
A
1 kg
B
1 kg
C
4 m/s
1 kg
4 m/s
v com
m1v1 m2 v 2 m3 v 3 ...... 1 4 1 4 1 0
m1 m2 m3
1 1 1
v com
8
3
2 m/s
1/3
8/3
com
2/3
4 m/s
1 8
2
3 3
w 2 rod / s
Sol.18. (A)
v2
v1
initial
Initial Pi = 0
TEi = mgh
Pf = Mv1 + Mv2
TEf
Pi = Pf
1
1
mv 22 Mv12
2
2
O Mv1 mv 2
mv 2 Mv1
v2
. (1)
Mv1
m
TEi TEf
mgh
1
1
mv 22 Mv12
2
2
mgh
1
1
Mv
m 1 Mv12
2
m
2
Solving this v1 m
2gh
M m M
Sol.19. (ABD)
f
Fnet F ma
F
m
F f ma
f F R MR2
a
R
f F R
MR2
a
R
f F ma
F f ma
a
F
;
2m
f 0
Fnet F ma
F
m
tnet FR
Sol.20. (ABC)
F f ma
2
R
fR I
a
R
fR
ma
2
ma
ma
2
3ma
2
2F
3m
m 2F
2 3m
F
3
tnet fR
PART II : CHEMISTRY
SECTION 1 : (One Integer Value Correct Type)
Sol.21. (AC)
Sol.22. (BC)
This increase in temperature is balanced by addition of ice cubes of one molecule. Thus
number of moles of ice cubes.
Sol.23. (BC)
Sol.24. (C)
pH pK a log
salt
acid
salt
0.02M
0.02M
salt
0.02M
pH 4.87 log
Sol.25. (AC)
Sol.26. (B)
Use G 2.303RTlogK
Sol.27. (BD)
Sol.28. (BD)
t0 1
t eq 1
1
3
0
1
3
n 3 3 3 3
A g B g
1
3
n nB P
Kp A
n
nAB
ng
1 1
P 1 1 3P P
P
3 3
8
6 4
8
Kp
2 4 / 3
3
Sol.30. (AC)
s Zn2 Zn OH4
2
K sp
OH
K c OH
ds
d OH
Hence
0
2K sp
OH
2K c OH 0
1/ 4
2K
OH sp
2K c
1/ 4
1.2 1017
0.13
9.8 105
pH 14 4.01 9.99
Sol.31.
1.2 1017
9.8 10
2.5 109 M.
(A)
As p-derivative give only one product whereas o & m give more than one nitro
product.
Sol.32. (ACD)
(C)
isothermal wadiabatic
Area under curve is greater for isothermal process, than that for adiabatic process.
(D) Uisothermal 0
For adiabatic process:
TV 1 constant
T1V11 T3 V31
T3 V1
T1 V3
i.e.,
Sol.33. (ABD)
Sol.36. (ABD)
Sol.37. (D)
Sol.39. (AC)
Uisothermal Uadiabatic
Sol.34. (BCD)
Sol.35. (ACD)
dH dU PdV VdP
SECTION 3 : (Comprehension Type)
Sol.38. (C)
Equilibrium is achieved at point X. In graph A, at point X, the free energy of both reactants
and products are equal and G 0 which is the characteristic of reaction at equilibrium.
Sol.40. (BD)
P
R
y=
y2 = (tan x sin x) + y
y=
z2 = x3 + z
1 1 4(tan x sin x)
1 1 4x 3
z=
2
2
y>0
y=
z>0
1 1 4(tan x sin x)
2
lim
x 0
z=
1 1 4x 3
2
1 1 4(tan x sin x)
1 1 4(tan x sin x)
2
= lim
Rationalization
x 0
3
1 1 4x 3
1 1 4x
1
2
= lim
1 1 4x3
4(tan x sin x)
tan x sin x
2
= lim
3
3
x 0
2
4x
x
1 1 4(tan x sin x)
= lim
1 cos x
sin x
= 1 1/2 =
x
x2
x 0
x 0
Sol.42. (C)
x3 z
1
2
2 1
Let A = cosec1 3x 1 4 + sec1 3x 4
2 1
2 1
1 3x
1 3x
= cosec1
+
sec
4
4
where 3x2 +
1
1
4
1
3x 2 = 1
12
A=2
y = f(x) = 4x x 2x + 1
1 1
,
2 4
1
3
1
2
f(x) ; 0 x 2
g(x) = f(1/ 2) ; x 1
2
3 x ; 1 x 2
1
1
5
1
3
5
So g =
; g =
; g = 3 .
4
4
4
2
4
4
Sol.44. (AC)
From graph it is clear that m 0, = 5
2
(0, a)
|x| + |y| = a
x2 + y2 = a2
| x| | y| a
Sol.45. (CD)
(a, 0)
(a, 0)
(0, a)
a2 1 2 ( 2)a 2
a =
4
2
4
1 2
a
2
|y| =
= (9 2)
Now
a
0
( a x )2 dx
a2
12
A2 1
A1 3
9 2
2 , A = 9,
B=1
A+B1=9
9
2 x12
x 2
x1 (0,
2)
2 x12
&y=
9
x1
9
x 22
x 22
9
mN = +
9
x2
= x23 x24 = 81
as x2 R
x2 = 3
x2 = 3
y2 = 3
Hence minimum distance =
32 32 2 =
3=2
x (y dx + x dy) + y3 (y dx x dy) = 0
xd (xy) = y (x dy y dx)
xd (xy) = x2y3 d
Y
y = 3/16
On integrating
1
1 y
xy 2 x
+c
at (4, 2)
+ c c = 0 y3 = 2x y = ( 2x)1/3
Since y = g(x) =
sin2 x
sin 1 t dt
1/ 8
cos2 x
cos1 t dt
1/ 8
(constant)
c1 = (sin1 + cos1) dt =
y = g (x) =
3
y dy
2
1 3
.
