Fig (23)

Spectra of the compound (49-e)

pH Absorbance
[λ=305 nm]
3 1.720
4 1.670
5 1.455
6 1.282
7 1.219
8 1.199
9 1.190
10 1.182
11 1.180

Fig (25)
Spectra of the compound (49-g)
pH Absorbance Absorbance
[λ=314 nm] [λ=378 nm]
3 1.881 0.055
4 1.826 0.125
5 1.480 0.386
6 0.960 0.751
7 0.840 0.898
8 0.800 0.922
9 0.800 0.928
10 0.770 0.930
11 0.760 0.931

Fig (19)
Spectra of the compound (49-a)
pH Absorbance Absorbance
[λ=315 nm] [λ=374 nm]
3 1.599 0.100
4 1.509 0.180
5 1.190 0.550
6 0.800 1.070
7 0.650 1.250
8 0.650 1.311
9 0.610 1.308
10 0.560 1.310
11 0.560 1.311
 Fig (22)
Spectra of the compound (49-d)
pH Absorbance Absorbance
[λ=260 nm] [λ=305 nm]
3 1.280 1.854
4 1.390 1.723
5 1.600 1.400
6 1.856 1.250
7 1.856 1.140
8 1.858 1.100
9 1.846 1.080
10 1.876 1.080
11 1.874 1.081

Fig (21)
Spectra of the compound (49-c)
pH Absorbance Absorbance
[λ=280 nm] [λ=305 nm]
3 0.900 1.269
4 0.970 1.130
5 1.060 0.930
6 1.250 0.740
7 1.290 0.710
8 1.280 0.720
9 1.290 0.770
10 1.300 0.770
11 1.310 0.770

Fig (24)
Spectra of the compound (49-f)
pH Absorbance Absorbance
[λ=280 nm] [λ=318 nm]
3 1.040 0.220
4 1.140 0.400
5 1.290 1.000
6 1.440 1.460
7 1.450 1.480
8 1.530 1.537
9 1.533 1.514
10 1.600 1.510
11 1.666 1.556
 Fig (20)
Spectra of the compound (49-b)
pH Absorbance Absorbance
[λ=266 nm] [λ=311 nm]
3 0.790 1.435
4 0.910 1.390
5 1.120 0.955
6 1.240 0.766
7 1.250 0.728
8 1.300 0.735
9 1.330 0.732
10 1.452 0.698
11 1.450 0.676

Fig (33)
Spectra of Hf- (49-a)

Cppm Absorbance F
[λ=327 nm]
500 3.3 151
400 2.65 151
300 1.98 151
200 1.31 152
100 0.638 156.7
50 0.319 156.7
25 0.16 156
10 0.064 156
5 0.031 161

Fig (34)
Spectra of Hf- (49-f)
Cppm Absorbance F
[λ=329 nm]
500 3.50 143
400 2.82 142
300 2.14 140
200 1.415 141
100 0.692 144.5
50 0.34 147
25 0.158
10 0.076
5 Out of scale
 Fig (35)
Spectra of Hf- (49-g)
Cppm Absorbance F
[λ=329 nm]
500 3.7 135
400 3.05 131
300 2.27 132
200 1.49 134
100 0.735 136
50 0.355 140
25 0.18 138
10 0.07 143
5 Out of scale

Fig (36)
Spectra of Hf- (49-b)
Cppm Absorbance F
[λ=322 nm]
500 2.95 169.5
400 2.37 168.8
300 1.806 166.1
200 1.215 164.6
100 0.925 162.16
50 0.615 162.6
25 0.474 158.23
10 0.318 157.23
5 0.15 166.67
 Fig (37)
Spectra of Hf- (49-e)
Cppm Absorbance F
[λ=343 nm]
1000 1.9 526
900 1.67 539
800 1.43 559
600 1.085 553
500 0.911 549
400 0.737 543
300 0.565 531
200 0.39 513
100 0.195 512
50 0.095 526
25 0.047 531
10 0.019 526
5 Out of scale

Fig (38)
Spectra of Zr- (49-a)
Cppm Absorbance F
[λ=384 nm]
1000 0.55 1818
900 0.495 1818
800 0.425 1882
600 0.313 1916
500 0.261 1915
400 0.212 1886
300 0.159 1886
200 0.113 1770
100 0.06
50 0.074
25 0.031
10 0.023
 Fig (39)
Spectra of Zr- (49-a)
Cppm Absorbance F
[λ=415 nm]
1000 0.225
900 0.195
800 0.174
600 0.135
500 0.118
400 0.1
300 0.085
200 0.056
100 0.048
50 0.038
25 0.032
10 0.026

Fig (40)
Spectra of Zr- (49-f)
Cppm Absorbance F
[λ=417 nm]
1000 0.555 1801
900 0.5 1800
800 0.427 1873
600 0.322 1863
500 0.264 1894
400 0.212 1887
300 0.159 1887
200 0.111 1802
100 0.063
50 0.042
25 0.032
10 0.023
 Fig (41)
Spectra of Zr- (49-f)
Cppm Absorbance F
[λ=389 nm]
1000 1.58 633
900 1.426 631
800 1.121 661
600 0.9 666
500 0.733 682
400 0.587 681
300 0.44 682
200 0.301 664
100 0.16 625
50 0.095
25 0.062
10 0.044

Fig (42)
Spectra of Zr- (49-g)
Cppm Absorbance F
[λ=433 nm]
1000 0.24 4166
900 0.204 4411
800 0.178 4494
600 0.135 4444
500 0.116 4310
400 0.079 4124
300 0.077 3896
200 0.062 3226
100 0.04 2500
50 0.03
25 0.025
10 0.022
 Fig (43)
Spectra of Zr- (49-g)
Cppm Absorbance F
[λ=392 nm]
1000 0.542 1845
900 0.484 1859
800 0.413 1937
600 0.309 1941
500 0.257 1945
400 0.204 1960
300 0.161 1863
200 0.118
100 0.084
50 0.069
25 0.044
10 0.033

Fig (44)
Spectra of Zr- (49-b)
Cppm Absorbance F
[λ=417 nm]
1000 0.07 1429
900 0.505 1782
800 0.413 1937
600 0.294 2040
500 0.244 2049
400 0.186 2150
300 0.141 2127
200 0.098 2141
100 0.056
50 0.038
25 0.028
10 0.021
 Fig (45)
Spectra of Zr- (49-b)
Cppm Absorbance F
[λ=395 nm]
1000 1.37 730
900 1.095 822
800 0.894 894
600 0.648 926
500 0.528 947
400 0.410 975
300 0.303 990
200 0.206 971
100 0.112 893
50 0.069
25 0.047
10 0.032

Fig (46)
Spectra of Zr- (49-e)
Cppm Absorbance F
[λ=410 nm]
1000 0.35 2857
900 0.315 2857
800 0.278 2877
600 0.21 2857
500 0.18 2778
400 0.145 2758
300 0.113 2655
200 0.102
100 0.076
50 0.05
25 0.035
10 0.23
 Fig (47)
Spectra of Zr- (49-e)
Cppm Absorbance F
[λ=383 nm]
1000 1.02 980
900 0.9 1000
800 0.783 1021
600 0.594 1010
500 0.505 990
400 0.4 1000
300 0.303 990
200 0.21 952
100 0.162
50 0.095
25 0.063
10 0.038