.

1 Physics

IiW Directions: Questions No.1, 2 arid 3 a re based an the following pa rag ra ph,

Wave property of electrons implies that they will show diffraction effects_ Davisson and Germer demonstrated this by diffracting electrons from crystals. The low governing the diffraction from a crystal is obtained by requiring that electron waves reflected from the planes of atoms in a crystol interfere constructively [see figure),

Incoming Electrons

Outgoing Electrons

d

1. Electrons accelerated by potential V are diffracted from a crystal. If d == 1 A and i == 30°, V should be about (h = 6.6 x 10-34 J- s , me = 9.1 x 10-31 kg, e == 1.6 x 10-19 C)

(a) 2000 V (b) 50 V

(c) 500 V (d) 1000 V

2. If a strong diffraction peak is observed when electrons are incident at all angle i from the normal to the crystal planes with distance d between . them (see figure), de-Broglie wavelength AcW of electrons can be calculated by the relationship (n is an integer)

(a) d sin i == nAdB (b) 2d cos i == nAd/!

(c) 2d sin i = n/-dB Cd) d cos i = nt-dB

3. In an experiment, electrons are made to pass through a narrow slit of width d comparable to their de-Broglie wavelength. They are detected on a screen at a distance D from the slit (see figure).

Crystal Plane

Which of the following graphs can be expected to represent the number of electronsN detected as a function of the detector position y (y = 0 corresponds to the middle of the slit)?

(a) ___d;

IV '--it.

(C)__d;

N "it

(b) __d;

N yt

(d) __d;

N~t_

4. A planet in a distant solar system is 10 times more massive than the earth and its radius is 10 times smaller. Given that the escape velocity from the earth is J] kms ", the escape velocity from the surface of the planet would be

(a) 1.1 km S-1 (b) 11 krn 5--1

(c) 110 km S-l (d) 0.11 km S-l

5.. A spherical solid ball of volume V is made of a material of density Pl' It is falling through a liquid of density P2 (P2 < PI)' [Assume that the liquid applies 3. viscous force on the ball that is proportional to the square of its speed v, i.e., Fviscous = - kv2 (k > 0)1. The terminal speed of the ball is

.--~~-

(a) ~Vg(Plk - p~2

(c) JV~l .

(b) VgPI k

(d) Vg(pj -P2) k

6. Shown in the figure adjacent is a meter-bridge set up with null deflection in the galvanometer. The value of the unknown resistor R is

55Q

R

'---------t 1-----0) , .... >-- --~

(a) 13.7sn Ce) 110 o

(b) 2200 (d) ss n

7. A thin rod of length L is lying along the x-axis with its ends at x = 0 and x -= L. Irs linear density

(mass/length) varies with x as k( f r, where II can be zero or any positive number. If the position xeM, of the centre of mass of the rod is plotted against n, which of the following graphs best approximates the dependence of XCM 01111'

(al +~ ~l~. .

~n or - n

'E=XCM Xq.~~------ .

Ce) (d) ~. .. --------,

II 0': n

8. While measuring the speed of sound by performing a resonance column experiment, a student gets the first resonance condition at a column length of 18 em during winter. Repeating

the same experiment during summer, she measures the column length to be x em for the second resonance. Then

(a) 18> x

(b) x » S4

(c) 54> x> 36 Cd) 36> x » 18

9. The dimensions of magnetic field in M, L, T and C (Coulomb) is given as

(a) [MLT"'lC1]. (b) [MT2c-2]

(c) [Mrlc1] Cd) [MT-2et]

10. Consider a uniform square plate of side a and mass m. The moment of inertia of this plate about an axis perpendicular to its plane and passing through one of its corners is

5 2 I 1 2

(a) -rna (0) .. ·-ma·

6 12

7 . 2

ec) - ma2 (d) - llla2

12 3

11. A body of mass m = 3.513 kg is moving along the x-axis "With a speed of 5.00 ms'". The magnitude of its momentum is recorded as

(a) 17.6 kg ms" (b) 17.565 kg ms'

(c)" 17.56 kg ms-1 (d) 17.57 kg ms .t

12. An athlete in the olympic games covers a distance of 100 I1l in 10 s. His kinetic energy can be estimated to be in the range

(a) 200 J - 500 J

(b) 2 x 105 J - 3 X 105 J

Cc) 20,000J -'50,000 J (d) 2,000 J - 5,000 J

13. A parallel plate capacitor with air between the plates has a capacitance of 9 pF. The separation between its plates is d. The space between the plates is now filled with twO dielectrics. One of the dielectrics has dielectric constant K, -= 3 and

thickness ~. while the other one has dielectric

3

constant K2 -= 6 and thickness 71_. Capacitance of 3

the capacitor is now (a) 1.8 pF

(c) 40.5 pF

(b) 4S pF

Cd) 20.25 pF

14. The speed of sound in oxygen (02) at a certain temperature is 460 rns ". The speed of sound in helium (He) at the same temperature will be (assume both gases to be ideal)

ea) 460 ms " (b) 500 ms'"

ec) 650 ms-1 Cd) 330 ms-1

mar Directions: Question numbers 15 to 16 are Assertion·Reason type questions. Each of these questions contains two statements : Statement I (Assertion) CJnd Statement /I (Reason), Each of these question also has four olternotive choices, only one of which is the correct answer. You have to seled the cotrect choice.

(0) Statement I is folse, Statement II is true

(b) Statement I is true, Statement II is false; Stotement II is a correct explanation for Statement I

(c) Statement I is true, Statement II is true; Stotemeni [I is not a correct explanation for Statement I (d) Statement [ is true, Statement II is false

15. This question contains Statement I and Statement II. Of the four choices given after the statements, choose the one that best describes the two statements.

Statement I : Energy is released when heavy nuclei undergo fission or light nuclei undergo fusion.

and

Statement II-: For heavy nuclei, binding energy per nucleon increases with increasing Z while for light nuclei it decreases with increasing Z.

16. This question contains Statement J and Statement II. or the four choices given after the statements, choose the one that best describes the two statements.

Statement I : For a mass M kept at the centre of a cube of side a, the flux of gravitational field passing through its sides is 4 rc GM.

and

Statement II : If the d i rection of a field due to a point source is radial and its dependence. 011 the

distance r from the source is given as~, irs flux

r

through a closed surface depends only on the strength of the source enclosed by the surface and not on the size or shape of the surface.

17. Ajar is filled with two non-mixing liquids 1 and 2 having densities PI and P2 respectively. A solid ball, made of a material of density P3' is dropped in the jar. It comes to equilibrium . in the position shown in the figure.

Which of the following is true for P1> pz and P3 ?

(a) P3<Pl <pz (b) PI >P3 >P2

(c) PI <1'2 <1:)3 (d) PI <P3 <P2

- 18. A working transistor with its three legs marked P, Q and R is tested using a multimeter. No conduction is found between P and Q. By connecting the common (negative) terminal of the 'mulrimeter to R and the other (positive) terminal to P or Q, some resistance is seen on the multimeter, Wil ich of the following is true for the transistor?

(a) It is an npn transistor with R as base

(b) It is a pnp transistor with R as collector (c) It is a pnp rransistor with R as emitter (d) It is an npn transistor with R as collector

IIlW Directions: Questions No. 19 and 20 are based on the following paragraph.

Consider 0 blOCK of conducting material of resistivityp shown in the figure. Current I enters at A and leaves from D. We apply superposition pr-inciple to find voltcqe IW developed between 8 and C. The calculotion is done in the follOWing steps:

(i) Toke current I entering from A and assume it to spreod over a hemispherical surface in the block

I "v I

(ii) Calculate field E{r) at distance t from A by using Ohm's low E:;: pl, where J is the current per unit area at r. (iii) From the r dependence O'f E(r), obtain the potential Vir) at r.

(iv) Repeat P), (ii) and (iii) for current Ileoving D and superpose results for A and D.

19. 6V measured between Band Cis

Ca) pI _ __l!!____ (b) pI _~

Jill n(a+ b) a (a+ b)

(e) _£!_ _. pI Cd) ---.P!.~._

21!a 2lt(a_+ b) - 211:(a- b)

20. For current entering at A, the electric field at a distance r from A is

(a) .s: (b) P;

. 811,2 ,

pI Cd) ..2!_

(c) -2 .2

211:r 4m

21. A student measures the foeallength of a convex lens by putting an object pin at a distance II from the lens and measuring the distance v of the image pin .. The graph between u and v plotted by the student should look like

v (ern) ~
Cal / (b)
a ~( (em) )
_).(mi) v (em)
(c) (d) -,
a u (em) 0 /I (em) 22. A block of mass 0.50 kg is moving with a speed of 2.00 ms-1 on a smooth surface. It strikes another mass of 1.00 kg and then they move together as a single body. l11e energy Joss during the collision is

(a) 0.16 J (b) 1.00 J (c) 0.67 J on 0.34J

23. A capillary tube (A) is dipped in water. Another identical tube eB) is dipped in a soap-water solution. Whidl of the following shows the relative nature of the liquid columns ill the two tubes?

