The level of dissolved oxygen in a water sample can be determined by the

Winkler method. In a typical analysis, a 100.0-mL sample is made basic, and

treated with a solution of MnSO4, resulting in the formation of MnO2. An excess
of KI is added, and the solution is acidified, resulting in the formation of Mn2+
and I2. The liberated I2 is titrated with a solution of 0.00870 M Na2S2O3,
requiring 8.90 mL to reach the starch indicator end point. Calculate the
concentration of dissolved oxygen as parts per million of O2.

Jawaban :
Diketahui : 100 ml sampel(H20)
Na2S2O3 0,00870 M = 8,90 mL
Indikator amilum
Jawaban :
reaksi
H20 + MnSO4

MnO2 +H2SO3

MnO2 + H2SO32- +2KI

I2+2 Na2S2O3

MN

2-

2+

+ I2 + K2SO4+H2O

2 NaI +NA2S4O6

BE O2 = 32/4 = 8
N Na2S2O3 = 0,00870/2 = 4,35.10 -3
KOK mg/L 02 = v Na2S2O3 x N Na2S2O3 x BE O2 x 1000/ Volume sampel
=8,9 mL x 4,35x10-3 x 8 x 1000/100
= 3,0972mg/L