Table 1.

Products distribution as a function of various CZA catalyst

catalyst conversion selectivity (%)

CH4 (%) H2 CO CO2 C2 C3 C4
blank 28.1 17.0 45.5 21.5 9.3 1.3 1.7
CZA 25.3 10.9 36.8 12.0 5.6 0.0 0.0
CZAi 31.0 11.2 35.7 10.6 6.7 0.0 0.0
CZAb 29.8 14.6 34.8 12.3 7.5 0.0 0.0

1
Table 2. Products distribution as a function of catalyst loading in the reactor

metal conversion selectivity (%)

loading (gram) CH4 (%) H2 CO CO2 C2 C3 C4
blank 28.1 17.0 45.5 21.5 9.3 1.3 1.7
0.5 gram 25.3 10.9 36.8 12.0 5.6 0.0 0.0
1 gram 30.6 13.6 34.8 9.7 3.6 0.0 0.0
1.5 gram 33.9 12.0 32.9 6.6 6.9 0.0 0.0

2
Table 3. Products distribution as a function of supplied power

power conversion selectivity (%)

(Watt) CH4 (%) H2 CO CO2 C2 C3 C4
50 28.5 10.9 36.8 12.0 5.6 0.0 0.0
80 38.0 14.7 39.5 13.3 4.8 0.0 0.0
110 39.5 18.9 40.0 15.2 6.2 0.0 0.0
140 45.0 20.5 42.7 18.3 4.0 0.0 0.0

3
Table 4. Products distribution as a function of various metals loading doped on CZA catalyst

metal conversion selectivity (%)

loading CH4 (%) H2 CO CO2 C2 C3 C4
blank 28.1 17.0 45.5 21.5 9.3 1.3 1.7
CZA 25.3 10.9 36.8 12.0 5.6 0.0 0.0
1% Pt/ CZA 24.6 15.4 35.6 9.5 3.5 0.0 0.0
3% Ni/ CZA 26.0 18.9 35.0 15.7 7.5 2.2 0.0
3% Fe/ CZA 30.8 13.7 34.4 12.1 9.5 0.0 0.0
3% Y/ CZA 25.3 10.1 33.8 9.0 5.6 0.0 0.0