(a)

(b)

, (c)

Cd)

24. Suppose an electron is attracted towards the origin by a force ~., where k is a constant and r is

T

the distance of the electron from the origin. By applying Bohr model to this system, the radius of the nth orbital of the electron is found to be r" and

the kinetic energy of the electron to be T". Then which of the foHowing is true?

1 2

(a) TQ o: -2' Tn OC II 11

(b) T~ independent of rt, r" oc n 1

(c) t ;«>, rn ecn n

1 .

(d) Tnoc-,r"ocn2 n

25. A wave travelling along the x-axis is described by the equation yex, t) "" 0.005 cos (ax - Bt). If the wavelength and the time period of the wave are 0.08 m and 2.0 s, respectively, then a and 13 in appropriate units are

(a) (X = 25.00 "It, f3 = n

(b) 0: = 0.08 , 13 := 2.0

1t. "It

C-) - 0.04 Q ~ 1.0

c a --~'F-~· ~

11: -n

- n

(d) 0. = 12.50 n, p =0 _. 2.0

.26. Two coaxial solenoids are made by winding thin insulated wire over a pipe of cross-sectional area A = 10 cm2 and length = 20 CIn. If one of the

solenoids has 300 turns and the- other 400 turns, their mutual inductance is

U-to "" 41t xlO-7TmA -I)

(a) 2.411: x10-5 H

(b) 4.8.1t x 10-4 H

(c) 4.8 11: x 10-5 H

(d) 2An-xl0-4 H

27. In the adjacent Circuit, A and B represent two inputs and G represents the output,

The circuit represents (a) NOR gate

(b) AND gate

(c) NAND gate

{d) ORgate

28. A body 'is at rest at x = O. Att ~ 0, it starts moving in the positive x-direction with a constant acceleration. At the same "instant another body passes through x =.= 0 moving in the positive x-direction with a constant speed. The position of the first body is given by Xl (t ) after time t and

that of the second body by xz(t) after the same time interval. Which of the following graphs correctly describes (Xl - X 2) as a. function of time t?

(aJ ]:;, ~J L,

ec)

(dJ:CL,

29. An experiment is performed to find the refractive index of glass using a travelling microscope. In this experiment distances are measured by

(a) a vernier scale provided on the microscope (b) a standard laboratory scale

(c) a meter scale provided 011 the microscope (d) a screw gauge provided on the microscope

30. A thin spherical shell of radiUS R has charge Q spread uniformly over its surface. Which of the following graphs most closely represents the electric field E(r) produced by the shell in the range 0 :::; r < <>J, where r is the distance from the

centre of the shell?

(aJ I . ~J EL

~~

(c) r A

~

A 5 V battery with internal resistance 2.0 and a iv battery with internal resistance 1 n are connected to a 10.0 resistor as shown in the figure.

31.

5V 2Q

2V 111

100

PI

The current in the 10 n resistor is (a) 0.27 A,Pz to PI

(b) 0.03 A, P1 to Pz

(c) 0.03 A, P2 tOPl

Cd) 0.27 A, PI to Pz

32. A horizontal overhead powerline is at a height of 4 m from the ground and carries a current of 100 A from east to west. The magnetic field directly below it on the ground is

Q.to :=4n: x10-7 TmA-1)

(a) 2.5 x 10-7 T, southward (b) 5 x 10-6 T, northward (c) 5 x 10.0.6 T, southward Cd) 2.5 x 10-7 T, northward

33. Relative permittivity and permeability of a material are s, and f.t r> respectively. Which of the following values of these quantities are allowed for a diamagnetic material?

(a) s, = 0.5, J.l r := 1.5

(b) s, '" 1.5, J.l P' = 0.5

Cc) s = 0.5, ~t r ~ 0.5

(d) Er:= 1.5, u , = 1.5

34. Two full turns of the circular scale of a screw gauge cover a distance of 1 mm on its main scale. The total number of divisions on the circular scale is 50. Further, it is found that the screw gauge has a zero error of - 0.03 mm. While measuring the diameter of a thin wire, a student notes the main scale reading of 3 mm and the number of circular scale divisions in line with the main scale as 35. The diameter of the wire is

(a) 3.32 rom (b) 3.73 mm

(c) 3.67 mm (d) 3.38 mm

35. An insulated container of gas has two chambers separated by an insulating partition. One of the

chambers has volume Vi and contains ideal gas at pressure PJ and temperature TI• The other chamber has volume V2 and contains ideal gas at pressure P'l. and temperature T2.lf the partition is removed without doing any work on the gas, the final equilibrium temperature of the gas in the container will be

ea) TlT2(PlVi + P21!~ (b) PJViTl + pzV2Tz

Pt Vi~2 + pzV2T1 PJ Vi + P2V'J.

(c) PlltJ.T2 + P2V2Tj Cd) TtT2(Pt Vi + P2V2)

PI VJ + P2 V2 PI Vj_T] + pz VzT z

.".

1. The organic chloro compound, which shows complete stereochemical inversion during a SN 2 reaction is

(a) (C2Hs)2CHCl (c) (CH3)2CHCl

(b) (CH3)3CCl Cd) CI:i3C1

2. The coordination number and the oxidation state of the element 'E' in the complex [E(enMCp4)]N02 (where (en) is ethylene diamine) are, respectively,

(a) 6 and 2 (b) 4 and 2

(c) 4 and 3 (d) 6 and 3

3. Identify the wrong statements in the following (a) Chlorofluorocarbons are responsible for ozone layer depletion

"cb) Greenhouse effect is responsible for global - warming

(c) Ozone layer does not permit infrared radiation from the sun to reach the earth

(d) Acid rains is mostly because of oxides of nitrogen and sulphur

4. Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives

(a) 2,4,6-trinitrobenzene (b) o-nitrophenol

(c) p-nitrophenol

(d) nitrobenzene

5. Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and then heated with cuprous bromide. The reaction mixture so formed contains

(a) mixture of a-and p-bromotoluenes (b) mixture of a-and p-dtbromobenzenes (c) mixture of a-and p-bromoanilines

Cd) mixture of a-and m-brornotoluenes

6. In the following sequence of reactions, the alkene

affords the compound 'B'

03 H20

CH3CH =CHCH3 -~ A ~ B. The

compound B is

(a) CJ-I:Pi2CHO (c) CH3CH2COCH3

Cb) CH3COCH3 Cd) CH;P'IO

7. Larger number of oxidation states are exhibited by the actinoides than those by the lanrhanoides, the main reason being

(a) 4f orbitals more diffused than the Sf orbitals (b) lesser energy difference between Sf and 6d

than between 4f and Sd orbitals

(c) more energy difference between Sf and 6d than between 4f and 5d orbitals

(d) more reactive nature of the actinoids than the lanthanoids

8. In which of tile following octahedral complexes of Co (at no 27), will the magnitude of 110 be the highest?

. (a) (Co(CN)6]3-

(c) [CO(HP)613+

(b) [CoCC20,,)a]3- Cd) [Co(NH'3)6]3+

9. At 80°C, the vapour pressure of pure liquid 'A' is 520 mmHg and that of pure liquid 'B' is 1000 mmHg. If a mixture solution of 'A' and 'B' boils at 80°C and 1 atm pressure, the amount of 'A' in the mixture is (1 arm = 760 mmHg)

(a) 52 mole per cent (b) 34 mole per cent (c) 48 mole per cent (d) SO mole per cent

10. For

a reaction

1

-A __, 2B.

2

rate

disappearance of 'A' is related to the rate of appearance of 'B' by the expression

(a) _ d [AJ "'.!_ d[B] (b) _ d[A] '" 1 d[B]

dt 2 dt dt' 4 dt

(c) __ d[A] = d[B] (d) _ d[A] = 4 d[B]

dt dt dt dt

11. The equilibrium constants K PI. and K P.l for the reactions X ~ 2Y and Z ~ P + Q, respectively are in the ratio of 1 : 9. If the degree of dissociation of X and Z be equal, then the ratio of total pressure at these equilibria is

(a) 1: 36 (b) 1 : 1

(c) 1 : 3 (d) 1 : 9

12. Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below :o

AhvdHG

eng)' Cnaq)

The energy involved in the conversion of ~CI2Cg)

2

to cnaq) (using the data,

AdisfIg12 = 240 kJ mol ",

6r",Hc1 = - 349 kJ rnol ",

D.hydHCI := - 381 kJ mol-1)will be

(a) + 152 kJ mol " (b) - 610 kJ mol "

(c) - 850 kJ morl

(d) + 120 kJ mol "

13. Which of the following factors is of no significance for roasting sulphide ores to the oxides and not subjecting the sulphide ores to carbon reduction directly?

