Class Test

1. 1 mole each of H2(g) and I2(g) are introduced in a 1L evacuated vessel at 523K and equilibrium
H2(g) + I2(g) ↔ HI(g) is established. The concentration of HI(g) at equilibrium

(a) Changes on changing pressure

(b) Changes on changing temperature
(c) Changes on changing volume of the vessel
(d) Is same even if only 2 mol of HI(g) were introduced in the vessel in the begning.

Ans. (b,d)

2. What is minimum mass of CaCO3(s), below which it decomposes completely, required to establish
equilibrium in a 6.50 litre container for the reaction:[Kc = 0.05 mol/litre]
CaCO3(s) ↔ CaO(s) + CO2(g)

(a) 32.5 g (b) 24.6 g (c) 40.9 g (d) 8.0 g

Ans. (a)

3. For the equilibrium,

NH4HS(s) ↔ NH3(g) + H2S(s)

The value of Kp is 0.109 atm2 at 300 K. The vapour pressure of NH4HS at 300 K would be

(a) 0.33 atm (b) 0.109 atm (c) 0.66 atm (d) 1.0 atm

Ans. (c)

4. 10 ltr box contain O3 and O2 at equilibrium at 2000 K.The ΔG˚= 534.52 kj at 8 atm equilibrium
pressure. The following equilibrium is present in the container.
2O3(g) ↔ 3O2(g). The partial pressure of O3 will be (ln 10=2.3, R = 8.3 J/mol K)

(a) 8×10-6 (b) 22.62×10-7 (c) 9.71×10-6 (d) 9.71×10-2

Ans. (b)

5. The reactions

PCl5(g) ↔ PCl3(g) + Cl2(g) and COCl2(g) ↔ CO(g) + Cl2(g)

Are simultaneously in equilibrium in an equilibrium box at comstant volume. A few moles of CO(g)
are later introduced into the vessel. After some time, the new equilibrium concentration of

(a) PCl5 will remain unchanged (b) Cl2 will be greater

(c) PCl5 will become less (d) PCl5 will become greater.

Ans. (c)

6. 1.0 mol of Fe reacts completely with 0.65 mol of O2 to give mixture of only FeO and Fe2O. The mole
ratio of ferrous oxide to ferric oxide is

(a) 2 : 3 (b) 4 : 3 (c) 1:2 (d) 2 : 7

Ans (b)

7. In the reaction
 Na2S2O3 + 4Cl2 + 5H2O ↔ Na2SO4 + H2SO4 + 8HCl
The equivalent weight of Na2S2O3 will be

(a) M/4 (b) M/8 (d) M/1 (d) M/2

Ans (b)

8. In the reaction CrO5 + H2SO4 ↔ Cr2(SO4)3 + H2O + O2 one mole of CrO5 will liberate how many
moles of O2

(a) 5/2 (b) 5/4 (c) 9/2 (d) none of these

Ans. (d)

9. What weight of AgCl will be precipitated when a solution containing 4.77 g NaCl is added to a
solution of 5.77 g of AgNO3

(a) 4.87 g (b) 5.82 g (c) 3.45 g (d) 6.60 g

Ans. (a)

10. Mole fraction of I2 in C6H6 is 0.2. calculate molality of I2 in C6H6.

(a) 4.44 (b) 5.50 (c) 3.20 (d) 6.30

Ans. (c)