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    Ren Ren Billones
    191 просмотров18 страниц
    Coordination compounds are often brightly colored. Counter ions are not always needed; neutral coordination compounds can form. Cations (+ ions) are named before anions (io) Coordinated ligands are named in alphabetical order.

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    Coordination compounds are often brightly colored. Counter ions are not always needed; neutral coordination compounds can form. Cations (+ ions) are named before anions (io) Coordinated ligands are named in alphabetical order.

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    191 просмотров18 страниц

    Image 0021

    Загружено:

    Ren Ren Billones
    Coordination compounds are often brightly colored. Counter ions are not always needed; neutral coordination compounds can form. Cations (+ ions) are named before anions (io) Coordinated ligands are named in alphabetical order.

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    Coordination Compounds: Nomenclature and Isomerism Coordinate Covalent Bonds ine coordinate covslent bond —— “© One ate contibutes both e-frming the bond 1» Atoms with one pais (5, P..| can rm these bends | tock metals ions form coordinate covalent tends | {© Moiecues orion that ind to a metal fon recalled ar | Metal ion + igands =a complexion “© INGO} has 6 H,0 bound to NP (© INCUP has 4 Cons tune to Ni a Te [| Coordinate Covalent Bonds _\, ‘Coordination compounds are ofen bright colored * (NiH,O}INO,)is green Ligand Names [Newall ane Ten Ug Wane oO is pu co Cat Jes cme | aac ee es oH, Eerste) [eh ome | | Ko fae r (Nt canta he compl (NP and 2 Ct on ‘cre ong balnos te Sarge | cor Jee Courter on re ot aways needed raul conraton |sen compounes can fom spat L___ Nomenclature 1. Cations (+ fons) are named before anions (-iohs). Coordinated ligands are named in alphabetical | order. | 1 Pree that pec S| (@=2.in=3 tea=4, penta = 5,hexa=6, ec) se ‘ot used aipebetizng| | "Prefs thats part ofthe nam of he gana, sus Ineceveres wae tn Bess] Nomenclature 3 For complicated ligands, especially those tnat have a prefix such as dior tr as par of the ligand name, these prefixes are used to specify the number of those ligands that are attached to the central atom bee 2 e=3 letras = 4 ental = 5 f Nomenclature \ 4 The names of most neutral ligands end in\ Nomenclature 5 The names of most neutral ligands are Ynabl onal sates @ dosages yo \ Roman umera in parenesee olowrg te tame ofthe complex on ormaeciic 2 | 7 Higgarelesis at anon the su" ens Gece kes eters = lar fe eer as non eereaeaneph cena patil) ee Tein otona Sree ee seabesectbetes the sutix-0 Unchanged when used in naming the '= Examples of igands ending in -o are | complex \ = ct chi | 1 There are several important exceptions to = suteo this ue eluding: 20 oe 8, ommine OH yr = 0 oma | = CN cyano CO exon | Noy ta oe = NO toy _d #50 sutto - ee / Nomenclature \ \ 6. The oridation numberof a metal that exhibits Typist spat ype om mvc big 8 Oe Bead eid fam alone PM WN.) gc 1 Mipgesiteonation ane snes yds Nomenclature \ '= Name the following compounds: NaslFe(Ch sodium hexachloroferrate (li) IN(NH,).(OH,),1(NO3), | You do it! Nomenclature Coordinate Covalent Compouhds ‘geomet aroun the met! ent Koenig THLORINO,, tear rite civiornsias ams IM bevaannneniceh ce compounds: ee ICO(NH,)OM)) ‘Wiamminetrihydroxocobait(ttl) (PW daneardcirpomt Potassium hexacyariochromate(f) [Fe(HO)ANH)ICL, teraamminediaquatrontt) es KslereN) ‘tis(ethylenediammine) cobalt(l) nitrate eames ‘You do it Campin nario snk rare iin a = Exercise. arise 1 Exerose2 ‘Name the fellowing compounds, dicate the ‘Write the formule fr the following coordination carat mmr de wel ee compaurds (damminetaquahycroxochromiun(l}) irate : 2 tetvakis(pyriine platinum tetraphenyiborate ; Letina 41 dibromotetracarbonylon) Pau 44 ammonium damminetetaks(stho- Skater ‘yanatojtromatal) © KgMONLon] © ‘isfthylenediaine)ecbai} ate -SEATWORK Give systematic names fo the fellowing compounds. (@) NalAu(CN), (©) PPuNH (©) [Coty (@) [GottsOp* (©) Na[PuCN)] © = Wit formals forthe following. (a) diamminedichlorozine (0 i) bexeyanoferat(T (0 tercyanopainae on (@) potaium hexachorosanue() (© tevammineplatinun() Coordination Number Coorsnaton number «ruber of coor Sovaen etwoon amet ion and fo hae a amor a rey — = mc l (One-bon gard = monodentate, “wood igands = Bientate (09 etnyerestenine, Gees Chelating Ligands Structures (Chelating tgands (ok chee = claw) “ra metal one. = perenne =a EDTAIshexadenate. 