(a) Metal sulphides are thermodynamically more stable than CSz

(b) CO2 is thermodynamically more stable than CS2

(c) Metal sulphides are. less stable than the corresponding oxides

(d) CO 2 is more volatile than CS2

14. Bakelite is obtained from phenol by reacting with

Ca) (CH20H)2 o» CH3CHO

(c) CH3COeH3 Cd) HCHO

of

15. For the following three reactions L II and III, equilibrium constants are given

l. eoCg) + H20(g) ~ COz(g)+ Hz(g); x, II. CH4(g) + H20Cg) ~ COCg)+ 3H2(g); K2

III. CH4Cg) + 2Hz0Cg) ~ C02Cg)+ 4H2Cg); KJ Which of the following relations is correct?

(a) K1·JK; =K3 (b) K2K3 =K1

(c) K3 = KjK2 Cd) K3K~ = K~

16. The absolute configuration of

H02e C02H

HO~OH (b) R, R (d) S, R

(a) S, S (c) R, S

17. The electrophile, E9 attacks the benzene ring to generate the intermediate a -complex, Of the following, which a-complex is of lowest energy?

(a) J; (b) Gf~

X

NOz

(d) @i;

i3 -0-( + j-glucose are (1) epimers

(d) enantiomers

18. a-DC + )-glucose and (a) conformers

(c) anomers

19. Standard entropy of X 2' Y2 and X'1':3 are 60! 40 and 50 JIC1 mol ", respectively. For the reaction, 1 3

- X 2 -l- - Y2 ~ XY3' MI = - 30 kJ, to be at

2 2

equilibrium, the temperature will be

(a) 1250 K (b) 500 K

(c) 750 K (d) 1000 K

20. Four species are listed below

0) HCO; (ii) H30'"

(iii) HSO:; (iv) HS03F

Which one of the following is the correct sequence of their acid strength?

(a) (iv) < (ii) < (iii) < (0

(b) (ii) < (iii) < (i) < (iv)

(c) (0 < (iii) < (ii) < (iv)

(d) (iii) < (i) < (iv) < (ii)

21. Which one of the following constitutes a group of the isoelecrronic species?

(a) C~-, 0;:, CO, NO (b) NO+, C~-, CW, N2

ee) eN"', N2, O~-, CO~- (d) Nz, 0;, NO+, CO

22. Which one of the following pairs of species have the same bond order? (a) CN"' and NO+ (c) 0; andCN"'

(b) CW and CN" (d) NO" and CN+

23. The ionisation enthalpy of hydrogen atom is 1.312 x 106 J mol ". The energy required to excite

the electron in the atom from n '"" 1 to n = 2 is

(a) 8.51 xlOs J mol'" - (b) 6.56 :><105 J mol "

(c) 7.56 xl0" J mol'" (d) 9.84 xl05 J mar']

24. Which one of the following is the correct statement?

(a) Boric acid is a protonic acid

(b) Beryllium exhibits coordination number of six

(e) Chlorides of both beryllium and aluminium have bridged chloride structures in solid phase

(d) BzH6· 2NH3 is known as 'inorganic benzene'

25. Given E"3+ ""-O.72V,Eoa,, ",-OAlV.

CI' ICr Fe Ire

The potential for the cell -

Crl Cr3+(0.IM)11 Fe2+(0.OIM) I Fe is

(a) 0.26 V (h) 0.399 V

Cc) - 0.339 V (d) - 0.26 V

26. Amount of oxalic acid present in a solution can be determined by its titration with KMn04 solution in the presence of H2SO 4' The titration gives unsatisfactory result when carried out in the presence of HCl, because HCI

(a) gets oxidised by oxalic acid to chlorine

(b) furnishes H+ ions in addition to those from oxalic acid

(c) reduces permanganate to Mn 2+

(d) oxidises oxalic acid to carbon dioxide and water

27. The vapour pressure of water at 20~C is 17.5 mmHg. If 18 g of glucose (C6H1Z06) is added to 178.2 g of water at 20°C, the vapour pressure of the resulting solution will be

(a) 17.675 mmHg (b) 15.750 mmHg

(c) 16.500 nunHg Cd] 17.325 mmH.g

28. Among the following substituted silanes the one which will give rise to crosslinked silicone polymer on hydrolysis is

(a) R4Si (c) R~iC12

(b) RSiC13 (d) R3SiCI

29. In context with the industrial preparation of hydrogen from water gas (CO + H21 which of the following is the correct statement?

(a) CO and H2 are fractionally .separated using differences in their densities

(b) CO is removed by absorption in aqueous Cu 2C12 solution

(c) H2 is removed through occlusion with Pd

(d) CO is oxidised to CO2 with steam in the presence of a catalyst followed by absorption 0[C02 in alkali

30. In a compound atoms, of element Y from ccp lattice and those of element X occupy 213rd of tetrahedral voids. The formula of the compoun!:J will be

(a) X4Yg (c) X2Y

(b) XZY3 (d) X3Y4

31. GoLd numbers of protective colloids A, B, C and D are 0.50, 0.01, 0.10 and 0.005, respectively. The correct order of their protective powers is

(a) D < A < C < B (b) C < B < D < A

(c) A <C <B-<D (d) B <D <A <C

32. The hydrocarbon which can react with sodium in liquid ammonia is

(a) CHgCH2CH~C =CCH2CHzCH3 (b) CH3CH2C-· CH

(c) CH3CH =CHCH3

(d) CH3CH2C ""'" CCH2CH3

33. The treatment of CH3MgX with CHsC =c - H produces

(a) CHg-CH=CH2 (b) CH3C ~C -CH3

H H .

I I

(e) CH3-C ____;C-CH3 (d) CH4

34. The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC system of nomenclature is

(a) -COOH, -S03H,-CONH2,-CHO (b), -S03H, -COOH,-CONH2,-CHO (c) -eHO, -COOH,-S09.H,-CONH2 Cd) -CONH2, - CHO,-SO sH,-COOH

35. The pKa of a weak acid, HA, is 4.80. The pKb ora weak base, BOH, is 4.78. The pH of an aqueous solution of the corresponding salt, BA, will be

(a) 9.58 (b) 4.79

(c) 7.01 Cd) 9.22

1. AB is a vertical pole with B at the ground level and A at the top. A man finds that the angle of elevation of the point A from a certain point C on the ground is 60°. He moves away from the pole along the line BC to a point D such that CD = 7 m.". From D the angle of elevation of the point A is 45°. Then, the height of the pole is

(a) 7.../3 (~) m (b) 7.../3 (.../3+ l)m

2.J3-1 2

7.../3 7J3( 1 )

(c) -(J3-l)m (d) - -- m

2 2 J3+1

2. It is given that the events A and B are such that

peA) oo.!., P (~) =.!. and p(!!_) =~. Then, PCB)

4 B 2 A 3

is

1 (a) -

6 2 (c) - 3

(b) .!. 3

Cd) .!. 2

3. A die is thrown. Let A be the event that the number obtained js greater than 3. Let B be the event that the number obtained is less than 5. Then, peA uB)is

3

(a) _. (b) °

5

(c) 1

on ~ S

4. A focus of an ellipse is at the origin. The directrix is the line x = 4 and the eccentricity is .!.. Then, 2

the length of the semi-major axis is

(a) ~ (b) ~

3 3

Cc) ~ (d) ~

3 3

5. A parabola has the origin as its focus and the line x = 2 as the directrix. Then, the vertex of the parabola is at (a) (0,2) ec) (0, 1)·

(b) (I, 0) Cd) (2,0)

6. The point diametrically opposite to the point P(1, 0) on the circle x2 + y2 + 2x + 4y - 3 = 0 is

(a) (3, - 4) (b) (- 3, 4)

(c) (~3, - 4) (d) (3, 4)

7. Let f: N -,) Y be a function defined as f(x);" 4x+ 3 where Y ={y EN : y =4x+ 3 for some x EN}. Then, the inverse of f(x1 is

3y+ 4 y+:3

(a) g(Y)=-3- (b) g(Y)=4+-4~

(c) g(y)=y+~ «n g(y)=y-3

4 4

8. The conjugate of a complex number is~. Then,

. I-I

that complex number is

(a) __ 1_ (b) _I_

i-I i+1

. (c) -~- Cd) _1_

i+I i-I

9. Let R be the real line. Consider the following subsets of the plane R x R

S == {(x, y) : y = x + 1 and 0 < x < 2}

T = {(x, y) : x - y is an integer}. Which one of the following is true ?

Cal Neither S nor T is an equivalence relation

onR

(b) Both S arid T are equivalence relations on R (c) S is an equivalence relation on R but T is not Cd) Tis an equivalence relation on R butS is not

10. The perpendicular bisector of the line segment joining PC1, 4) and Q{k, 3) has y-intercept - 4. Then, a possible value of k is

(a)_1 (b) 2

(c) -2 (d) - 4

11. The solution of the differential equation dy = x + y satisfying the condition y (1) = 1 is

dx x "

(a) y = log x + ~ (b) Y = x log x + x2

(c) Y = xe(x-l) Cd) y = x log x « x .

