2/124

2106E222 Candidate's Seat No: ~--o

GUJARAT UNIVERSITY

B.E. Semester VIII (Chem.) Examination Petroleum Refming & Petrochemicals

[Max. Marks : 100

Date: 21-06-2010 Monday) Time: 03-00 p.m. to 6-00 p.m.]

Instructions:

1. Figures to the right indicate fUU marks. Z. Draw neat diagram wherever necessary. 3. Attempt 1111 questions.

Q.l

(A)

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Q.2

Answer the foUowing.

(16)

Describe the distillation characteristics of Crude.

Explain dehydration &ad desalting of crudes and discuss el,ctric desalting

method. '. .

Discuss about the physical & chemical impurities in Petroleum Fractions. Explain Octane number and knocking characteristics.

Answer any two.

(16)

(A~/Explain and discuss Catalytic reforming and platforming with neat ./ diagram along with reactions.

(8) Define Smoke point and describe the improvement of smoke point with solvents DMF & DMSO for kerosene with diagram.

ce( Discuss the composition of Petroleum and general properties of f;/' . homologous series.

Q.3

Write short notes (any three)

(18)

. (a) Catalytic cracking and Houdri flow catalytic cracking process.

h) Additives of Gasoline.

(c) Phenol Extraction of Lubes Treatment Techniques. (d) Unisol treatment process for Gasoline.

(e) Isomax Hydrocracking

(I) Thermal properties of Petroleum Fractions.

(p.T.O)

Q.4

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Q.6

Answer the following.

(A) ~ne Petrochemicals, List its principal raw materials and Describe tbe petroleum industries and its product in India.

Write and discuss the chemical reactions aDd major engineering problems involved for tbe production of Methanol.

(ii) Mention the uses and applications of LDPE and HDPE.

Answer any two.

(A) Discuss the production of Ethylene by steam cracking with diagram.

What is Aromatics and Discuss the production ofBTX. of

Explain with neat diagram the manufacturing process Isopropanol along

with its safety aspects. . 1\

Write short notes (any three)

(a) Major Engineering problems involved for the production of S~rene and its uses.

/(b) Chemical and Physical properties of different Cbloro~nes and its uses with applications.

J) VCM via acetylene-HCI reaction along with·fJeW diagram. (d) Stor~ge and band ling information of Butadiene.

(e) Properties and Forms of Formaldehyde along with its safety aspects •

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(16)

(16)

(18)

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{Time: 3 Hours 1\'1 ax. Marks : 100

: nSlind :I)IlS : (1) Attempt all !{!estions

(2) Answer to the two sections must be written in separate answer hooks,' (Jl Assume suitable datu if rer. uired ,

(4) Figures to the right indicate (lin marks. (5) Draw neat diagram where- '::' necessarv.

SLCTION I

(Ui)

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~~) Explain Atmospheric disullation lHld. Vacuum. distillatiop of crude oil SIIQ\\'III:!

~ tl::: urr.urgement II f !(l\'I(;rt; f 0 obtain principul fractions lct C'l__.\) .

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t. 1';:U.';\1'I'\ any (WO.

(''Jll\par~: (jilt! di:,tingudl Gd\V'el~n .l.cnual and catalytic cracking tor specific pet.oleum feed ~j\li(;;': Exptaiu l;:'.:'lIllca! and economic cousideratious. (3\ 0 '1

L};pl;\illlb,; It:rI;, ,"'~t;\l(i\I()I! "i' ~'>:U:)le.\lIl. l.lude.._~ISl \.IlI_! information requireu iiy ~ r " ' -:i\ refiners before 0stauiislling rdlni.li)l, process, ivlention standard product mix of a ~ y /

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\)IS':·lIS:-; Jelaved coking, opcranor. ,·;;tll major engineering preble-us involved. J \. ~

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4 Answer the foil(>'YiHg questions (i6)

~ Define Petrochemicals, name important petrochemicals plant in India. Mentio~

_ important raw material used in manufacture of few typical petrochemicals. ~

'> ~.~~EXPlain with a neat flow diagram for manufacture of Formatdehyd!"/Lt\:

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~~1) f'.'1arll'~'l~~lIIil1g p~~.·of ~~i~~lal~~)~~e:.~. y.~ ', .. ' ..' " ( .

