7.a Gases Ideales

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\fs18\cf0\par\pard\li4573\ri0\sl-480\slmult0 \fs24\cf0\f0\charscalex100\b {GASES
IDEALES}\b0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-
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\fs22\cf0\f0\charscalex100\b \i {Lic. Lidia I�igo}\b0 \i0
\par\pard\sect\sectd\sbknone\pard\li1173\ri0\sl-213\slmult0
266\slmult0 \*\tx6413\fs22\cf0\f1\charscalex100 {A esta altura de tus estudios
seguramente ya sab�s}\tab \fs22\cf0\f1\charscalex100 {que hay muchas sustancias
formadas }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {por
mol�culas, qu� es una mol�cula, y que una sustancia determinada puede presentarse
en tres }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {distintos
estados de agregaci�n.}\par\pard\li1173\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li1173\ri0\sl-306\slmult0 \fs22\cf0\f1\charscalex100 {Si
pensamos en una sustancia molecular, en el caso m�s sencil o, en el agua por
ejemplo:}\par\pard\sect\sectd\sbknone\cols2\colno1\colw1173\colsr-
0\colno2\colw9920\pard\li466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li466\ri0\sl-
\fs24\cf2\f0\charscalex100\b { 1}\b0 \par\column\pard\li0\ri0\sl-213\slmult0
\fs22\cf0\f0\charscalex100\b \i { �Qu� diferencia hay a nivel de c�mo se encuentran
esas mol�culas cuando el agua}\b0 \i0 \par\pard\li0\ri0\sl-253\slmult0
\fs22\cf0\f0\charscalex100\b \i { est� en estado s�lido, l�quido o gaseoso?}\b0 \i0
\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li0\ri0\sl-373\slmult0 \fs22\cf0\f1\charscalex100 {Para que un
sistema gaseoso quede correctamente determinado no alcanza
simplemente }\par\pard\sect\sectd\sbknone\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {con conocer la masa de gas, o la cantidad de gas (que
se mide en moles). Se deben conocer otras }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {tres variables, que son: temperatura, presi�n y
volumen. Un gas no tiene volumen propio, por lo }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {tanto ocupar� todo el volumen del recipiente que lo
contenga. Estas cuatro variables no son }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {independientes, lo cual significa que a lo sumo se
podr�n poner arbitrariamente tres de el as, y, }\par\pard\li466\ri0\sl-
266\slmult0 \fs22\cf0\f1\charscalex100 {autom�ticamente la cuarta quedar� fijada.
La ecuaci�n que relaciona estas cuatro variables es la:}\par\pard\li3613\ri0\sl-
\fs18\cf0\par\pard\li3613\ri0\sl-373\slmult0 \fs22\cf0\f0\charscalex100\b {Ecuaci�n
General del gas ideal}\b0 \par\pard\li4360\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li4360\ri0\sl-346\slmult0 \fs24\cf0\f0\charscalex100\b {P. V =
n . R . T}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-360\slmult0 \fs20\cf0\f1\charscalex100
{La }\fs20\cf0\f0\charscalex100\b {TEOR�A CIN�TICA DE GASES}\b0
\fs20\cf0\f1\charscalex100 { expresa que las mol�culas de un gas est�n
totalmente }\par\pard\li466\ri0\sl-266\slmult0 \fs18\cf0\f1\charscalex100 {libres,
sin ninguna interacci�n entre el as. Dichas mol�culas se mueven
con un movimiento }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {rectil�neo, chocando entre s� y con las paredes del
recipiente con choques el�sticos. Las mol�culas }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {se consideran puntuales, y el volumen que ocupan dichas
mol�culas es totalmente despreciable }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {con respecto al volumen del recipiente que se encuentra
ocupando dicho gas.}\par\pard\sect\sectd\sbknone\cols2\colno1\colw1173\colsr-
520\slmult0 \fs24\cf2\f0\charscalex100\b { 2}\b0 \par\column\pard\li0\ri0\sl-
\fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \fs22\cf0\f0\charscalex100\b \i {�Que es
un choque el�stico?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0
\fs22\cf0\f1\charscalex100 {Entonces, un gas ideal es el que cumple con la teor�a
cin�tica de gases y por lo tanto con
la }\par\pard\sect\sectd\sbknone\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {ecuaci�n general de un gas
ideal.}\par\pard\li1173\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {No siempre
los gases cumplen con esta ecuaci�n, un gas real puede no
cumplirla. }\par\pard\sect\sectd\sbknone\cols2\colno1\colw1173\colsr-
\fs22\cf0\f0\charscalex100\b \i {�Por qu�, entonces, estamos utilizando la ecuaci�n
para un gas ideal, si un gas }\b0 \i0 \par\pard\li0\ri0\sl-253\slmult0
\fs22\cf0\f0\charscalex100\b \i {real no la cumple?}\b0 \i0
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i1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-213\slmult0
{Cualquier gas real puede comportarse como ideal dependiendo de las condiciones en
que }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {se encuentre.