12. The mean of the numbers a, b, 8,5, 10 is 6 and the variance is 6.80. Then, which one of the following gives possible values of a and b ?

(a) a == 0, b= 7 (b) a = S, b =: 2

(c) a=l, b=6 (d) a", 3, b=4

13. The vector it ;, (I i + 2) + ~ k lies in the plane of the vectors b ;1 -+- j and ~ = J+ k and bisects the

0-+ ...

angle between band c. Then, which one of the

following gives possible values of a and 13 ?

(a) a'" 2, 13 == 2 (b) 0: = 1, 13 == 2

(c) a =2, 13 == 1 (d) a = 1, 13 = 1

~ ,-) , _,.

14. The non-zero vectors a, band c are related by

--.t :-t ...;.. _ -:-t ~>

a = 8 band c = -7 b. Then, the angle between a

-,

andc is

Ca) °

(b) ~ 4

Cd) rr

Ce) ..::. 2

15. The line passing through [he points (5, 1, 0) and (3, b, 1) crosses the yz-plane at the point

(0 ~_.7_. _- .1.3). Then

, 2' 2 '

(a) a'" 2, b = 8 (e) a=6, b=4

(b) a=4,b", 6 Cd) a"" 8, b "" 2

16.

If the straight lines

x-l y-2 z-3

._-- =--.

2 3

and

k x-2 _J --3 :=.z-1

k 2

3

intersect at a poirn, then the integer k is equal to

(a) - 5 (b) 5

(e) 2 (d) - 2

Il¥ Dlredion!>: Question Ilumbers 1 7 to 21 are Assertioll-Reoson Iype questions. Eaell of these questions con to ins r.1I0 statements : Stofel11e,~t I (kserlioll) Gild StoJemem /I (Reason). Each 01 these question- also has four oltemative choices, oilly one of which IS the correct answer', You have to select Ihe Correct choice.

(a) Stoternent I is leise, Statement II is true

(b) Statement I is true, Statement II is true; S\otement ll is a correct explonofion for Stctement I

(c) Statement I is true, Statement II is true, Statement II is not (1 correct explanation for Statement I (d) Srcremerd I is true, Stcrsment II is Iolse

17. Statement I : For every natural number n 2: 2,

J 1 1, -

:Ii + 0,;,15.1- ••• , + ,il~ > e,,! n .

Statement II; For eVE:IY natural number n z 2, ,,in(,, + i5 < n+ 1.

18. Let A be 2 x 2 matrix with real entries, Let I be the 2 x 2 identity matrix" Denote by tr(A), the sum of diagonal entries of A. Assume that A 2. "" 1 .

Statement. I If A ¢ J and A '" - I, then

det(A) ",-l.

If A '!' I and A ot - J, then

Statement n tr(A) '" O.

19. Statement I : f (r + 1) 't: r = (n + 2) 2'1-1 .

l[

Statement II : L: (r + 1) 't C XC

= (1 + x)" + nx {1 + ;{'j'--l •

20. Let p be the statement "x is an irrational number", q be the statement 'Jr is a transcendental number" and r be the statement "x Is a rational number iffy is a transcendental number".

Statement I : r is equivalent to either q or p Statement II: r is equivalent to -(p 0- q)

21. In a shop there are five types of ice-creams available, A child buys six ice-creams,

Statement I : The number of different ways the child can buy the six ice-creams, is lOCS '

Statement II : The number of different ways the child can buy the six ice-creams is equal to the number of different ways of arranging 6 A's and 4 B's in it row.

22. c r:» I(X-l)Sin _1_, if x s l

• Let' J (x) "" 1· x-I

0, if x 0= 1

Then, which one of the following is true?

(8) fis neither differentiable at x = Onor at x = 1

(b) f is differentiable at x '" 0 and at x = 1

(c) f is differentiable at x '" 0 but not at x "" 1 (d) f is differentiable at x = 1 but not at x = 0

23. The first two terms of a geometric progression add up to 12. The Slim: of the third and the fourth terms is 48. If the terms of the geometric progression are altemateiy positive and negative, then the first term is

(a) -4 (e) 12

(b) - 12 Cd) 4

24. Suppose the cubic x3 - px + q has three distinct real roots where p > 0 and q > O. Then, which one of the following holds 7

(a) The cubic has minima at \I~ and maxima at

_ fE'

V3

(b) The cubic has minima at -l.fE and maxima at \' 3

,.'

(c) The cubic has minima at bOth~; and - Vll~

r- r:-

Cd) The cubic has maxima at both Vi, _e and - ,J E.

3 j 3

25.' How many real solutions does the equation x7 + 14x5 + 16x3 + 30x - 560", 0 have?

(a) 7 (b) 1

ee) 3 Cd) 5

26. The statement p --? (q --? p) is equivaJ~nt to

(a) p --? (p ---7 q) (b) p ---7 (p v q)

(c) p --} (p A 11) (d) p ---7 (p t-)- q)

27 Th 1 f ( -'1 5 -1 2''1 .

. e va tie a cot. cosec "3 + tan 3) IS

(a) .~ (b) ~

17 17

ec) It Cd) 157

28. The differential equation of the family of circles with fixed radius 5 unit and centre 011 the line y '" 2is

(a) (x - 2)y,2 = 25 _ (y _ 2)2

(b) (y-2)y,2=:25-(y-2i (c) (y-2iy,2 = 25-(y":2)2 (d) ex - 2P 1'2 = 25- (y- 2)~

1 . 1

J sin X f cos x

Let I = -- ,- dx and J "" ----r=- dx .

o ""Xu -s x

Then, which one of the following is true?

(a) f > ~ and J> 2 (b) [<.3 and J < 2

3 :3

ee) I < ~ and J > 2 Cd) I > .3 and J < 2

3 3

29.

30. The area of the plane region bounded. by the curves x + 2y2 := 0 and x + 3y2 '" I is equal to

(a) ~ sq unit

3

( ) 2 .

c - sq umt 3

(b) .!. sq unit 3

(d) ~ sq unit 3

The value of.J2 f "~in(. ~J',' is sin x--

4

(a) x + log I cos ( x - %) 1+ c

I ( 'J I

(b) x -log I sin lx _!5. + c.

\ 4 :

ec) X+logisin(x-~)i+c

(d) x-log I cos( x ~~)!+ c

32. How many different words can be formed by jumbling the letters in the word MISSISSIPPI in which no two S are adjacent?

(a) 8 be;, ?C4 (b) 6·7·sC4

(e) 6.8JC4 Cd) 7· 6c4• sC4

31.

33,. let G, b, c be any real numbers. Suppose that there are real numbers x, y, z not all zero such that x", cy + bz, Y = (IZ + ex and z = bx -+ ay. Then, a2 + b2 + c1 + 2abe is equal to

(a) 2 (b) - 1

eel 0 Cd) 1

34. Let A be a square matrix aU of whose entries are integers. Then, which one of the following is true?

(a) If det CA) '" ± 1, then A ·:1 exists but ali its

entries are not necessarily integers

(b) If det (A) oF ± 1, then A-I exists and all irs

entries are non-integers

(c) If det (.4)= ± 1,. then A"'1 exists and all irs

entries are integers

(d) If det (A) = ± 1, then Kl need not exist

35. The quadratic equations

x2-6x 10=0

and x2-cx+6=O

have one root ill common. The other roots of the first and second equations are integers in the ratio 4 : 3. Then, the common root is

(a) 1 (b) 4

(c) 3 (d) 2

24. Suppose the cubic x3 - px + q has three distinct real roots where p > 0 and q > O. Then, which one of the following holds 7

(a) The cubic has minima at \I~ and maxima at

_ fE'

V3

(b) The cubic has minima at -l.fE and maxima at \' 3

,.'

(c) The cubic has minima at bOth~; and - Vll~

r- r:-

Cd) The cubic has maxima at both Vi, _e and - ,J E.

3 j 3

25.' How many real solutions does the equation x7 + 14x5 + 16x3 + 30x - 560", 0 have?

(a) 7 (b) 1

ee) 3 Cd) 5

26. The statement p --? (q --? p) is equivaJ~nt to

(a) p --? (p ---7 q) (b) p ---7 (p v q)

(c) p --} (p A 11) (d) p ---7 (p t-)- q)

27 Th 1 f ( -'1 5 -1 2''1 .

. e va tie a cot. cosec "3 + tan 3) IS

(a) .~ (b) ~

17 17

ec) It Cd) 157

28. The differential equation of the family of circles with fixed radius 5 unit and centre 011 the line y '" 2is

(a) (x - 2)y,2 = 25 _ (y _ 2)2

(b) (y-2)y,2=:25-(y-2i (c) (y-2iy,2 = 25-(y":2)2 (d) ex - 2P 1'2 = 25- (y- 2)~

1 . 1

J sin X f cos x

Let I = -- ,- dx and J "" ----r=- dx .

o ""Xu -s x

Then, which one of the following is true?

