(Group A)

Attempt any six questions; 6x2 = 12

1. Define the terms: (a) extensive properties
(b) intensive
properties.
2. Starting from a suitable Grignard's reagent how would you obtain
2,2-dimethylpropanol.
3. What are symmetrical and unsymmetrical ethers? Give example and
their IUPAC names.
4. Draw resonance hybrid structure of Phenol and Phenoxide ion.
Which one is stable and why?
5. Calculate the pH value of 10-7M HCl solution.
6. How many coulombs of electricity are required to change 100ml of
0.1M Cr2O72- to Cr3+?
7. Carry out the following conversions:
(i) phenol to anisole and (ii) ethyne to ethanol.
8. Taking an example of acidified KMnO4 solution derive the relation
between equivalent and molar conductance.

9. Give an example of : (a) Oxo Process and (b) Esterification.

10. An aqueous solution of copper sulphate is acidic, basic or neutral?
Explain.
(Group B)
Attempt any two questions:
11. Silver is electrodeposited on a metallic vessel of surface area
800cm2 by passing a current of 0.2 ampere for 3 hours. Calculate the
thickness of silver deposited. Given the density of silver as 10.47g/cc
and atomic mass = 107.92amu.
12. Write short notes on: (any one)
(a) Oxidation of primary, secondary and tertiary alcohol.
(b) Reduction reactions of nitrobenzene in different media.
13. Predict whether zinc and silver react with 1M sulphuric acid to
give out hydrogen gas or not. Given that the standard reduction
potentials of zinc and silver are -0.76V and 0.8V respectively.
14.Explain why electrophilic substitution in bezaldehyde takes place at
meta position? Which of the following test is more suitable for
benzaldehyde and why? (a) Tollen's Test and (b) Fehling's test.