Teniendo en cuenta la ecuaci�n general, matem�ticamente puede verse qu�
sucede }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {con el
volumen al disminuir la temperatura o aumentar la presi�n: el volumen
disminuye. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrs
xn133\cols2\colno1\colw1173\colsr-0\colno2\colw9920\pard\li466\ri0\sl-
\fs24\cf2\f0\charscalex100\b { 4}\b0 \par\pard\li466\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \fs22\cf0\f0\charscalex100\b \i {�Qu�
pasar� con las mol�culas al estar cada vez m�s juntas?}\b0 \i0
\fs18\cf0\par\pard\li0\ri0\sl-373\slmult0 \fs22\cf0\f1\charscalex100
{Entonces: }\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-
\fs22\cf0\f0\charscalex100\b \i {�En qu� condiciones un gas real se comportar� como
ideal?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-
{Qu� son presiones bajas y temperaturas altas depende de cada sustancia en
particular,
por }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\p
ard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {ejemplo el ox�geno a
presi�n atmosf�rica normal (1 atm�sfera) y temperatura ambiente (20 \uc1\u8211X
25 }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {�C) seguramente
se comportar� como ideal, en cambio el agua a 1 atm. y 150 �C no se
comporta }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {como
ideal. }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn13
3\cols2\colno1\colw1173\colsr-0\colno2\colw9920\pard\li466\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li466\ri0\sl-480\slmult0 \fs24\cf2\f0\charscalex100\b { 6}\b0
\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-
\fs22\cf0\f0\charscalex100\b \i {�Por qu� el agua a 1 atm. y 150 �C no se comporta
como gas ideal?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0
\fs22\cf0\f1\charscalex100 {Cuando se quiere estudiar experimentalmente un gas, al
existir cuatro variables, no
se }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pa
rd\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {pueden cambiar todas
juntas, porque no se l egar�a a ninguna conclusi�n. Lo que se puede
hacer }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100
{experimentalmente es dejar fijas dos de el as, y ver como var�a la tercera en
funci�n de la cuarta. }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {Eso fue lo que hicieron Robert Boyle (1627 \uc1\u8211X
1691) y Edme Mariotte (1620 \uc1\u8211X 1684) por un lado
y }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {Jacques A.
