IN Resonence” Educating for better tomorrow TARGET : JEE (ADVANCED) 2016 Course : VIJETA & VIJAY (ADP & ADR) Date : 10.04.2016 TEST INFORMATION DATE : 13.04.2016 PART TEST-01 (PT-01) Syllabus : Inorganic Nomenclature, Periodic table, Chemical bonding and Coordination compounds. DPP No. # 02 (JEE-ADVANCED) Total Marks : 169 Max. Time : 118 min. Single correct Objective ('-1' negative marking) Q.1 to Q.15 (3 marks, 2 min.) (45, 30] One or more correct objective (no negative marking) 2.16 to. 2.20 (4 marks, 2 min.) _—_—[20, 10] Single digit integer type ('=1" negative marking) Q.21 to 0.28 (4-marks, 3 min.) —_[36, 27] Assertion and Reason (‘-1' negative marking) @.30 to @.32 (3 marks, 3 min.) [09, 09] Comprehension ('-1" negative marking) Q.33 to Q.41 (3 marks, 2 min.) (27, 18] Match the Following (no negative marking) @.42 to Q.45 (8 marks, 6 min.) __[32, 24] 4. During the complete combustion of ethene C,H,, what change in hybridisation does the carbon atom undergo? (A) sp°to sp. (8) sp to sp? (©) sp? to sp. (©) sp? to sp* 2, Which ofthe following substances ges not exhibit H-bonding with water ? (A) CH,CH,OH @ch-J-oh © ch,-cH,-cH, NCH, 3. Inwhich ofthe following pairs, the number of lone pair(s) over central atom and molecular geometry is same? )TeCI,, PCL (®)CIF,, PCl, (©) Sicl, BF (OBI, XeF > 4. Inwhich of the following, the x-bonds can lie in same plane ? Ry )CI-C=C-Cl_— (B)O=C=0 oa =CH (DN, H Br 5. What is the maximum number of electrons which can be accommodated in an atom in which the highest principal quantum number is 4? (a)10 18 (©)36 O54 6. The ligand N(CH,CH,NH,), is (A) tridentate @tetradentate (C)didentate (O)pentadentate Resonance’ fan easton Spo ae Educating for beter tomorow | Freres SGU ZOU UT THON PEE GEES] CON, URSSOAR SOOT COPIERS ee10. 1. 12, 13, 14. 15. 16" The correct name forthe complex [Pt(NH,),Cl,], which has maximum planes of symmetry is (A) cis-platinum tetrachlorodiammine (@)trans-platinum tetrachlorodiammine (©) trans-Diamminetetrachloroplatinum(IV) (©) cis-Diammine tetrachloroplatinum (IV) Which of the following pairs of coordination compound show same type of isomerism ? (A) [Co(NH,)-B1] SO, and [Ni(dmg),] (®) [PUNH,,Cl,] and [Cofen),8rCIIC1 (C) [Co(NH,),J[CM(CN),] and K[PIC!,(C,H,)} () [Ni(en),P* and [Pt(en),* The correct electronic configuration for [CrF,}* will be A) tye," Bert? Cte! Oe,'t,” 4-nitrophenyl hydrazine is an example of (A) a tridentate ligand (@) abidentate ligand (©) amonodentate ligand (O)atetradentate ligand What is the coordination number of La in the compound [La(EDTA) (H.0),). 3,0 ae es ©10 O12 Which among the following will be named as dibromobis(ethylenediamine)chromium (Ill bromide ? (A) [Cr(en),Br,1Br, @)[Cr(en),81,]81, (©) [Cr(en), Br, Br (©) [er(en),Br, 9 ciel cis, is cated benzoylacetonato. Bis(Benzoylacetonate)berylium wll show (A) structural isomerism, (®) geometrical isomerism (©) optical isomerism (0) None of these In which of the following pairs of elements the electronegativity ofthe first element is less than that of second element ? (A)ALGa Lik (c.s FCI Which of the following can not show linkage isomerism ? NH, a (8)NO; (ocn- ON; Which among the following is stronger lewis bases than HN(SIH.,), ? (NH, (®)H.NCH) ()H.NGIH) © @) mw SS | Educating for better tomorrow | FearpreeyaoS TO SET TAO [PEE S555] CIN: UBDIOIRIZ00TPLOUDAOZS Metina7 18° 19" a. 22. 