*~), A!'('I~l~lhcS chemicals n)ong:Wlth IL".P~P.~UCS il!'ld ~ppl~~tIOns.· .. £\OD· (PR ~ ·t~)

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. \TiulC .. 1-3v p.w. 'io 5<)\) PIt: {MaX.Marh : 1 Gij

Instructions :(11 Figure to theright indicate full ruarks. (2) Dra~~ neat diagr!1!l1'wherev;:;r necessary. .. (2) Att#-tilprail qil~StibD,>.

(3) Useseparate answer books for each section.

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( 1 ~ Disccss the origin. and formation of petroleum along with organic theories. !! '" i ,-' j

';"';c{~> ) . Explain catalyticcracking and-D~scljbe the fluid, catalytic cracking process. s' \.:J

. ~ ~'3Lr4

2 .!~;~empt any two: ?J1.., Ii ~ 0:,:\ ~

~~ Explain term coking and discuss Delayed coking operation :vilh major engineering problcl~~S . . ~ Explain Atmospheric dtstillarion and vacuum. distillation to obtain principal fractions ~~O-6

9' :J) Discuss with diagram 1vl;~i( ))e ..... vaxing process, ~?> ~ c -:::::

3 Write short notes (any three) : ' , a

L,-Lf,"7) .Additi\~es for Ga:oline ~. \ < 1..-

5- \ (~) C~talytlc l~efom;mg -. ~ f1. < <~

.~ MerOX5wectenFit+process.:.~ .:~ v

'. I,d; Test methods andproperties ofDiesel fuets leo 'j ~'-\

,~~..(~) Dehydrationand Desaltingofcrudes .. ' 1'1-1

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SECTIONlf

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4 t.J» Describe with a neal Ilow.digramrnanufacturc of chloromethanes. +~ l\ ~.. :3

; (0 ) Discuss ~l1eCleh)'(lrogel1lii:0116f ethylbcnzenc for styrene along With m~orengineeringproblellE.V

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.5 Attemptany two: .... - . .' ...... J sr ~ (a) Explain tJ~", !-'\:-li1tlim:wri.ngof~thytene by.stca.n crac!drig 'ofl1aj)htlia'and gils oil., .,/,(~

. ( ( b) Discuss l1H., dehydrogcuationof Butane for Buradienc. ~. \ , ~. . . .

-' ( c) E \ph;;n the' manufacturing of Isopropanol by hydration of piopylene via sulfaticn and _

_J hjtiroIysis·'p.:o.:c.o;s ... ~9G' _ . .

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18.

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,.-' , t t Candidates Seat4N . -

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. Gl JJARAT UNIVERSITY] t l'l:-'4::iIV' . t

B.J l. Semester - VII (Chemical) . \. o~ ( '(j ,.;,'

Petroleum Pteflning a~d Petrochemicals (Electiv~I).\~ .;; - -~~::/'

Saturday, 10th December, 20051 [Tune. 02-30 ·~_._-t:il1..-P·JIl· [Max.Marks : 1 00'

,i12/0S

Instructions:

( 1 ) (2) ( 3 ) ( 4 ) ( 5 )

Attempt all . cstions from both -:,~tions.

Use separate answ-er book for each section. Figures to the right indicate, full marks. Assume suitable additio':':''ll data, if necerssary. Draw neat diagram ",~herevernecessary.

Attempt any two

(a) Enumerate composition of petroleum crude and list

out major impurities in crude including sulphur

(nitrogen and oxygen) compounds in crude. - .~ 1:9 ;"3 \

Discuss delayed coking operation with major /

engineering problems involved. ~1- S

Explain catalytic reforming incorgorating

chemical reaction involved. 8 c; L

Q-3 W rite short notes (any three)

® (a) Atmospheric distillation and Vacuum distillation of crude oil ,~ U -u.