(a) f > ~ and J> 2 (b) [<.3 and J < 2

3 :3

ee) I < ~ and J > 2 Cd) I > .3 and J < 2

3 3

29.

30. The area of the plane region bounded. by the curves x + 2y2 := 0 and x + 3y2 '" I is equal to

(a) ~ sq unit

3

( ) 2 .

c - sq umt 3

(b) .!. sq unit 3

(d) ~ sq unit 3

The value of.J2 f "~in(. ~J',' is sin x--

4

(a) x + log I cos ( x - %) 1+ c

I ( 'J I

(b) x -log I sin lx _!5. + c.

\ 4 :

ec) X+logisin(x-~)i+c

(d) x-log I cos( x ~~)!+ c

32. How many different words can be formed by jumbling the letters in the word MISSISSIPPI in which no two S are adjacent?

(a) 8 be;, ?C4 (b) 6·7·sC4

(e) 6.8JC4 Cd) 7· 6c4• sC4

31.

33,. let G, b, c be any real numbers. Suppose that there are real numbers x, y, z not all zero such that x", cy + bz, Y = (IZ + ex and z = bx -+ ay. Then, a2 + b2 + c1 + 2abe is equal to

(a) 2 (b) - 1

eel 0 Cd) 1

34. Let A be a square matrix aU of whose entries are integers. Then, which one of the following is true?

(a) If det CA) '" ± 1, then A ·:1 exists but ali its

entries are not necessarily integers

(b) If det (A) oF ± 1, then A-I exists and all irs

entries are non-integers

(c) If det (.4)= ± 1,. then A"'1 exists and all irs

entries are integers

(d) If det (A) = ± 1, then Kl need not exist

35. The quadratic equations

x2-6x 10=0

and x2-cx+6=O

have one root ill common. The other roots of the first and second equations are integers in the ratio 4 : 3. Then, the common root is

(a) 1 (b) 4

(c) 3 (d) 2

I.Answers.1
Q PHYSICS
1. (b) 2. (b) 3. Cd) 4. (e) , 5. (a) 6. (bl 7. (a) 8. (b) 9. (el 10. (d)
11. (a) 12. (d) 13. (e) 14. (*) 15. (a) 16. (e) 17. (d) 18, (a) 19. (e) 20. (e)
21. (el 22. (c) 23. (e) 24. (bl 25. (a) 26. (d) 27. ,(d) 28. (b) 29. (a) 30. (a)
'31. (e) 32. (e) 33. (b) 34. (d) 35. (a)
Q CHEMISTRY
1. (d) 2. (d) 3. (el 4. (b) 5. (a) 6. (d) 7. (b) 8. (a) 9. (d) 10. (bl
11. (a) 12. (b) 13. (e) 14. (d) 15. (c) 16. (bl 17. (bl 18. (c) 19. (el 20. (el
21. (b) 22. (a) 23. (d) 24. (e) 25. (a) 26. (c) 27. (d) 28. (b) 29. (d) 30. (a)
31. (e) 32. (b) 33. (d) 34. (a) , 35. (e)
e MATHEMATICS
1. (b) 2. (b) 3. (c) 4. (a) 5. (bl 6. ,(e) 7. Cd) 8. (e) 9. (d) 10. (d)
11. (d) 12. (d) 13. (d) 14. (d) 15. (c) 16. (a) 17. (b) 1,8. (d) 19. (b) 20. ( .. )
21. (a) 22. (e) 23.' (b) 24. (a) 25. (b) 26. (b) 27. (a) '28. (c) 29. (bl 30. (d)
31. (c) 32. (d) 33. (d) , 34. (c) 35. (d)
Note: '*' None of the given options is.correct, 1. For constructive interference,

2dcos i == nil. == ,.;_ on substituting values we

v2meV '

get, V::: so V.

2. Expression is given by 2d cos i == n"'.m.

3. As diffraction pattern has to be wider than slit width, so (d) is the correct option.

4. Mass of planet, M p == 10M., where M. is mass of earth,

Radius of planet, Rp == R., -where R, is radius of

10 -

5. The forces acting on the ball are gravity force, buoyancy force and viscous force. When ball acquires terminal speed, it is in dynamic equilibrium, let terminal speed of ball is VT' SO,

Vpzg + kv; = VPlg

111, == ITO"Y;-=(P-l-.-- ••. P-z-:'"·)g~V . k

6. From balanced Wheatstone bridge concept, 5SO: 20

-----

R 80

R =2200

7.

fXdm XCM =-1-dm

x=o x~L

~1!Z·=~1

If n == 0,

. L

thenXCM """2

As rt increases, the centre of mass shift away from x = !:._ which only option (a) is satisfying,

2

Alternately, you can use basic concept.

X J(i)' xxdx ~L[n + 1_]

CM L (x)n. n+2

f k -, dx -

o L

8. II == 18 em

VI

f =411

f == 3v2, where ~ '" x according to given situation 4lz

and also VI < Vz as during- summer temperature would be higher:

3v2 =2l

4lz 411

G '" 311 X v2 VI

X = 54 x (A quantity greater than 1)

So,

9. From ~

x>54

F =qvB

[MLr2] =(C][Lr1)[B]

[B) =(MC-1r1)

. 2 10. Moment of inertia of square plate aboutXYisma 6

moment of Inertia about ZZ'can be computed using parallel axis theorem

y

, 2

Izz, =t» + m(~)

ma2 ma2 2ma2

=-,~.+~-==--.

6 2 3

11. m = 3.S13kg and v = 5.00 m/s So, momentum, p = mv = 17 .S65

12.

As the number of significant digits in m is 4 and ill v is 3, so, p must have 3 significant digits

p = 17.6 kgms :'

Question is somewhat based all approximations. Let mass of athlete is 65 kg.

Approx velocity is 10 m/s

KE= 65xl00 =3750J

So, 2

So, option Cd) is most probable answer.

c = C1C2 ..• (0

C! + C2

13.

where

c _ KlEOA 1 - d/3

C _ K2f:oA 2 - 2dJ3

... (ii)

and

... (iii)

.. h f~A9F

It IS given t at d" P'

On substituting Eqs. (ii) and (iii) in Eq. CO, we get the result Ceq = 40.5~IF ~

Speed of sound is given by, II = ,/T:;

r R; r~R;

V02 =\/-\2 and vHt '"" \1) 4-

V02 _ [t.: 3 x 4

VUe - V 5 X 32 X 5

~ vHe == 460 X 10 x Vr;; = 1420 m/s.

No option matching.

IS. Here, Statement I is correct and Statement II is wrong can be directly concluded from Binding energy/nucleon curve,

16. Correct option is (c) you can make an analogy with Gauss's law in electrostatics.

17. PI < pz as denser liquid acquires lowest position of vessel.

14.

P3 > PI as ban sinks in liquid 1 and P3 < P2 as ball doesn't sinks in liquid 2, so

PI <P3 <pz

18: Since no conduction is found when IIlu.I.1 i meter is connected across P and Q, it means either both P and Q are 11 type or p type. So, it means R is

base. When R is connected to common terminal and conduction is seen when other terminal is connected to P orQ, so in means transistor is npn with R as base.

19. Electric field at a distance I' fromA is, E == p x ~ 211r

=> J dV = - JEd!"

a ~ bpI dr

~ Vc - Vs '" ~V = - J ~)(--

2ft 1'2

"

~ ilV=PI[.!. __ l_]

211: a a+ b

p xl

20. FromE =pJ '" --

2ltr2

1 1 1 .

21. - - - '" -- == constant, so (c) is correct graph. v U f

22. 0.5 x 2'1·1 x 0 = 1.5 x v

[assumed that 2"d body is at rest]

~ v=2/3

M<.=Kf -K.

~ ~ ,.~rr . m x ~ ~ +

=- 0.67 J So, energy lost is 0.67 J.

23. Soap solution has lower surface tension, T as compared to pure water and capillary rise

I 21" cos 9 I' 1 for soao soluti

1 = SO 1 IS ess or soap so unon.

prg

l'1'!v2. k .

24. -- = _ .. gIVen

,;, I~

mVII, '" nh from Bohr's theory 211:

Solving, ';1 «: n and '1'" is independent of 11.

25. y(x, r) "" 0.005 cos (ax - j3t)

2n 21C

.. _" = u and - = p

i. T

2n 2n

So a = -- = 2511 and j3 = .. - = 11

'0.08 2 .

26. M ""yoNl x!'J, xA

I

where "l'l'J = 300 turns, N 2 = 400 turns, A..::. 10 cm;! and 1= 20 em.

Substituting the values in the given formula, we get M = 2.4n x 10 <1 H.

