3.1 3.3 oo eal Since the reachin order, hence concentrahion dependency, is not Rnown we are not given enough information te fird the rate F reackén at the higher concentration —¢—————— For the 24 order Asappeavance ofa angle reactant Et, oy 4 ques Xa fe g, a) : o --- dog (SS Non for 50% conserson: ty? FE ey = Sin For IS cowersim: tos (ak) Ee = 1S min ho tthe extra hme needed Is 10 minukes —q— Swce the fractional disappearance is independent of mital Concentration we have a first order rate , or de. Co ae ie he Ave = he ~~ where C= monomer We also can find the rate constant, thus replacing valves dn Se = RAHM) = or ee TEES scabs tenn! Hence the rate of cisappearance of monomer iS given by Ic -TeH a = (0.00687 ain )C << Mogoos betting halbits, and his losses, can be described by dE hg oe In Bete here $= money at hen Now at ao $2180 } fon Uhh we can fad his ‘pasgocity" constant eetde be odd = orn te= 3.7 After his ratse we have tro -- =? | fy i fone (Contnved) eat Ses) : For echanged betting halos An be = (omey(a) --- ov $= 208 Hence his rake ig 208-180 -- o $28 ———_______ B.% For @ fist order reversible reaction Aft e {ewnesmatt a Cen = 0 the thtegrated conversion equatién in a batch reactor (constant Arolume because iris a Juquid) Is quen by - x, =dn (i= #) = (brkat Replacng values we then fd \ on (\- z \ xfs) Bwin sb BE = o0sttas ws! gs Xpe = 0.667 Now from thermodynamics we Bow that Cee . & poe de Ke ee - af Cre & osxls or eaesioar Thos 222. : w BES - 0 o2eBIS Solog @ Say quvet [A> 2988 Vey: 0.057750 This the rate expressuin forthe duappearance of A -™|% = 0.05775 Cy ~ 0.020815 Ca ——___—— \ c ot saan C. 4 neti Drow” Csciea eX From the table ef data at Cy =500 t= l00mm Thos ot t=Shre+loomn = 400m Cys 200 ML. or Xq =O6 Let A= SPP. Then by ths game. one -(B)-be Let Bxclukearluck then by this game atone (44) H (iy a 7 . ey ty ‘ : ab (48) (43) Ge Playrig A&B smaltanesusly ea “ '; (byte) 6 From the problem stakement we can fird & Promdr, “Ry from (i), We then use these in (ji) To see how Vong he can play both gemes simultaneously, This is oer strategy Inkegeahig Ga we get mbit rr finbe ard with the data gquew dys tn wee Ow) Stenilarty oath @ tg=d dna a Were Gj oe wlbgiBy)é ner te phy In Be 2 a 7% ar and with (vy & wy) \ tha 1900 B98 TAes << Bann Note: This is simply a case of two lf order reactions’ iw parallel, See 42.Co) S15 We cam test the fit of the Michoelis- Menten type equation wh many ways, inteyal or differential We will ake these dfferent colstions in torn. But Pst let us transform the MoM equation vito the folowing usefol fore = Peo “qe Ceo = _feaCy ~- where a a eh Cy | ae a af ™ Case this form Integral _n method Integrating ra) ques fio. 6 See dnelte 4, at a ” Py Cro— Ca BT Gene | nteneagt = bg Wn crol | Goh eA Plot he dato ) 5 a the | ‘on the newt: gage: # oo eet 7 Regn AT measured ~ | From foetna o+—_— . £ interagt (5.0824 A fM=o,1a7 From this Mgore the constants in Eq. ty ave kaa l@7bem! | ART EnCEo_ M =0197 reine! { ONVT + Cy thusais fe In Caolca t a t & Che-Ca— hor : 0.84 1.09 bas 2 0.68 1a 6.25 3 083 Le 6.39 oe (56 6S 5 027 180 6.85 6 ob aig WS 9o (acs Qos V7 2 0.0% 2.26 8.34 4 B 4.08 417 10 Gis (0 ul 0025 lo Ae AG 3 aude ’ 2.17 for firet order processes a ileal 8.12% IO