Doctors sweetening process for gasoline treatment. .'2. {~ Composition and properties of natural, associated and refinery off gases, 9 r-

Octane number and Cetane number. );_ () ~ ; \ \..\.. \Dehydration and desalting of crudes. \'\3

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(b)

Q-2

(b)

( , ,_c)

(d) ~ (e)

. '

!

SECTION - I

\.,/Explain the term evaiuation of petroleum crude.q.ist (08)

out informationrequired by refiners before establishing refining process. Men tio n standard product mix of.a

petroleum refinery.) / ~.

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Compare and distinguish between thermal and catalytic cracking for specific petroleum feed stocJjs. Explain technical and econo-mic considerations. .:.-

(08) 9.\0

(16)

(18)

(b) (£)

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(b)

Define Petrecu. '~(C~l 's, name imp f .rta.it petrochemicals (08) plant in India. Mentbi1 important raw material used in manufacture offew tYl-",c.ai petro cuemicals.

Explain with a neat nOWSi~·~et m'an::facture of (08)

methanol. ::,'~,

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(a)

Q-5 Attempt any two.

(a) Discuss the manufacturing ofHDPE

.~ along with major applications. \ ~ ,.~

(08)

(b)

Discuss the dehydrogenation of butane for \~ (OS)

Butadie~e along with major engineering problems, 'l

(c)

Discuss the dehydrogenation of ethyl benzene for (O~)

styrene along with major engineering problems. \ Q C_\

Q-6 Write short notes (any three) (18)

(a) Manufacturing of vinyl chloride via acetylene-HCl rene-ton. h ~

(b) Manufacture of Ethylene oxide and Ethylene glycol (;l1 l-1

~) Manufacturing of LDPE. \ ~ ~ J

C , (d) Separation process of BTX. ,,~ 'L

L-___(e) Manufacturing of formaldehyde. ll.. Q

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._-;;;<'.' .y;",l'nginrrring problems involved. (i ; (:Y>:~~)

(li) Exillain ·\toHJsphrric distillation a~ld \'a(l!UII1 (OS)

~islillaticir of crude oil showing, t h e arrnuze mcnt of

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B. E. Sern, YII (%h:~cal) Exa~.·~~.~, ..

{(}'9 "~

December ~. 2002 . i ~ ( .,y';' '-:f'l )

Petroleum Refining &. Petrochemica'~l~\?~-'r' - ):!)

:(Elective. .: 1) '.' \~v ~:, __ .. t;, :.",J:-~'I

Time : 3 Hours] [Total )h:~~!i~

Instructions .

'j. Figure to the right indicateSfull marks.

2. Draw neat diagram wberever'neceSsary

3. Attempt all questions . . . . , '.

4. Use sepilTliteaiJswer book for each section,

Section ~(-

~ .

Q.:t (a) Explain theterm evaluation of pelroleum crude. List (08)

'" out in~onnati0ll required by refiners before' establishing refining proces$. Mention'standard productinix ofa petroleum refinery.· .. ··: ; : '.

(b) Enumerate&mposition ofpetroieumcrude and list (08)

\t\ out major i.hpurities iO'crude indudings"phur

<1\ (nitrogen and oiygen) compounds in crude.

: -. ,_.

Q-2 Show with block diavamsthr~ types of refinery processes. (16)

(a) Topping and skimming process.

(b) Cracking process (Vacuum distillation and catalytic cracking). (c) Lubricatingclil processing (including solvent treating). Explain salient features of dia~~am.

OR

Explain significance of catalytic cracking, compare it (08) with thermal cracking, indicate basic cbanges in product mix, operating parameters feed stock selection and chemical reactioDs involved.

Write short note on cat2lytic: refonningincorporating (01) chemical-reaction involved.

'~S .~ (b)

Q-3 Write short notes (auy three) (t8)

~ ~_9 (a) Doctors ~eeteDing process (or gasoline treatment. .

'11 ~!b) . Delayed coking ~peration (neat diagram) with major

:-l engineerinl problems mvolved..

(c) ASTM vIs TBP distillation of petroleum.

(d) Com~itio. and properties of natu~ associated and

j ~=- refine..,. oft'gasa. . .

