open excel the press alt+f11 then dbclick on required sheet and paste the

following code

private sub worksheet_change(byval target as range)

dim targ as range, cel as range, rg as range
set targ = [d:d] 'change to the cell range being watched for duplicates
set targ = intersect(targ, target)
if targ is nothing then exit sub

for each cel in targ.cells

if cel <> "" then
set rg = columns(cel.column).find(cel, lookin:=xlvalues, after:=cel)
if rg.address <> cel.address then
application.enableevents = false
cel = ""
cel.select
application.enableevents = true
msgbox "duplicate entry! " & cel.value
end if
end if
next
end sub