Charles (1746 \uc1\u8211X 1823) y Joseph L. Gay Lussac (1778 \uc1\u8211X 1850) por
el
otro.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\
cols2\colno1\colw1173\colsr-0\colno2\colw9920\pard\li466\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \fs22\cf0\f0\charscalex100\b \i {�Cu�les
son las variables que quedan como constantes en el experimento de Boyle}\b0 \i0
\par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i { y
Mariotte?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-
\fs18\cf0\par\pard\li0\ri0\sl-400\slmult0 \fs22\cf0\f1\charscalex100 {Si se coloca
un gas en un recipiente herm�ticamente cerrado, con un �mbolo m�vil
(como }\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133
\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {el que tienen las
jeringas), desde ya, al no poder entrar o salir gas, la cantidad
de gas es }\par\pard\li466\ri0\sl-266\slmult0 \fs18\cf0\f1\charscalex100
{constante. Si ese recipiente se mantiene a temperatura constante,
coloc�ndolo en un ba�o }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {termost�tico queda constante tambi�n la temperatura. Si
ahora se colocan pesas sobre el �mbolo }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {estamos aumentando la presi�n, intuitivamente
se ve que el volumen disminuye. }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {Experimentalmente, si la presi�n se aumenta al doble el
volumen disminuye a la mitad. Este es el }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {experimento de Boyle y Mariotte. Matem�ticamente el
producto de la presi�n por el volumen se }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {mantiene constante. P . V = cte. Al hacer el gr�fico
se obtiene una curva denominada hip�rbola }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100
{equil�tera.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margr
sxn133\pard\sect\sectd\sbkpage{\shp
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volumen en cualquier unidad? �y la presi�n? �y la temperatura?}\b0 \i0
\par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i {�Qu� sucede si se
est� usando la ecuaci�n general?}\b0 \i0 \par\pard\li0\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li0\ri0\sl-413\slmult0 \fs22\cf0\f0\charscalex100\b \i {�Por qu�
la temperatura debe estar en temperatura absoluta y no en otra unidad,}\b0 \i0
\par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b \i { Celsius o
Fahrenheit, por ejemplo?}\b0 \i0 \par\pard\li66\ri0\sl-253\slmult0
\fs20\cf0\f0\charscalex100\b {Ayuda}\b0 \fs20\cf0\f0\charscalex100
{: }\fs20\cf0\f1\charscalex100 {Volv� a los experimentos de Charles y Gay Lussac y
a lo que sucede al
cambiar}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn13
3\pard\li466\ri0\sl-240\slmult0 \fs20\cf0\f1\charscalex100 { la escala
de temperaturas. Ah� encontrar�s la
respuesta.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsx
n133\pard\sect\sectd\sbkpage
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373\slmult0 \fs22\cf0\f1\charscalex100 {As� como la masa molar es la masa de un mol
de cualquier sustancia, el }\fs22\cf0\f0\charscalex100\b {volumen molar }\b0
\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {es el volumen que
ocupa un mol de cualquier sustancia. Por lo tanto se puede hablar del
volumen }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {molar tanto
de gases, como de l�quidos o s�lidos. En los gases el volumen molar var�a mucho con
}\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {las condiciones de
presi�n y temperatura. Observ� que la ecuaci�n general nos est� diciendo
que }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {cualquier gas,
siempre que se comporte como ideal, se comporta de la misma manera. Un mol
de }\par\pard\li466\ri0\sl-266\slmult0 \*\tx9640\fs22\cf0\f1\charscalex100
{cualquier gas, medido en las mismas condiciones de P y T, debe ocupar el mismo
volumen,}\tab \fs22\cf0\f1\charscalex100 {si no }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {fuera as� no se cumplir�a la