8 16
sq. units.
f() =
x2 x 1 x2 x 1
1
dx
cot 1
2
3 2x
1 x
2x 3x
x = 1
1
dt
t2
dx =
t cot
f() =
t 2 t 1 t 2 t 1 1
2t 3 3t 2 2t t 2 dt =
.....(1)
1 t cot
t2 t 1 t2 t 1
2t 3 3t 2 2t dt
1 t cot
t 2 t 1 t 2 t 1
dt
3 2t 2t 3t 2
....(2)
2f() =
1 t
= ln ln 1 = 2 ln
2
| x 3x 2 | | ( x 1)( x 2) | 1 dx
Now g()
| x 1 | | x 1 |
1
ln
Odd functioni.e. f ( x ) f ( x )
ln
g() =
ln
1.dx dx
1
= ln ln = 2 ln
1
ln
a+ b = 7
SECTION 2 : (One or More Than One Option Correct Type)
Sol.49. (ACD)
2sec 2 x
4 tan x
sec 2 x
4 tan x
f(x) = n (4 + tan x) + c
f(x) 0, so f (x) =
f(x) =
8
8
1 cos x 1 cos x
4
16
=
2
| sin x |
1 cos x
= 4|cosec x|
this is a periodic function.
(D)
1
1
f(x) = x + x + 2[ x]
2
2
Sol.51. (AB)
1
1
= x + x + 2 [ x]
2
2
1
1
1
1
= x x x x + 2 ( x { x})
2
2
2
2
1
1
= x x 2 { x}
2
2
f(x) = 0
Sol.52. (BD)
f(x) is into
2
x 2 , 1 x 2
2
2x , 1 x 2
x 2
f(x) =
f (x) =
, 2x3
2
x , 2x3
11
,
x3
3
function is increasing in each of the two intervals (1, 2) and (2, 3) but not in [1, 3]
Clearly least value of f(x) is 3 and greatest value of f(x) does not exist.
Sol.53. (AB)
Domain of sin1x and cos1x, each is [1, 1] and that of sec1x and cosec1x,
each is (, 1] [1, )
Domain of f(x) must be {1, 1}
Range of f(x) will be {f(1), f(1)}
where f(1) = sin1(1) cos1(1) tan1(1) cot1(1) sec1(1) cosec1(1)
6
3
3
= =
and f(1) = 0 {as cos1 1 = 0}
64
2
4 4
2
(i)
Thus, the graph of f(x) is a two point graph which
doesn't lie above x - axis
(A) is correct statement
(ii)
(iii)
(iv)
36
64
64
6
(1,0)
1, 3
64
f(x) is one
Sol.54. (ACD)
x
Sol.55. (BD)
(A)
We have
(t 1) sin t dt
Lim
x 1
(x 1)3
0 form
0 Lim sin( x)
Lim sin(1 x)
0 = x 1 3(x 1) = x 1 3(x 1)
Lim sin (x 1)
=
(1) =
x 1
3
(x 1)
3
3
(B)
(C)
g(x) dx = (1 sin t)
........... (i)
sin t
g(sin t) =
Putting
........... (ii)
in (2),
4
t=
1
g
= 2
2
We get
1
x
2 y
2
3
x
2
We have
y
3
2
(D)
3
3
x2 y
x2y 4
4
Maximum value = 4
Sol.56. (AC)
We have
a
sin1 ex cos1 ex ex
1
ex
.
dx
=
dx
1 x 2x
1 a
2 (tan1 ea tan1 e x ) (e 2x 1)
1
tan e tan e e
a
I=
Put tan1ex = t
I=
=
tan1 ea
ex
dx = dt
e2x 1
tan1 ea
dt
= ln(t tan1 ea )
1 a
0
(t tan e )
2
(B & C)
n
x
x
f(x) = lim cos
1
1 cos
= nlim
n
n
= e
x
lim cos
1 n
n
= e
1
lim 2sin2
n
2
x
n
n
1
2
n
1
n
= e
= e
x
x
1n
e 2
41
n
2 lim
y = f(x) = ex/2, x 0
g(x) = lim (1 x + x
range = (0, 1]
n
e )n
x
1
lim x
= en
(en 1)
1/n
1
= ex
1
x R
x
= ny
2
x = 2n
1
y
f1(x) = 2n
1
x
0<x1
y = g(x) = ex
g1(x) = nx
x = ny
Sol.59. (D)
1
g1 2 n = n 2 n for 0 < x < 1
x
1
h(x) = tan1 n n 2 for 0 < x < 1
x
f() = f() = 0
Hence k
Let f(x) = tan1x
then for some a (x, y), f() =
tan1 y tan1 x
(LMVJ)
yx
tan1 x tan1 y
1
=
2
xy
1
|tan1x tan1y| |x y|
END OF Solution