I assume your scenario is to send a notification from workflow as soon as good receipt is created.

To trigger the workflow, you have to use the business object MKPF. Also, you will have to implement a BAdI
named 'MB_DOCUMENT_BADI at method MB_DOCUMENT_BEFORE_UPDATE .In this method call the function
module 'SAP_WAPI_CREATE_EVENT' to trigger the workflow.

Alternative to BAdI, you can use the enhancement spot MB_MIGO_BADI or user exit EXIT_SAPLMBMB_001
to trigger the workflow.

Inside the workflow, create a send mail step for sending notification.