igualdad.}\par\pard\li1173\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {Esto
mismo, pero enunciado al rev�s, es lo que se conoce
como }\fs22\cf0\f0\charscalex100\b {Hip�tesis de Avogadro: }\b0
\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {vol�menes iguales de
diferentes gases, medidos en las mismas condiciones de P y T, tienen
el }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {mismo n�mero
de \uc1\u8220Xpart�culas\uc1\u8221X. La hip�tesis de Avogadro habla
de part�culas porque en el }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {momento en que fue enunciada no se conoc�a lo que eran
las mol�culas, hoy sabemos que esas }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {\uc1\u8220Xpart�culas\uc1\u8221X son las mol�culas del
gas.}\par\pard\li1466\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1466\ri0\sl-
\fs18\cf0\par\pard\li1466\ri0\sl-426\slmult0 \fs24\cf0\f0\charscalex100\i {Las
llamadas }\i0 \fs24\cf0\f0\charscalex100\b \i {condiciones normales de presi�n y
temperatura (CNPT)}\b0 \i0 \fs24\cf0\f0\charscalex100\i { son }\i0
\fs24\cf0\f0\charscalex100\b \i {1 atm. y }\b0 \i0 \par\pard\li760\ri0\sl-
280\slmult0 \fs24\cf0\f0\charscalex100\b \i {273 K}\b0 \i0
\fs24\cf0\f0\charscalex100\i {. El valor del volumen molar de cualquier gas ideal
en CNPT es }\i0 \fs24\cf0\f0\charscalex100\b \i {22,4 dm}\b0 \i0
\fs14\cf0\f0\charscalex100\b \i {3}\b0 \i0 \fs24\cf0\f0\charscalex100\i {, y es el
}\i0 \par\pard\li760\ri0\sl-280\slmult0 \fs24\cf0\f0\charscalex100\i
{denominado }\i0 \fs24\cf0\f0\charscalex100\b \i {volumen molar normal de un gas
ideal.}\b0 \i0
\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\
\fs18\cf0\par\pard\li0\ri0\sl-426\slmult0 \fs22\cf0\f0\charscalex100\b \i {En
condiciones distintas de las normales pero iguales para cualquier gas}\b0 \i0
\fs22\cf0\f0\charscalex100\b {:}\b0 \par\pard\li0\ri0\sl-240\slmult0
\fs22\cf0\f0\charscalex100\b \i {�El volumen molar es igual para cualquier gas que
sea? �Es igual a 22,4 dm}\b0 \i0 \fs14\cf0\f0\charscalex100\b \i {3}\b0 \i0
\fs22\cf0\f0\charscalex100\b \i {?}\b0 \i0
\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\l
\fs18\cf0\par\pard\li466\ri0\sl-466\slmult0 \fs22\cf0\f0\charscalex100\b {MEZCLA DE
GASES}\b0 \fs22\cf0\f0\charscalex100\b { \uc1\u8211X Ley de Dalton de las presiones
parciales}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
{Como todos los gases ideales se comportan de la misma manera, el volumen que va
a }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {ocupar cualquier
gas en las mismas condiciones de P y T depende solamente del n�mero
de }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {moles, o lo que
es lo mismo del n�mero de mol�culas. Si se tiene una mezcla de gas A y gas B,
no }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {importa de qu�
gas sean las mol�culas, solamente importa el n�mero total de el as. La
ecuaci�n }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {general se
transforma en: }\par\pard\li4000\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li4000\ri0\sl-320\slmult0 \fs22\cf0\f0\charscalex100\b {P}\b0
{\sub \fs14\cf0\f0\charscalex100\b {tot}\b0 }\fs22\cf0\f0\charscalex100\b { . V =
(n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {A}\b0 }\fs22\cf0\f0\charscalex100\b { +
n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {B}\b0 }\fs22\cf0\f0\charscalex100\b {). R
. T}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
{Pasando de t�rmino el volumen y aplicando propiedad distributiva se l ega
a:}\par\pard\li3493\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li3493\ri0\sl-213\slmult0
\fs14\cf0\f0\charscalex100\b {tot}\b0 \fs22\cf0\f0\charscalex100\b { = n}\b0
\fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { . R. T / V +
n}\b0 \fs14\cf0\f0\charscalex100\b {B}\b0 \fs22\cf0\f0\charscalex100\b { . R .T /
V}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
{Esta ecuaci�n es suma de dos t�rminos, que son la presi�n que tendr�a el gas A si