23. 24. 25. 26, 27. In which of following silicate(s), the number of comers shared per tetrahedron is > 2? (A) Four membered cylic silicate (®)Pyrosilicate (©) Chain silicate (O)2-Dsilicate Which of the following is/are correct ? (A) vander Waal's radius of iodine is more than its covalent radius (B)Allisoelectronic ions belong to the same period of periodictable (C) First ionisation eneray of Be is more than that of C (0) Electron affinity of N as well as noble gases is negative. How many nodal suface can be present in the molecular orbital formed by the overlap of sand p, (X axis is the molecular axis)? (a2 1 ©s3 (O) None of these Which of the following show intramolecular hydrogen bonding ? (A) salicylaldenyde (@)onitrotoluene COOH (©) p-nitrophenol (O) hydrogenpthalate ion CL coo" 1 i How many types of C-O bond length are present in CH, -C-CH,-CH-C-0° ? I OH How many of the following compound can be optically active ? (@) [Co(en),C1B1] (b)[Co(en)(NH,),CL}* — (c) [Cr(NH,),CLIY (@ [Co(NH.),CL) (e) [Coven)..* (INi@mg),] (@) [PED TA (h) [Cr(ox)(amg) 4 [Cr(dmg),} The sum of oxidation state of Co and Cr inthe following complex is [Co(NH,),] [enNH,),Cl, How many of the following species use 4. orbital in their hybridization ? (a) [Ni(CN) (b) (CoBr,> (@)NH,CI (a) XeF, (©) [Cr(NH) 1” ICuNH.) @ Fer iy Find total number of N-Cr-O bond angles in tris(glycinato)chromium (II) Find the value of x + y where x and y indicate number of H atoms in H,Fe(CO), and H/Re(CO), respectively. (EAN rule is followed) How many of the following relations is/are correct ? (a) Mg > Al (electropositive character) (b)Al> Ga (electronegativity) (©) N'>N (lonization energy) (d) Se> S (magnitude of 4H) (e) He* > H (Atomic size) () 02 <0, (paramagnetic nature) (9) C, > N, (Number of x bonds) (h) F, > B, (bond order) () B,> F, (bond length) () NO3> NO; (bond angle) mw SS Educating for better tomorrow | FearpreeyaoS TO SET TAO [PEE S555] CIN: UBDIOIRIZ00TPLOUDAOZS eben28. 29. 30. 3. 32. How many N atoms in cyanuric amide (melamine) are sp? hybridized ? ens A, N, No i nH, Mer 5 rgcMe X CuSO, +KCI (excess) > Y The color of species X and hybridization of Cu init are respectively. (A) Deep blue and sp? (©) Blue and sp? (©) Deep blue and dsp? (0) Black and dsp? mw SS Educating for better tomorrow | FearpreeyaoS TO SET TAO [PEE S555] CIN: UBDIOIRIZ00TPLOUDAOZS Meiealinaehd34. 36. IUPAC name of Yis (A) Potassium (tetrachloride) disulphate copper (I) (©) Potassium tetrachloridocuprate (I) (©) Potassium tetrachloridocopper (I) (©) Dipotassiumeuprate(t) chloride To Y, excess KCN is added due to which a highly stable complex results. This complex is (A) [Cu(CN),* paramagnetic (© [Cu(CN),* paramagnetic (©) [Cu(CN),)~ diamagnetic (©) [Cu(CN),* diamagnetic. Comprehension # 2 36, 37. 