(e) Wu purification by aaysdective proces~q ('

F·622] 1 [Contd ...

.;

Section -II

Q-4 (a) u_O

! ~'3 (b)

. Explain with a neat tlowsheet manufacture of (08)

farmaldehyde from methanol.

Discuss the manufacturing of LDPE via high pressure (08)

process. State the major engineering problems.

Q-S Attempt any two.

, I (.'J' (a) Explain the manufacturing of ethylene by steam

"\ '6 cracking of naphtha and gas oil

(b) Explain the manufacturing ofiso propanol by

90 hydration of propylene via sulfation and bydrolysis process,

Discuss the dehydrogenation of ethyl benzene !'or styrene along with major engineering problems.

(08) (08)

(c) \C£lj

(08)

Q-6 Write short notes (any three) . (18)

~~ Major engineering problems involved in tbe manufacture .

~ of methanol.

\~' ~b) Separation process of BT~.

G ,:-1__(.c) Manufacturing orviny'-~b40ride via acetylene-Rel reaction.

~ (d) Properties and uses for methyl chloride. methylene chloride.

L\ ~ chloroform and carbon tetra cbloride.

~) Petrochemical industry in Gujarat.

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( h ) Discuss the manufacluril:1g of ethylene dichlooiic Tnlm cthylcn~. p. ~ .:

6 Writ'c short notes (any three) .:' . . . .. . '.'

( a) Dcl1ydrllgc~lln of Fthyl,bcn7.enc f~r styrene .. \ \ ~~./

( b) Manufacturing of ~ylcne glycol. 'T1 '. /:

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Petroleum Refining & Petrochemical (E.P •• I)

Wednesday. 261ft December. 20011 I Time: 2-30 1'.111, to 5·30 p.ni:

Instructions: ( 1) Answer all questions.

( 2) Usc separa.te answer-book f"ir each section. ( 3) Draw neat diagram wherever necessary .

. ( 4) Figures to the right indicates full marks,

SEC1'ION I

Discuss composition of petroleum. Enu;ilcralC til<:. sulfur compounds in crude oil, Explain evaluation of crude oil. mention major petroleum. cuts and tests for

Gasoline and Kerosene. S"l.1 . 9 r-, \ oj 1- . .

Explain atmospheric distillation and\'4}{\lul.n distillation of crudcuil l\howing the arrungcmcut ut' towers to obtain prinq.(lal fractions. QC 'u;

Draw diagram for delayed coking of residue or rewaxing of crude and mention

important process parameters. ;::t-' ~ ~,!. , li \" .

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. OR

Explain principle of treatment technique for petroleum Iractions. Discuss with diagram particulars of Doctors treatment for sweetening of gnsolinc. (~~ ~ Compare and distinguish between catalytic cracking and Thermal cracking of crude residues, mechanism and product mix advantages and disadv;Ultag_cs.:\\D

3 Writ~ short notes (any tllrce) : ,1 X

( a) ASTM or TBP (equilibrium) distillation of crude .' \(K) 0" <;.~

( b) Reili vapour pressure (gasoline) and smoke point (Kerosene), t (, l.\ / \ 4

( c) Aniline point anti ~onrad:iOn carbon residue. \'ll. S" \ s-~

( tI) Catalytic rdocming..3 5"'2...

( e) Natural and associitcd gas.~ S--

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( a ) ( b )

G1 (3.)

( b )

2 (a)

( b )

SECTION II

4 (a) Define term petrodlcmieal. name important raw materialS for manufacturing of petrochemicals. Mention the names of major important pcPlX:hc!lli~ planL s in India.

( h) Describe me manutpcturing process for the ethylene oxldc, What . prccauuons rcquircq in storage 'of ethylene oxide. . G.!] .

Explain the manufacturing of butadiene hy any one pr(IfCss. 1 \ 6 Explain the manuf~puring of HOPE. Mention the uses :"f HOPE. \ ()

~j " "OR .

5 (a) Discuss the manufacturing of' isopropanol hy hyrulttion of propylene via sulfation and hydrolysis method.·(,3 C --..:...--- - -

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