ocupara }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {s�lo el
mismo volumen y a la misma temperatura y lo mismo para el gas B. Estas son las que
se }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {definen como
presi�n parcial del gas A y presi�n parcial del gas B en la
mezcla.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn13
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\fs24\cf0\f0\charscalex100\b \i {LA PRESI�N PARCIAL DE UN GAS EN UNA
MEZCLA es la presi�n que }\b0 \i0 \par\pard\li760\ri0\sl-280\slmult0
\fs24\cf0\f0\charscalex100\b \i {ejercer�a ese gas si ocupara el mismo volumen que
la mezcla a la misma temperatura.}\b0 \i0 \par\pard\li3080\ri0\sl-213\slmult0
\fs22\cf0\f0\charscalex100\b {P}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0
\fs22\cf0\f0\charscalex100\b { = n}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0
\fs22\cf0\f0\charscalex100\b { . R. T / V }\b0 \fs22\cf0\f1\charscalex100
{y}\fs22\cf0\f0\charscalex100\b { P}\b0 \fs14\cf0\f0\charscalex100\b {B}\b0
\fs22\cf0\f0\charscalex100\b { = n}\b0 \fs14\cf0\f0\charscalex100\b {B}\b0
\fs22\cf0\f0\charscalex100\b { . R. T / V}\b0 \par\pard\li1173\ri0\sl-
\fs18\cf0\par\pard\li1173\ri0\sl-360\slmult0 \fs22\cf0\f1\charscalex100 {Venos que
la presi�n total es igual a la suma de las presiones parciales de los gases A y
B.}\par\pard\li4586\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li4586\ri0\sl-213\slmult0
{\sub \fs14\cf0\f0\charscalex100\b {tot}\b0 }\fs22\cf0\f0\charscalex100\b { = P}\b0
{\sub \fs14\cf0\f0\charscalex100\b {A}\b0 }\fs22\cf0\f0\charscalex100\b { + P}\b0
{\sub \fs14\cf0\f0\charscalex100\b {B}\b0 }\par\pard\li1466\ri0\sl-213\slmult0
\fs24\cf0\f0\charscalex100\b \i {LEY DE DALTON DE LAS PRESIONES PARCIALES: la
presi�n total es igual a }\b0 \i0 \par\pard\li760\ri0\sl-280\slmult0
\fs24\cf0\f0\charscalex100\b \i {la suma de las presiones parciales de todos los
gases que componen la mezcla.}\b0 \i0 \par\pard\li1466\ri0\sl-213\slmult0
\fs24\cf0\f0\charscalex100\b \i {Cuando se resuelve un problema de mezcla de gases
hay dos caminos posibles. Uno }\b0 \i0 \par\pard\li760\ri0\sl-280\slmult0
\fs24\cf0\f0\charscalex100\b \i {es utilizar la ecuaci�n P}\b0 \i0
\fs14\cf0\f0\charscalex100\b \i {tot}\b0 \i0 \fs24\cf0\f0\charscalex100\b \i { . V
= (n}\b0 \i0 \fs14\cf0\f0\charscalex100\b \i {A}\b0 \i0
\fs24\cf0\f0\charscalex100\b \i { + n}\b0 \i0 \fs14\cf0\f0\charscalex100\b \i
{B }\b0 \i0 \fs24\cf0\f0\charscalex100\b \i {). R . T y el otro es utilizar
presiones parciales.}\b0 \i0 \par\pard\li466\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li466\ri0\sl-320\slmult0 \fs22\cf0\f0\charscalex100\b {FRACCI�N
MOLAR }\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
\fs18\cf0\par\pard\li1173\ri0\sl-373\slmult0 \fs18\cf0\f1\charscalex100 {La
fracci�n molar es una forma expresar la composici�n de una
mezcla, que es muy }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {utilizada en el caso de mezclas
gaseosas. }\par\pard\li1173\ri0\sl-386\slmult0 \fs20\cf0\f1\charscalex100 {Para una
mezcla de las sustancias A, B, y C; se define la fracci�n molar de A como el n�
de }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {moles de A sobre
el n� de moles totales.}\par\pard\li1173\ri0\sl-213\slmult0
\fs22\cf0\f0\charscalex100\b {
n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {A}\b0 }\par\pard\li1173\ri0\sl-
386\slmult0 \fs22\cf0\f0\charscalex100\b
{ X}\b0 {\sub \fs14\cf0\f0\charscalex100\b
{A}\b0 }\fs22\cf0\f0\charscalex100\b { =}\b0 \par\pard\li1173\ri0\sl-
386\slmult0 \fs22\cf0\f0\charscalex100\b {
n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {A}\b0 }\fs22\cf0\f0\charscalex100\b { +
n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {B}\b0 }\fs22\cf0\f0\charscalex100\b { +
n}\b0 {\sub \fs14\cf0\f0\charscalex100\b {C}\b0 }\par\pard\li1173\ri0\sl-
{De la misma forma se puede definir la fracci�n molar de B y de
C.}\par\pard\sect\sectd\sbkpage
(946,680);}}
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2;14;16384;45824;1;45824;1;45824;1;45824;1;45824;1;45824;24577;32768}}
