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  • Chapter 3

    Загружено:

    Prasad Yarra
    49 просмотров2 страницы
    This document discusses gravimetric analysis methods for quantitatively analyzing various analytes. It lists the analyte, precipitate formed, measured form of the precipitate, and common interferences for each analyte. Gravimetric analysis relies on precipitating the analyte as an insoluble salt and weighing it. Various metal ions can be analyzed by precipitating salts such as sulfates, chromates, oxides, and complexes. Non-metal analytes include anions that precipitate as silver, barium, or other salts that can be isolated and weighed. Interferences that also form insoluble precipitates with the same ions must be avoided or accounted for.

    Исходное описание:

    gravimetric analysis

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    This document discusses gravimetric analysis methods for quantitatively analyzing various analytes. It lists the analyte, precipitate formed, measured form of the precipitate, and common interferences for each analyte. Gravimetric analysis relies on precipitating the analyte as an insoluble salt and weighing it. Various metal ions can be analyzed by precipitating salts such as sulfates, chromates, oxides, and complexes. Non-metal analytes include anions that precipitate as silver, barium, or other salts that can be isolated and weighed. Interferences that also form insoluble precipitates with the same ions must be avoided or accounted for.

    Авторское право:

    © All Rights Reserved
    Скачайте в формате PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    49 просмотров2 страницы

    Chapter 3

    Загружено:

    Prasad Yarra
    This document discusses gravimetric analysis methods for quantitatively analyzing various analytes. It lists the analyte, precipitate formed, measured form of the precipitate, and common interferences for each analyte. Gravimetric analysis relies on precipitating the analyte as an insoluble salt and weighing it. Various metal ions can be analyzed by precipitating salts such as sulfates, chromates, oxides, and complexes. Non-metal analytes include anions that precipitate as silver, barium, or other salts that can be isolated and weighed. Interferences that also form insoluble precipitates with the same ions must be avoided or accounted for.

    Авторское право:

    © All Rights Reserved
    Скачайте в формате PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    из 2

    5/25/2016

    Chapter3.Gravimetry

    Analyte

    Precipitate

    Measuredform

    Interferences

    K+

    KB(C6H5)4

    KB(C6H5)4

    NH4+ ,Ag+ ,Hg2+ ,Tl+ ,Rb+ ,Cs+

    Mg2+

    Mg(NH4)PO4.6H2O

    Mg2P2O7

    Manymetals(nonefrom
    Na+ andK+ )

    Ca2+

    CaC2O4.H2O

    CaCO3orCaO

    Manymetals(nonefromMg2+ ,
    Na+ andK+ )

    Ba2+

    BaSO4

    BaSO4

    Na+ ,K+ ,Li+ ,Ca2+ ,Al3


    + ,Cr3+ ,Fe3+ ,Sr2+ ,Pb2+

    Ti4+

    TiO(5,7dibromo8
    hydroxyquinoline)2

    TiO(5,7dibromo8
    hydroxyquinoline)2

    Fe3+ ,Zr4+ ,Cu2+ ,C2O42,citrate,


    HF

    VO43

    Hg3VO4

    V2O5

    Cl,Br,I,SO42,
    CrO42,AsO43,PO43</sup>

    Cr3+

    PbCrO4

    PbCrO4

    NH4+ ,Ag+

    Mn2+

    Mn(NH4)PO4.H2O

    Mn2P2O7

    Interferencesfromnumerous
    metals

    Fe3+

    Fe(HCO2)3

    Fe2O3

    Interferencesfromnumerous
    metals

    Co2+

    Co(1nitroso2
    naphtholate)3

    CoSO4(byreactionwith
    H2SO4)

    Fe3+ ,Zr4+ ,Pd2+

    Ni2+

    Ni(dimethylglyoximate)2

    Ni(dimethylglyoximate)2 Pd2+ ,Pt2+ ,Bi3+ ,Au3+

    Cu2+

    CuSCN

    CuSCN

    NH4+ ,Pb2+ ,Hg2+ ,Ag+

    Zn2+

    Zn(NH4)PO4.H2O

    Zn2P2O7

    Interferencesfromnumerous
    metals

    Ce4+

    Ce(IO3)4

    CeO2

    Th4+ ,Ti4+ ,Zr4+

    Al3+

    Al(8hydroxyquinolate)3

    Al(8hydroxyquinolate)3

    Interferencesfromnumerous
    metals

    Sn4+

    Sn(cupferron)4

    SnO2

    Cu2+ ,Pb2+ ,As(III)

    Pb2+

    PbSO4

    PbSO4

    Ca2+ ,Sr2+ ,Ba2+ ,Hg2+ ,


    Ag+ ,HCl,HNO3

    NH4+

    NH4B(C6H5)4

    NH4B(C6H5)4

    K+ ,Rb+ ,Cs+

    Cl

    AgCl

    AgCl

    Br,I,SCN,S2,S2O32,CN

    http://www.csudh.edu/oliver/che230/textbook/ch03.htm

    1/2

    5/25/2016

    Chapter3.Gravimetry

    Br

    AgBr

    AgBr

    Cl,I,SCN,S2,S2O32,CN

    AgI

    AgI

    Br,Cl,SCN,S2,S2O32,CN

    SCN

    CuSCN

    CuSCN

    NH4+ ,Pb2+ ,Hg2+ ,Ag+

    CN

    AgCN

    AgCN

    Cl,Br,I,SCN,S2,S2O32

    (C6H5)3SnF

    (C6H5)3SnF

    Exceptalkalimetals,many
    interferences,
    andSiO44,CO32

    ClO4

    KClO4

    KClO4

    SO42

    BaSO4

    BaSO4

    Na+ ,K+ ,Li+ ,Ca2+ ,Al3


    + ,Cr3+ ,Fe3+ ,Sr2+ ,Pb2+

    PO43

    Mg(NH4)PO4.6H2O

    Mg2P2O7

    Manyinterferencesexcept
    Na+ ,K+

    NO3

    Nitronnitrate

    Nitronnitrate

    ClO4,I,SCN,CrO42,ClO3,
    NO2,Br,C2O42

    CO32

    CO2(byadditionofacid)

    http://www.csudh.edu/oliver/che230/textbook/ch03.htm

    CO2

    CO2istrappedasNa2CO3on
    Ascarite

    2/2

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