38. ‘Sulphur forms numerous compounds and show variety of oxidation states. It also exhibit a good tendency of catenation. It forms variety of oxoacids and oxoanions also. Sulphur also occur in several biomolecules and Is also used in chemotherapy as sulphadrugs. ‘Sulphapyridine was shown to be effective drug against pneumonia NH, SO.NH yy (Sulphapyridine) What isthe hybridization of in this compound (A) sp? (@) spd (rsp (sper NH,-SO,H is called as sulphamic acid. NH,-CO,H is called as carbamic acid. Using this knowledge, find which formula is correctly matched with name ? (A) Calcium sulphamate => Ca(N-SO,H) —_(B) Aluminum pyrophosphate = Al,(P.0,), (C) Sodium carbamate = Na(NH,-COO) (©)Ammomium thiosulphate > (NH,)S,0, Among the following compounds of sulphur, which contain no SS bond ? AHS! (B)H,S,0, (©)Na,S,0,, (0) Caso, Comprehension #3 39. Electronegativity is a feature which is relative and depends on several factor like oxidation number, hybridizations etc. For instance, the electronegativity of differently hybridized carbon are sp 2.99 sp 2.68 sp? 2.48 Which of the following contain all carbon of equal electronegativity ? (A) Propene (®)Propadiene (©)Cyclopropene (©) Cyclopropane mw SS Educating for better tomorrow | FearpreeyaoS TO SET TAO [PEE S555] CIN: UBDIOIRIZ00TPLOUDAOZS eceanee40. 4. 42. 43. Which of the following is correct ? HC=CH H,C-CH, , H.C @ ©) CH, (A) The C~C c bond is of equal strength in (a) and (b) (B) The C-C a bondis stronger in (a) than (c) (©) The C=C a bondis stronger in (b) than (c) () The CC cbondis stronger in (c) than (a) The direction of dipole of C=O is from Oto C, This means theres slight positive charge on O. This can be explained by (A) higher electronegativity of O (©) positive formal charge on © Column W)XeOF, @)S0,Cl, ()Cocl, (HCI, Column (A) Na{Co(ox),] (©) [RhCKCO)(PPh,)(NH)] (C) KICK(NH,) (CN), (©) BalCoBr,Cl,] Column (A)Mn0,- ()Mn02 (oy euen),> ()Ni(dmg), (8) sp hybrization of C (@)Allofthese Column it (p) Central atom is sp hybridized with no lone pair on it (@ Central atom is sp? hybridized (9 Central atom involves 4,2_,2 orbital in hybridization. (8) Contain central atom in oxidation state, two less than the highest, Column it (p) Show geometric isomerism. (@) Low spin complex. (9 Paramagnetic with more than two unpaired electrons, (8) Show colligative property comesponding of {wo particles per formula. ( Electrically conducting Column it (p) Paramagnetic and colored (@) Diamagnetic and colored. (9 Diamagnetic and colorless (6) Tetrahedral complex. () Square planar complex. mw Se Educating for better tomorrow | FearpreeyaoS TO SET TAO [PEE S555] CIN: UBDIOIRIZ00TPLOUDAOZS PAGE NO.45. Column (A) B> Be > Li (B)NaCa (0) S>Se Column it (P) Electronegativity (Q) lonization energy (9 Atomic radius (6) Metallic nature. (Acidic nature of oxide IDPP No. # 01 (JEE-ADVANCED) 15. 22. 29. 36. 42. Oo 2 ® 3 (Oe) 10) © 16 cD) 17. Asse) 2A SD eo) els ® 7% B® % (A)-1;(8)-s;(C)-p;(O)-4 (A)~s:8)-p.4;(C)-4,5;O)-a.r 45. ANSWER KEY Oo 4 ® & A & A F O Oo 1 ® 2 O8 8B © & AW (ABC) 18. (BD) 19. (ABD) 20. (ACD) 21. 5 2 2 6 2% 1 2 25 2B ® 2 B® 3 OQ 34, A % © ® % A 0 OO 4 & 43. (A)-a, 5; (B)-4,8; (C)-a,r; O)-s @-4:@)-4;(C)-a.5,t;@-nt Se Educating for better tomorrow | FearpreeyaoS TO SET TAO [PEE S555] CIN: UBDIOIRIZ00TPLOUDAOZS PAGE NO.