\fs18\cf0\par\pard\li1173\ri0\sl-333\slmult0 \fs22\cf0\f1\charscalex100 {Se deben
tener en cuenta tres cosas importantes con respecto a la fracci�n
molar:}\par\pard\li1613\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1613\ri0\sl-
320\slmult0 \fs22\cf0\f1\charscalex100 {A. Se esta dividiendo moles sobre moles,
con lo cual resulta un n�mero adimensional, }\par\pard\li1893\ri0\sl-280\slmult0
\fs22\cf0\f1\charscalex100 {que }\fs22\cf0\f0\charscalex100\b {no tiene
unidades}\b0 \fs22\cf0\f1\charscalex100 {.}\par\pard\li1613\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {B. Se est� dividiendo un n�mero de moles por ese mismo
n�mero m�s otros n�meros }\par\pard\li1893\ri0\sl-280\slmult0
\fs22\cf0\f1\charscalex100 {de moles, con lo cual el n�mero
resultante }\fs22\cf0\f0\charscalex100\b {siempre ser� menor que uno}\b0
\fs22\cf0\f1\charscalex100 {.}\par\pard\li1613\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {C. Si se suman todas las fracciones molares vemos que,
sacando divisor com�n :}\par\pard\li1173\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li1173\ri0\sl-293\slmult0 \fs22\cf0\f0\charscalex100\b {
n}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { + n}\b0
\fs14\cf0\f0\charscalex100\b {B}\b0 \fs22\cf0\f0\charscalex100\b { + n}\b0
\fs14\cf0\f0\charscalex100\b {C}\b0 \par\pard\li1173\ri0\sl-386\slmult0
\fs22\cf0\f0\charscalex100\b { X}\b0
\fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { + X}\b0
\fs14\cf0\f0\charscalex100\b {B}\b0 \fs22\cf0\f0\charscalex100\b { + X}\b0
\fs14\cf0\f0\charscalex100\b {C}\b0 \fs22\cf0\f0\charscalex100\b { =
= 1}\b0 \par\pard\li1173\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100\b {
n}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { + n}\b0
\fs14\cf0\f0\charscalex100\b {B}\b0 \fs22\cf0\f0\charscalex100\b { + n}\b0
\fs14\cf0\f0\charscalex100\b {C}\b0 \par\pard\li1893\ri0\sl-213\slmult0
346\slmult0 \fs22\cf0\f1\charscalex100 {Por lo tanto }\fs22\cf0\f0\charscalex100\b
{la suma de todas las fracciones molares de los componentes de }\b0
\par\pard\li1893\ri0\sl-280\slmult0 \fs22\cf0\f0\charscalex100\b {la mezcla es
igual a 1.}\b0 \par\pard\li1173\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li1173\ri0\sl-293\slmult0 \fs20\cf0\f1\charscalex100 {Podemos
decir entonces que la fracci�n molar es un tanto por uno en moles, o sea,
que }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {fracci�n hay de
cada componente de la mezcla en el total de un mol de todos los gases
que }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {forman la
mezcla. }\par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
{Si tomamos una mezcla de gases A y B podemos plantear:}\par\pard\li1173\ri0\sl-
426\slmult0 \fs22\cf0\f0\charscalex100\b { P}\b0
\fs14\cf0\f0\charscalex100\b {tot}\b0 \fs22\cf0\f0\charscalex100\b { = (n}\b0
\fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { + n}\b0
\fs14\cf0\f0\charscalex100\b {B}\b0 \fs22\cf0\f0\charscalex100\b {) . R . T/V
}\b0 \fs22\cf0\f1\charscalex100 {y}\fs22\cf0\f0\charscalex100\b { P}\b0
\fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { = n}\b0
\fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b { . R . T/V}\b0
426\slmult0 \fs20\cf0\f1\charscalex100 {Dividiendo miembro a miembro estas dos
ecuaciones se simplifica el factor R }\fs20\cf0\f0\charscalex100\b {.}\b0
\fs20\cf0\f1\charscalex100 { T / V y se }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {l ega a:}\par\pard\li1173\ri0\sl-213\slmult0
\fs22\cf0\f0\charscalex100\b { P}\b0 \fs14\cf0\f0\charscalex100\b
{tot}\b0 \fs22\cf0\f0\charscalex100\b { (n}\b0 \fs14\cf0\f0\charscalex100\b
{A}\b0 \fs22\cf0\f0\charscalex100\b { + n}\b0 \fs14\cf0\f0\charscalex100\b
{B}\b0 \fs22\cf0\f0\charscalex100\b {) 1}\b0
\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\cols2\
\fs22\cf0\f0\charscalex100\b { =}\b0
\par\column\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100\b { =
Reordenando: P}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0