27. If we give the following inputs to A and B then corresponding output is shown in table

A '~~Y'B~ ~;;:c;~_~

9. ·~o ~tj

The.above table is similar to OR gate.

at!' 28. Here, x2 ;::: vt and Xl ;:::-- 2

So, the graph would be like

29. Factual.

30. For uniformly charged spherical shell,

£=0, r<R

- _Q_" r?R

- 4Ti:;o~i

31. Let potential of PI is 0 Vand potential of P2, is \1;), Now appiy KCL at P2'

P2

2(1~1Q

,vtv 'lOU +~v

i"1

Vo - 5 V()- 0 Vo - (- 2)

-,--- +" --+----=0

2 10 1

5

'101=

, 16

~ So, current through 10 n resistor is Vo from Po to

10 -

PI'

~~ Chemist1'Jf_

~'l" ....

W---..,....---E

Direction is given by Right hand palm value No.1

2)(10-,7 xlOOT

B '" towards south

4

33. For diamagnatic material, 0 < ~l r < 1 and for any material 8" > 1

34. Diameter = Main scale reading + Circular scale reading x LC + Zero error 1

'" 3+ 35 x -_ + 0.03= 3.38 mm 2x50

35_ As no work is done and system is thermally insulated from surrounding, it means sum of internal energy of gas in two partitions is constant ie, V = V1 -I- U 2

Assuming both gases have same degree of freedom, then

U co, fen1 + 1l2)RT and VI = j'I~l~:!\

2 2

U _ fn2R1'z

2 - 2

1 '1' - (PI "'I + P2V2)T1TZ

So ving we get, "- ---------

PJ."'IT2 + P2V2TI

1. Nucleophilic substitution bimolecular '(5",2) prefers less sterically hindered site to attack. Lesser the steric hindrance better the SN 2 reaction. So ease of reaction is 1 c > 2° > 3°

SN 2 involves inversion of configuration stereo chemically.

(Remember' if molecule is optically active, optical inversion, Walden inversion is known)

2. en, CHo _- NJ-I~ is bidentate ligand

I -

CHz -NH2

C 20 ~'- is also bidentare ligand

Hence, coordinating head are six (en 2x2=4+ (ox) 2)

Coordination number 6

Complex can be ionised as

r E{enh(Cp 4)]NO~, -) [E(enMC20 4t NO 2 oxidation number x + 0 + (-2) = +1

=> oxidation number = 3

3. Ozone layer permits the infrared radiation to pass through but doesn't permit the higher range of ultraviolet radiation to pass through.

60H .

4 Cone H2S04

. sulphonatiori'

¢

S03H

First sulphonation is the . means to block para position and to reduce the reactivity of phenolic." ring against strong oxidising agent HN03. ( The use of cone HNO 3 over phenol cause the oxidation of ring mainly). The strong acidic medium in second step cause desulphonation (ipso mechanism) also.

OH

.Cone O. N02 HN031

~

5.

CH3

6 ConcHN03 + H2S04

0-, p-directing

1 NaN02, HCl dlazotisation

CH3 CH3

CrN-N~-¢

+N NCr

.r., U

jCUBr, Heat Sandmeyer's reaction

+Q

Br

o

03 /\

6. CH3CH =CHCH3 -----"7 CH3 -CH CH-CH3

. I I

0-0

,

i Zn, Hp

J Reductive I

I ozonolysis 'f'

2CH3-CH=O

'B'

7. Lanthanoides: [Xe]4jl-,j45dO-16s2 Actinoides : [Rn] 5t -146do.-17s2

Lathanoides and actinoides use core d and f orbitals also to show higher oxidation state. As actinoides have comparatively low energy difference between j and d orbitals show more oxidation states.

8. CFSE (crystal field splitting energy) for octahedral complex, ~o depends on the strength of negative ligand: Spectrochemically it has been found,that the strength of splitting is as follows:

CO> CN- > NO;; > en> NH3 > py >

NCS- > HzO > 02- >OX2- > OW> F- > cr > SCN- > S2- > Be> r

9. Pr == P~XA + P~XB

Mixture solution boils at 1 atm == 760 mm == total

pressure

10.

760 == 520 XA + 1000(1- X A) XA == 0.5, mol % of A '" 50% 1

- A ------+ 2B 2

Remember for aA ~ bB

1 d[A] 1 d[BJ .

- - -- '" - -- == Rate-of reaction

a dt b dt

For the given reaction

2d[A] 1 d[B] ,

- -- == - -_. '" Rate. of reaction

dt 2 dt

Rate of disappearance of A

d[A] 1 d[8] 1 d[B]

11_

2 x2 dt X~2Y 1 0

at equilibrium 1 - x 2<:

Total no. of moles= 1 + x

4 dt

dt

KI'l

[~'P1J2

l+x

~.____ll_

(1 - x) (1 + x)

[1- x)

1+i'P1

At equilibrium

Z~P+Q

1 0 0

1- x x X

X2 P2

K ", __ . __

P2 (1 - x) (1 + x)

KPl "'.!.

KP2 9

4xPJ. "'.!.

P2 9

Similarly

So,

1 36

!. Cl2 (g) -----'I' Cnaq) 2

MI -'" !. !Vidi.,(C12) + !Vi EA Cl + !Vihyd (Cl-:-) 2

'" 240 _ 349 - 381 2

== - 610kJ mol "

13. 2MS + C -----'I' 2M + CS2

12.

aG1 == positive

2MO + C -----'I' 2M + CO2 t"G2 == negative

The value of t"G for the formation of CO2 is negative, ie, it is thermodynamically more stable than CS2• Also metal sulphides are thermodynamically more stable than CS2• Metal sulphides are more stable than the corresponding oxides, so they are roasted to convert into less stable oxides.

14. Bakelite is obtained from phenol by reacting with HCHO in the acidic or alkaline medium

15. As equation 'III' is obtained on adding equation 'I' and equation 'II', so K3 = KI ·K2

16.

2 2

HOOC . COOH

M·

H~ ,,,OH or

1

HOR H

1

COOH H+OHR HOiH R

eOOH

t

E

17.

W = electron withdrawing group

Reaction coordinate

M = electron releasing group

electron withdrawing group destabilises the arenium ion (J -complex.

] 8. 0: - D( + ) glucose and P- D- (+ )glucose are anomers

HO~CO" HO~OH

H~* HO HO *

OH

o-anomer

p-anomer

19 ..

1 3

- X 2 + - Y2 -----'I' XY3

2 2

L'l.Sreocrion '" Sproducrs - S,eatt1lll1S

L'l.Sreattion '" 50 - (~ x 40 + ~ x 60) '" - 40 Jmol-1

L'l.G = !Vi -TL'l.S

At equilibrium as dG = 0

sn =T8S

3

T =~ =~C?..~2..~. "'7S0K

AS 40

20. Addity order

?i

o

-r II

I-J.--O·-S-F> H-O-H >-H-O--S·-O-

II i II

o H 0

(conjugate anion decreases .. cidiiy)

o

II

> H--O-C--O"

21. Isoelecrronic species have same number of electrons, NO+, C~-. CN- and Nt all have 14

electrons.

22. eN"' and NO'" both have same number of electrons and same bond order (3).

23. Ionisation enthalpy of hydrogen atom is 1.312 x 106 j mol", lt suggest that [he energy of

electron in the ground state (first orbit) is - 1.312 x106 r mol'"

6E =E2 -E1

'" __ 1.312 x 106 _ (- 1 '~_!_~~.!~ 'I

'fl 1)

= 9.84 xlOs J morl

24. Chlorides of both beryllium and aluminium have bridged structures in solid phase

Boric acid is not a protonic acid

HOVOH [HO OH]- +

B --OH2 -- )B< H

I HO OH

OH

Borazole, inorganic benzene contains B.,N3H6

25. CrICr3+(O.lM)11 Fe2+(O.0IM)I Fe

Oxidation half cell

Cr --+ Cr3+ + :3e- x 2

Reduction half cell

J"le1+ -I- 2e- ._-)- Fe x 3

Net cell reaction:

2Cr + 3Fe2-~ ----I> 2Cr3 .. + 3Fe n "'- 6

'" 0.72 -. 0.42~' O.30Y

0.0591 [Cr3;'J2

E,~li "" E~'II - ---~.--- log [Fei';]~i

0.0591 (o.li·

= 0.30 - -".------ log --

6 (0.01)3

= 0.30 _ O.059_~ log 10-1

6 10-6

= 0.30 - Q:..0591 log 104 6

Eccn '" 0.2606 V

26. Titration of oxalic acid by KMnO 4 in the presence of Hel gives unsatisfactory result because HCl is a better reducing agent than oxalic acid and HCi reduces preferably MnO 1 to Mn 2T

18

27. Moles of glucese « -- = 0.1 180

178.2 Moles of H20 =---;; 9.9 18

According to Raoult's law

r ;., P.; = X solute

17.5-p, 0.1

---_' !=-._

17_5 10

p, = 17.325 mmI-Ig

So,

28. RSiCI3 give cross linked silicone polymer on hydrolysis

/CI H- 0 /OH

2 Polymerisation

R-Si-CI -- R-Si-OH

"Cl "OH

29. CO is oxidlsed to CO ~ with steam in the presence of a catalyst followed by absorption of CO2 in alkali

co + H2 Steam) catalyst

CO2 + 2Hz !KOH K2COs

30. Suppose atoms of element Yin cep » 100 Number of tetrahedral voids", 2 x 100

. 2 400

Number of element X = - x 200 "" --

3 3

X 400

.,........... ;:;;;---

y 300

Formula", X S3

31. Higher the gold number, lesser will be the protective power of colloid.

32 CH CH C CH Na/Liq NH:l.

·3 . 2 ;;;;s i.\ -"-1'

,I Mathematics

Considering the options given it cppecrs correct. Nc/liq NH3 is k.iown for metal dissolved reduction. Actually it is truth that No llq NH:; reduces lnterncl friple bond and terminal double bond and do not reduce the terminal clkvne due to such clkvlide formation.