win ty b enin . After one day ea ake (tz nt ® (24x60) ic coe =2 = 1.98 x07 7 —q—_____ Thus the radioactiity drags to 2x10° of the original valse. eee ait - - the time for complete conversion of an ni& order reactun from &q, 24, is3.41 Filed ok or (BB)- 1252 0m : eA 6 Given SPSL is roneg (1 2A B 4o100%e., Tobslate gy ® tune (rama) (atm) assy We Lou 0.982, 0.440 0405 OSI asso 0932 0's 0.400 OS 0128 | Column @)is obtawsd from Eq 5, or SAS©°GsAo Gaon -o 2 Pa= Pho ~ aa (a —w,) = vas 25 (w-1252) = 2 tase. vy frst order kunehes, Fords plot as chown iy auc v lasa, _- We do net ger a shracglt hue & aloe = Ke. HES at Keo dik/mat tern Bole = 6:37 YE mH Lig/mot nin,aD 3.2% Let us try nw order kinetics, Then flow Eq 2a, toking B.S ratios, we get | G-Dete CoE) 1] ee : a ODER OG ee) Replacing values gue, i: ; eo ey et . ay™s 2 Replacing in Eq 23a gres okey = "Cet Loa] Guo to : f, wl ae & antl iy) | Here we ave gwen frost data, co we have two paste Cpproachas cay We could fut trausform wh pressure o.dvigs. wabo conewratums and then cae , ov thy We could clay wih pressuie reads auel then transform Oo Firat equation ule conconhabum units Leb vs chek with pessuve units, Awd let uo star by guessing fet order reversible knetics. Why reversible? Because at t=00 therers shit soma Uunveacted Pa. Se the rake equafion we wil test is Ame, Mr ekq-ble --- On megrahem we An(\- %e ) 2 KE [ rou) x( s.) Nae &<>) Sas \n plessure vits this nheqvated e2xpXession becomes Continues) oo ef eee eee os Bho~Pre Pho Bhe)/ Phe Let us eee whether this equation fits the facts So tablahe & ot farPre Ph ~fhe ° fame fh tyrtre 4% faerie © bo 1 ° i boo oo 0.2042, Note: For Pocder exe ioe AIS 328/10 ~ 0.02% 6 240 M/e10 ~ 0.2328 Keand kp have the 8 m0 Meo aT a 0. 25 fo 1505! ee (2 duo {9/610 = \.U26 fae ae OS/e10 ~ 2.2341 00 sO o - © 7 ‘ho ER From Gy the slope = zo ® = go A = 0.1295 wins! or . ea = 0.295 ms") pp On dividing both sides by RT eye we oblauin AG e wo - ae =p = ONS Cp 5 Tae \ _ th fo Lame, fain s lo ‘Ss Whar this shows is that if we have Wotermat & eidov kmehies we can use por Cy mithook chargug the rake corctnutsas) BQ1 Saice we are told thar the reaction Is elementavy the stoichiometric equation chous that the reackon 1& 2% oder, £0 fo a emall relate concentyatuon change vie can wine eo ce 324 Cyt SS G Amovet of Aor ® : Amouak of mat + =O, . a Tatat : Fora fst order veactin in a vanable volume set-up, we have from €q.78 Vv ~ (Se 3.91 Theunit's of the rate constant tells that this is a 22 order reoction ~ye ke he og Abus or ee Jak =An ko- & (45 Zo to bud the value of the vate condant, o, kyand Yes we must plot Ink os YT, the slope gues Bye ant the inteveagt gives ky. Let us follow this procedve> ai Fst letus tobolate Continued) Te Tk a k 50e BL 0.0012 01054 427 Too O00, 8.0031 BAe be 0.00\502 @,000588 356 G24 0.001540 Bod K1O-e 213 BHe 000822 — OAN2¥\o-e Next plot os shown befeu ° . ~Trom Eg uy and this graph clope=-£ = Se PER * Does 0.0004 = 2x 22727, K An / 10 | i -15 4 ——+—__ ee 0.00) 6000s O00 aotts To fad the Value of ko take the second data Point, From Eq o> e/ dak, = Ink= z(t) esc7Tb4 — 22727 (q) = 38.2487 ky = OPT 1 obxin'” So Bi the temperate fange covered wm the vegotted data -Nq = hobo’ e BPYT of, Yoo? sq