\fs22\cf0\f0\charscalex100\b { = P}\b0 \fs14\cf0\f0\charscalex100\b {tot}\b0
\fs22\cf0\f0\charscalex100\b { . X}\b0 \fs14\cf3\f0\charscalex100\b {A}\b0
\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133\pard\l
i466\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100\b { P}\b0
\fs14\cf0\f0\charscalex100\b {A}\b0 \fs22\cf0\f0\charscalex100\b
{ n}\b0 \fs14\cf0\f0\charscalex100\b {A}\b0
\fs22\cf0\f0\charscalex100\b { X}\b0 \fs14\cf3\f0\charscalex100\b
{A}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
{Por lo tanto vemos que la presi�n parcial de un gas puede calcularse como el
producto de }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {la
presi�n total por su fracci�n molar. O tambi�n podr�a calcularse la fracci�n molar
de un gas en }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {una
mezcla como el cociente entre la presi�n parcial y la presi�n
total.}\par\pard\sect\sectd\sbknone\pgwsxn11893\pghsxn16840\marglsxn666\margrsxn133
\pard\sect\sectd\sbkpage{\shp
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{Respuestas}\b0 \par\pard\li1146\ri0\sl-213\slmult0
\fs24\cf2\f0\charscalex100\b {1}\b0 \par\pard\li1173\ri0\sl-466\slmult0
\fs22\cf0\f1\charscalex100 {En el estado s�lido esas mol�culas est�n unidas por
fuerzas que hacen que se mantengan }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {unidas, �sas son las fuerzas intermoleculares. Se
encuentran muy juntas y adem�s ordenadas, lo }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {que hace que el s�lido tenga tanto volumen propio como
forma propia.}\par\pard\li1173\ri0\sl-266\slmult0 \fs18\cf0\f1\charscalex100 {En
el estado l�quido siguen existiendo fuerzas intermoleculares, pero
ahora son m�s }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100
{d�biles, lo que hace que las mol�culas en un l�quido tengan movilidad y el l�quido
fluya. El l�quido }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100
{sigue teniendo volumen propio, pero ya no tiene forma
propia.}\par\pard\li1173\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {En el
estado gaseoso, las mol�culas est�n totalmente libres, sin interacci�n entre el as,
por }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {lo tanto no
existen las fuerzas intermoleculares. Un gas ya no tiene ni forma ni volumen
propios.}\par\pard\li1146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1146\ri0\sl-
\fs18\cf0\par\pard\li1173\ri0\sl-360\slmult0 \fs22\cf0\f1\charscalex100 {Es un
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\fs18\cf0\par\pard\li1173\ri0\sl-453\slmult0 \fs20\cf0\f1\charscalex100 {No es que
un gas real no cumpla la ecuaci�n general de un gas ideal, sino que la
puede }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {cumplir en
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a haber interacciones entre el as, comienzan a sentirse las
fuerzas }\par\pard\li466\ri0\sl-266\slmult0 \fs18\cf0\f1\charscalex100
{intermoleculares que luego har�n que esas mol�culas se unan y la
sustancia pase al estado }\par\pard\li466\ri0\sl-266\slmult0
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\fs18\cf0\par\pard\li1173\ri0\sl-373\slmult0 \fs22\cf0\f1\charscalex100 {Un gas
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\fs18\cf0\par\pard\li1173\ri0\sl-280\slmult0 \fs22\cf0\f1\charscalex100 {Porque el
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encuentre en estado gaseoso. En cambio el ox�geno a presi�n
atmosf�rica normal y }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {temperatura ambiente se encuentra muy lejos de su
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\fs22\cf0\f1\charscalex100 {entre sus mol�culas.}\par\pard\li1146\ri0\sl-
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440\slmult0 \fs24\cf2\f0\charscalex100\b {10}\b0 \par\pard\li1173\ri0\sl-
{En forma general cualquier recta en los ejes cartesianos x e
y tiene la expresi�n: }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {y = a . x + b. En este caso las expresiones son:}