6 coordinate covalent bonds frm: 2 oor ° + 2N aioms (be shores) 4 | wt - ova + 4 0.ahoms (ed spheres) x = i a “diag : ciel | age | OO Sinaia 7 some | age | EDTAencapsvaos nell metal ing. rom fit cthatal | sptoret | acpi oo eo aerate es Le = MLZ” complexes are linear po od FOE ML" complexes are square planar or tetrahedral foes 2 cae ML3* complexes are octahedral 'somerism in Coordination Compounds 1 Ionization or lon-lon Exchange Isomers ‘=[PUO4).CLBr, compared to [PUNH,)8r,}0 "Note where the Cis and B's ar in the str = (PUNH,CLIBr, IPtNH,).Br1Cl ‘Structural (Constitutional) ee ‘= Hydrate isomers are a special case of ‘onization isomers in which water molecules' may be changed from inside to outside the ‘coordination sphere. = For example: ' Note whether the water molecule(s) are i ‘ outside the coordination sphere ‘Structural (Constitutional) Isomers FOr OCH HO = Coordination isomers denote an exchange of ligands between the coordination spheres ofthe cation and anion. 1= For example look at these two isomers: [PUNE AIPtC] vs sChIPICla] '= The isomeric distinction is whether the ligands are on the cation or the anios (PUNH:)AIPICl [PUNH,).C Linkage isomerism ‘Some ligands can bind in multiple ways: ‘Geometric isomerism (square planar and octahedral complexes). 7 i 4 a.) -D bm 485 “J oar? Coordination Compounds and Life Coa llc 12/2/2010 ‘ie ny + Meta or metal ion: Lews ack + Ligand: Lewis COORDINATION COMPOUNDS: eras cosas BONDING (oi CL Geometry Hybrids (ear 2) 4 tetrahedral =p 4 square planar dsp? ‘5. trigonal bipyramidal dsp* or sp'd 6 octahedral Psp? or spi? Example [6o(hP* Exam 1: (Co(t* Cola 3o 4st ee oe Co™ Yar} 3eP ltt Tt tlnpnyt a “s ~e ag ne if complex is diamagnetic cctaheceal if complex is diamagnetic PH [Xe] aft thi th|tet tie 8d ect eae paromegete Example 4: [NiCi,F*, tetrahedral —— Nese Twa (ule ynyt Tr a 3a Exercise 5 Exercise 6 How many unpaired electrons are in the Draw orbital diagrams for the following following complex ions? complexes: 1. [RU(NH,);*, diamagnetic 1. [Fe(H,0).]*, spo? 2. [Fe(CN),J*, Psp hybridization 2. [Fe(CN)_J*, dsp? 2. INH,O)*, sp*e hybridization 3. [CoCL| tetrahedral INCH}, 0% yb Sea mn ome ey + Ligands (Lewis base) form coordinate Covalent bonds uth metal center (Lewis acid) + Relationship between hybridization, ‘geometry, and magnetsm + adequate exlanatin for eos of complex €9., [CHH,O}], (Sr,0).01) Crystal Field Theory pair on he ligands create an electrostatic ld “el interacts with the metaon doit. ‘SF ay What wi hapoen wien ‘ign approach trom © the so vertices of 7 + Basis: purely electrostatic interaction + Spherical ld ¢ orale degenerate Electron Configurations ‘Te of depends von then oak asa Fa mn the ‘bie eon vow a ve es Color in Coordination Complexes ‘The color depends on 4 (ligand field strength): sno;seasmioncs>nont seh yasansanss. Castel Reid Theory Pairing energy (II) vs. Ao + Ifo I, strong field; €.9., [CCN] ‘Oxidation state of the metal ion 2. Nature ofthe mete on 3 Number and geomety ofthe ligands 4 Nature ofthe ligands | Crystal etd Teo Nature of the metal ion Ao increases down a group [Fe(ox),]* 14,140 om” t.? @,? [Ru(ox),}* 28,700 em-* ta,° Cryst Pet Mey | ‘Number and geometry of the ligands For the same metal ion, ligands, metalligand distances, by = 4/4 [NOP 15 400 ome! [VC1] 7,900 cn" yar | Nature ofthe igands RR. Tsuchida: empirical observations. ‘Spectochemical senes Ir

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