33. Terminal alkyne has acidic hydrogen which is enough to protonate the Grignard reagent.

CHgMgX + CH3C !!!!5!CH ~

CH4 + CH3C """CMgX

34. The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC system is -COOH > -S03H> -COOR > COCI

> -CONHz > -CN> -CH=O 35. For salt of weak acid and weak base

1

pH", - -[log Ko + log Kw -log Kb1

2

1 1 1

"'ZPKo + -iPKw -zpKb

= ! x 4.80 + 7 -! x 4.78

2 2

=7.01

1. In .1. ABC, BC = h cot 60° and in 6 ABD,BD == h cot 45° Since, BD - BC == DC

A

::0> h cot 45° - heat 60° == 7

. . h == ---_? = 2.___.

cot 45° - cot 60° (1 ----1,)

""I' "

7.J3 ,/3 + 1 7..J3 tz:

"" ./3-1 x7r;.-tzh'3+1) m

2. Given that, PCA)=~, p(i) = ~ and p(-i) '" ~

We know plf~) =£.0. nB2 - .. co

, B PCB)

and p(~_) = PCB nA) .. , (ii)

A PCA)

. P(~}PCA) (.~) ("1) 1

PCB) = --.-~ == ---_ .. "'-

p(i) GJ 3

A=- {4, 5, 6} andB =- {I, 2, 3, 4}

.. AnB :=-{4}

... PCA uB) = P(A)+ P(B)-PCA nB)

PCA uB)=~+ ~-.!:. =1

666

4. Since,~ -oe = 4 and e =!

e 2

3.

y

2a-·~ = 4 2

3a =4 2

8

:::0> a==-

3

5. From the figure, it is clear that vertex of the parabola at (1, 0).

y

6. Given equation can be rewritten as

(x + Ii + (y + 2l = (zJ2i' Let required point be Q(d, 13).

Then, mid point of PCl, 0) and Q(u, 13) is the centre of the circle.

0.+1 13+0

:.-- 0= -1 and-- "'-2

2 2

:::0> uo=-3andf3=-4

:.Required point is (- 3, - 4}

7 .. : y == {y EN: y = 4x + 3 for some x EN}

.. Y == {7, 8, ... , eo}

Let y = 4x + 3 =>

y-3

X=--

4

Inverse of f(x) is y-3 g(y) 0=-4-

8. Letz=_li-I

z=C~lJ= -/":'I=-i:l

9. " Since, (1, 2) E S but (2, 1) .. s . .. S is not symmetric.

Hence, S is not equivalence relation. Given, T = {(x, y): x - y ~1}'

N9W, x - x = 0 EI, it is reflexive relation x -yeT

:::0> y - XE T, it is symmetric relation,

Let x - Y = I} and y - z == 12

Now, x - z == (x - y) + (y - z) == 1) + 12 e 1 .', T is also transitive.

Hence, T is an equivalence relation.

., 4-3 1

10 •. ,'. Slope of PQ = -. - = -- 1-k 1-k

:.Slope of AM == (k -1)

t(1,4) ,,[ (~-D

:. Bquation of AM is

y _~ = {k -l{X _ (k; 1)]

ClQ (k,3)

For y-intercept, x = 0, y == - 4

.. _4_~==_(k_1)(k;1)

15 k2-1

=> -=--

2 2

=> k2 -1 =15

k2 0= 16

:::0> k=-4

11. Given equation can be rewritten as dy - ~ . y == 1 dx x

-J.!.dx" 1

Now, IF = e :It == e-)Ogx=_

. X

I> ired ] .~ ". ( 1 ) J" 1 dx I

:. neqUlre so unon IS y ~ = ~ 0= og X +.c

Since, y (1) = 1 => 1 == log 1 + c => c == 1

y =xlogx+ x

12.

According to the given condition

(6-al+ (6 - bi + (6- 8)2 + (6- 5)2 ·+(6-10)2 6.80 0= -------_.;_~...::..::..;:.__

5

::::::> 340= {6-a)2 + (6_'b)2 + 4+ 1 + 16

~ (6-oai+(6~bi=13o:9+4

~ (6 -, a)2 + (6 - bi = ~ + 22

.=> a=3,b=4~

" 13. Given that, b=1 + jand c = j + I( The equation of bisector of band f! is r"" ,,-(b + c)

0= ,,(iJz1 + j~k J

... (i)

Since, point C lies on Ai.

.. ~ (1 + 2] +k)==(l + j)+ J.tU+ k)

On equating the coefficient of i both sides, we get Ie tz:

.J2""I~A.=v2

On putting A. "".J2 in Eq. (0, we get

Since, the given vector .~ represents the same bisector equation -;.

.. u""landfJ=d

Alternate solution

• -? b-+ -->

Smce, a, ,c are coplanar.

a 2 Il

1 1 0 =0 o 1 1

~ a (1-0)- 2(1-0)+ Il (1- 0) "" 0

~ 0. + Il "" 2 which is possible for a == 1, Il == 1.

14. Since, a == 8 b and ~ == - 7 b

:.Bis parallel to b and cis anti-parallel to b.

--> --> •

~ a and e are anti-parallel.

--> -->.

~ Angle between a and C IS It.

15.

Equation of line passing through (5, 1, a) and (3, b, 1) is

x-3 y-b z-1

--==--==--

5-3 I-b a-I

Point (0, 1;, _1:) satisfies Eq. (0, we get

17 13

: 3 --b ---1 .. __ ==~2_.==_2_

2 I-b a-I

(_1;)

a - 1 == (_ ~) == 5 ~ a == 6

AlSO,-3(I-bJ==2(1; -b)

~ 3b-3==17-2b

... (n

=> 5b == 20 => b == 4

16.

. x-I y-2 z-3

Gwen, -- == -- == _. -

k 2 3

x-2 y-3 z-1 and -- = -- == -,-

3 k 2

Since, lines intersect at a point k 2 3

3 k 2 =0 1. 1 -2

~ k(- 2k_ - 2) - 2(.., 6 - 2)+ 3(3- k)= 0 ~ - 2k_2 - 5k + 25 = 0

... (ii)

... (i)

=> 2k_2 + 5k - 25 == 0

~ 2k_2 + 10k - 51 - 25 == 0 ~ 2k_(k + 5) - S(k + 5) = 0 ~k==~ -5

2'

, Hence, integer value of k is - S.

17. We have,

n (n + 1) == n2 + n < nl '+ n + n + 1 == (n + 1)2

~ ~ n en + 1) < n + 1, \;j n ~ 2

~ fit <,/n+l

1 1

~ -<--' n;::.:2

fit '/n+1'

Statement II is true.

1 iII 1 1

Also, h > r:> r;:. > r; r;:. > r:> ... ,

. ",1 ">In "12 vn ",3 ",n

1 1

In.> .In,vn;::.:2

On adding all of them, we get

111.1 n r:

f1 + .J2 + 13 + .... + In > ,/ii == "n, 'r/ n :::! 2

Clearly, statements I and Il are true and statement II is a correct explanation of

. statement L

18. Let

=> l::::~ ~~:!~J==[~ ~]

~ b (a + d) == 0, c (a + d) == 0 andrr' + be == 1, be + d2 == 0

~ a == 1, d == - 1, b == e == n

If A == [1 0], then o -1

A2=[.1 .. 0][1. 0.]=[1.0.]=1

o -1 0 -1 0 1

A;t:l, A;t:-l

det A '" -I (Statement I is true)

Statement n tr(A) '" 1-1 "" 0, Statement II is false.

19. Since, .t "C,' x' '" (1 + x}1!

, , .. 0

On multiplying by x, we get tncr·x:+J <=x(l+xt

r~O

On differentiating w.r.t. x, we get

t (r+ 1) "Cr' xr '" (1 + x)n + fl." (1 + x)"-l

,~O

r. Statement II is true. If x::: 1, then

:t (r+ 1) ncr '" 2" + n (2)11-1 '" (n + 2) 2'1-1

·r~O

:. Statement I is true and StatementIl is a correct explanation of Statement I.