{ }\fs22\cf0\f1\charscalex100 { V = a . t (�C) + b y P = a . t (�C) +
b }\par\pard\li1146\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1146\ri0\sl-213\slmult0
{Son constantes para esa recta determinada, a se denomina
pendiente (da idea de la }\par\pard\li466\ri0\sl-266\slmult0
\fs20\cf0\f1\charscalex100 {inclinaci�n de la recta) y b se denomina ordenada al
origen porque es el valor que toma y cuando }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {x vale 0.}\par\pard\li1146\ri0\sl-213\slmult0
{12}\b0 \par\pard\li1173\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1173\ri0\sl-
373\slmult0 \fs20\cf0\f1\charscalex100 {Es como correr el eje de las y, ahora la
recta pasa por el origen. Se elimin� la ordenada al }\par\pard\li466\ri0\sl-
266\slmult0 \fs22\cf0\f1\charscalex100 {origen (b). Con esta nueva escala tanto V
como P son directamente proporcionales a T.}\par\pard\li1146\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li1173\ri0\sl-346\slmult0 \fs20\cf0\f1\charscalex100 {Presi�n es
fuerza por unidad de superficie. El Pascal es la unidad de presi�n en el
sistema }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100
{internacional de medida. Es igual a una fuerza de un Newton sobre una superficie
de un metro }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100
{cuadrado.}\par\pard\sect\sectd\sbkpage{\shp
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{En la ecuaci�n de estado el volumen y la presi�n pueden ponerse en cualquier
unidad, }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {siempre que
se respete poner la misma unidad en el estado inicial y el final. No sucede lo
mismo }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {con la
temperatura, que debe estar en temperatura absoluta, tanto en la ecuaci�n de estado
como }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {en la general,
o en cualquiera de las ecuaciones vistas. En la ecuaci�n general las unidades
de }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {volumen y
presi�n dependen de las unidades de la constante molar de un gas ideal (R),
como }\par\pard\li466\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {nosotros
utilizamos R con unidades de dm}\fs12\cf0\f1\charscalex100
{3}\fs20\cf0\f1\charscalex100 { atm. / K mol el volumen deber� estar en
dm}\fs12\cf0\f1\charscalex100 {3}\fs20\cf0\f1\charscalex100 { y
la }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {presi�n en
atm.}\par\pard\li1200\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1200\ri0\sl-
\fs18\cf0\par\pard\li1173\ri0\sl-493\slmult0 \fs22\cf0\f1\charscalex100 {La
temperatura debe estar en temperatura absoluta porque las
expresiones }\par\pard\li466\ri0\sl-293\slmult0 \fs22\cf0\f1\charscalex100
{matem�ticas que se usan s�lo son v�lidas si la temperatura est� en Kelvin, al
eliminar la }\par\pard\li466\ri0\sl-293\slmult0 \fs22\cf0\f1\charscalex100
{ordenada al origen que quedaba con la temperatura en Celsius se obtiene una
expresi�n }\par\pard\li466\ri0\sl-293\slmult0 \fs22\cf0\f1\charscalex100
{matem�tica m�s sencil a, y tanto V como P son directamente
proporcionales a la }\par\pard\li466\ri0\sl-293\slmult0
\fs24\cf0\f1\charscalex100 {temperatura en Kelvin, pero no en otra
unidad.}\par\pard\li1213\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1213\ri0\sl-
480\slmult0 \fs20\cf0\f1\charscalex100 {El volumen molar de cualquier gas ideal
ser� el mismo siempre que se mida en las mismas }\par\pard\li466\ri0\sl-266\slmult0
\fs22\cf0\f1\charscalex100 {condiciones de P y T, pero no tiene por qu� ser igual a
22,4 dm}\fs14\cf0\f1\charscalex100 {3}\fs22\cf0\f1\charscalex100 {, salvo por
casualidad. }\par\pard\li1173\ri0\sl-266\slmult0 \fs20\cf0\f1\charscalex100 {Es un
error muy com�n que los alumnos pongan el valor de 22,4
dm}\fs12\cf0\f1\charscalex100 {3}\fs20\cf0\f1\charscalex100 { como volumen
molar }\par\pard\li466\ri0\sl-266\slmult0 \fs22\cf0\f1\charscalex100 {cuando las
condiciones en que est� el gas son distintas de las normales.}\par}

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