Tutorial heterocyclic compounds

A) Choose the correct answer

1) The correct parent ring in the heterocycles below is:

N N
N N N
N
N N N N N
H
(a) (b) (c)
Pyrazine Quinoxaline Triazole

2) The correct parent ring in the heterocycles below is:

S O N S
N

N N N S O
H (b) (c)
(a)
Pyrazole Oxazole thiophene

3) The correct name of this heterocycle is:

a) Pyrazino[4,5-c] pyridazine N
b) Pyrimido[4,5-c] pyridazine
c) Pyridazino[3,4-d] pyrimidine N
N N

4) Pyrrole:

a) Pyrrole is a -deficient heterocyclic molecule.

b) Nitrogen atom contributes its lone pair of electrons to the aromatic sextet.
N
c) Nitrogen contribute only one p electron to the aromatic sextet. H

5) The orbital structure of pyridine:

a) Pyridine is a -deficient heterocyclic molecule.

b) Nitrogen atom is sp3 hybridized.
c) The  electrons of the ring carbons overlap with doubly filled p orbital of nitrogen.

1
6) The compound which its name is written correctly is:

H O
NH H
Cl N
N Br
N
H
3-Chloroimidazole 2H-pyrrolium cation 2-Bromoisoxazole
(a) (b) (c)

B) Give the systemic name of the following:

N
S S N
(a) (b) (c)
N O

=================

Answers
OH
N
N N
N
a) b)
OH

Br HO N N
O H
7-bromobenzo[b][1,4,5]oxadiazepine 9H-purine-2,6,8-triol

S S N
(b)
(a)
N O
4H-thiopyrano[3,2-b]pyridine (4Z,6Z)-1,3,5-oxathiazepine

(c)

benzo[h]quinoline

2
 H O N
O N
N
N
O
N O
1H-pyrazolo[4,3-d]oxazole 2H-furo[3,2-b]pyran 5H-pyrido[2,3-d][1,2]oxazine
(1) (2) (3)

N O
N
N
O N N
N
difuro[2,3-b][2,3-e]pyrazine (6Z,8Z)-5H-tetrazolo[1,5-a]azepine
(4) (5)

N
H
N N

N
S 1,5-diazaanthracene
10H-pyrido[3,2-b]benzo[e][1,4]thiazine pyrido[2,3-g]quinoline
(6) (7)

N N
N
N
N N
N
[1,2,4]triazolo[4,3-a]pyridine pyrazino[2,3-d]pyridazine
(8) (9)

N
H N
dibenzo[b,f]azipine 4H-dibenzo[d,e][g]quinoline
(10) (11)