20. p: x is an irrational number

q: y is a transcendental number

r : x is a rational number, iffy is a transcendental

number ;:;} r :. - p+-» q :,Sl:rsqvp

and 52 : r == - (p ~ - q)

It is dear from the table that r is not equivalent to either of the statements,

Hence, none of the given option is correct.

21. Since, the number of ways that child can buy the six ice-creams is equal to the number of different ways of arranging 6 A's and 4 B's in a row.

.', Number of ways to arrange 6A's and 48's in a

row

101 10

=6141'" c..

and number of integral solution of the equation Xl +X2 + X3 + X4 + Xs :: 6

_ 6+S-1C_ _IOe .... lOC

- 5-1 - . 4"_ 5

Statement I is false and statement 11 Is true. 22, Now,!'(r)= lim f(1-h)-j.(l)

h->O -h

n-h-l)'Sin( 1 .• )-0

",lim . 1-h-l

1!-i>O -h

1· . ( 1) u . 1

:: 1m. sm . -~- :: - . 1m sm -

h-,Q \. h h->O h

and 1'(1+):: lim /(1 + 11)- f(1)

. h-+O h

(1 + h -1)5in (_1_.)_0

I, 1 + h -1 1" 1

'" Im~---·~- _. '" Imsm~

h->O h h .... O It

.·.j'{r),* f'(1+)

f is not differentiable at x = 1. Again, Now

(0+ h+ 1) sin (. 1 ) -sin 1. (0)

f'(O-)::lim O+h+l, _

h->O -h 0

,.

-{Ch+ 1)cos(2_) x (_1 --)}

h+l (h+1P

+sin(_1 )

:: Ijm---------~. h + 1 h->Q

-1

(using L' Hospital's rule) = 0051- sin 1

and

(0+ h -nsin( .... 1 I·· sin 1

+ O+h-l) -(0'\

f'{0 )= lim ~-- - . '.' -··1

1,-.0 h. 0;

(h -1) cos (__!__) (_ -.1 __ ) + sin (_. 1 . )

'. h-I (h-1)2 h-l

"'lim -... -- .. -----

h->O 1

(using L' Hospital's rule)

::: cos L» sin 1

::::) f'(O-):: F(O' )

:. fis differentiable at x = 0.

23. Since, a+ ar "" a(1 + r) = 12 (i)

and ar2 + ar3 ::: ar2(1 + r) = 48 (i0

From Eqs. CO and (il),

r2=4:::::;> 1"",-2

On putting the value ofr in Eq. (i), we get a= -12

24. Let f(x) '" x3 - px + q, then f'ex) '" 3x2 - P

Put rex) = 0 ~

p

X=I'E _rE \ 3' f3

Now, f" (x) '" 6x

:.At x '" ~.~-, I' (x) =: 6~~ > 0, minima

"

and at x > - \i"~, f" (x) < 0, maxima

25. Let f(x) '" x7 + 14x5 + 16x3 + 30x - 560 rex) '" 7x6 + 70x4 + 48x2 + 30> 0, v x ER :. f (x) is increasing.

:. f (x) ::: 0 has only one solution.

26.lIm~~~~

T T T T T T

T FF T T T

T

T:"I""L""'"'"

.. Statement p-) (q.....". p) is equivalent to p.....".(pvq).

27. Since, cosec-1 (~) = tan'-I( %)

LJ3

4 :. cot (tan'-1 % + tan -I ~)

~ax=-F::1 ~ax=-'l \W j

= cot{tan-lC:)}= Ii

28. The equation of family of circles with centre on y '" 2 and of radius 5 is '.

::::;> (x-Cti"+(y_·2)2::::52 ... (i)

x2 + a 2 - 2ax + y2 + 4 - 4y == 25

On differentiating w.r.t. x, we get

2x - 2a + 2y dy - 4 dy '" 0

dx dx

o =X +~.l. (y - 2) dx

On putting the value of ct in Eq. (i), we get

( dy )2 2 2

x-x- dx(y-2) -t-(y-2) =5

. (dyj2 2 2

-I (y-2) :::25-·(y-2)

dx;

. JI sin x J1 x

29. Since 1= -- dx < _ .. - dx

, o·../x o.,jx'

because in x E(O, 1), x > sin x. I < J 1 .JX·dx = 3[x3/2]~

o 3

2

~ 1<-

3

1

J 1 cos x J 1 -- .

and J", +=»: dx < x 2dx::: 2

o -s x 0

J <2.

30. Given equations of curves are x + 3y2 = 1

and

On solving Eqs. CO and (ii), we get y",,±landx=-2

:.Required area == I J ~1 (x1 - x2)dy I

y'

... (i) ... (i0

23. Since, a+ ar "" a (1 + r) = 12 (i)

and ar2 + ar3 ::: ar2(1 + r) = 48 (i0

From Eqs. CO and (ii),

r2=4:::::;> 1"",-2

On putting the value ofr in Eq. (i), we get a= -12

24. Let f(x) '" x3 - px + q, then f'ex) '" 3x2 - P

Put f'(x) = 0 ~

p

x=/Ir _rE \ 3' f3

Now, f" (x) '" 6x

:.At x '" ~.~-, r (x) == 6~> 0, minima

"

and at x", - Vl"~, f" (x) < 0, maxima

25. Let f(x) '" x7 + 14x5 + 16x3 + 30x - 560 rex) '" 7x6 + 70x4 + 48x2 + 30> 0, v x ER .'. f (x) is increasing.

:. f (x) == ° has only one solution.

26.~~~~~~

~)~£f.i~~1.;zrl~~~!t~jfi;t,\:_~l~ffi~itv~~~l.~~fJ_

T T T T T T

T FF T T T

T

T ""I',''''"N''''''''

.. Statement p-) (q--'Jo p) is equivalent to P--'Jo(pvq).

27. Since,cosec-l(~) =tan'-I(%)

LJ3

4 :. cot (tan'·1 % + tan -I ~)

~ax=-F::1 ~ax=-'l Wi j

= cot{tan-lC:)}= Ii

28. The equation of family of circles with centre on y '" 2 and of radius 5 is '.

:::;> ex -Cti" + (y _, 2)2:::: 52 ... (i)

x2 + a 2 - 2ax + y2 + 4 - 4y == 25

On differentiating w.r.t. x, we get

2x - 2a + 2y dy - 4 dy '" 0

dx dx

0: =X +~.l. (y - 2) dx

On putting the value of ct in Eq. (i), we get

( dy )2 2 2

x-x- dx(y-2) -J-(y-2) =s

( 12

dy 2 2

- (y-2) =25-·(y-2)

dx;

. JI sin x JI x

29. Since 1= --dx < _ .... Jx

, 0."/; o.,jx'

because in x E(O, 1), x > sin x. I < J 1 .JX·dx "= 3[x3.12]1

o 3

2

~ 1<-

3

1

Jl cos x JI -- .

and J "= ~- dx < x 2dx = 2

o -s x 0

J <2.

30. Given equations of curves are x + 3y2 = 1

and

On solving Eqs. CO and (ii), we get y",,±landx=-2

:.Required area == I J ~l (Xl - x2)dy I

y'

... (i) ... (ij)

31. Let

r.::.J sin x

1= ..... 2 '( 1l)dx

SIn x--

4

x-~""t => dx=dt 4

. sin ( ~, +t) dt

1=./2J--,,--4_, ~-

sm t

=./2 J[ 1 cott + ~Jdt

= t + log 1 sin t I + c

= X + log I sin ( x -~) j + c

3;2. Given word is MISSISSIPPI,

Here, I '" 4 times, S = 4 times, P =·2 times

Put

M=l time,

MIIIIPP

- ----- - - 8 7'

,', Required number of words: c 4 x _'_ 4! 2!

:Be x7x61==7,Be ,6e

4 4!21 4 4

33, Given equations are X - cy - bz = 0 ex-y+az=O

and bx+uy-zooO

For non-zero solution 1 -c -b

c -1 a = a b a-1

=> 1 (1_a2)+ c(-c-ab)- b(ac+ b) == 0 =:> 1 - Q2 - c2 - abc - abc - b2 = a

=> a2 + b2 + c2 + 2abc = 1

34. As dec (A) = ± 1, Kl exists and

';\ -1 == __ 1_ (adj A) = ± (adj A) det CA)

All entries in adj CA) are integers, ., A -1 has integer entries,

35. Let the roots of x2 - 6x + a = a be o., 4~ and that of Xl -ex + 6 = 0 be c , 3~.

0;+413=6 and 4(1.I3=a

u+3j3=c and 3u~=6 =>a=8 a 4

-=-=:>a=8

6 3

=> x2-6x+ 8 = 0 =:> (x - 4) (x - 2) == 0

=> x=2,4

and x2 - ex + 6 = 0

=> zZ-2c+6=O

and

=>

=> (=5 .. x2-Sx+6=O

=> x==2,3

Common root is 2,