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UNIVERSITY OF CAMBRIDGE LOCAL EXAMINATIONS SYNDICATE
General Certificate of Education Advanced Level
Higher 2
CHEMISTRY 9746/01
READ THESE INSTRUCTIONS FIRST
Write in soft pencil.
Do not use staples, paper clips, highlighters, glue or correction fluid.
Write your name, Centre number and index number on the Answer Sheet in the spaces provided unless
this has been done for you.
Paper 1 Multiple Choice
Additional Materials: Multiple Choice Answer Sheet
Data Booklet
October/November 2007
1 hour
There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet.
Read the instructions on the Answer Sheet very carefully.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
This document consists of 14 printed pages and 2 blank pages.
'SIIIIB,..--"
Examinations and Assessment Board
UNIVERSITYof CAMBRIDGE
International Examinations
UCLES & MOE 2007 [Turn over
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Section A
For each question there are four possible answers, A, B, C, and D. Choose the one you consider to
be correct.
1 Naturally occurring silicon is a mixture of three isotopes, ?8Si, 29Si and 30Si. The relative atomic
mass of silicon is 28.109.
What could be the relative abundance of each of the three isotopes?
A 91.1 % 28Si, 7.9 %29Si and 1.0 0A, 30Si
B 92.2 % 28Si, 4.70/0 29Si and 3.1 % 30Si
C 95.0 % 28Si, 3.2 % 29Si and 1.8 0A, 30Si
D 96.3 % 28Si, 0.3 %29Si and 3.4A, 30Si
2 When iron is reacted with aqueous iron(III) ions, iron(II) ions are formed.
Assuming the reaction goes to completion, how many moles of Fe and of Fe
3
+(aq) would result in
a mixture containing equal numbers of moles of Fe
3
+(aq) and Fe
2
+(aq) once the reaction had
taken place?
moles of Fe moles of Fe
3
+(aq)
A 1 2
B 1 3
C 1 5
D 2 3
3 An excess of cold water was added to 0.3 mol of a chloride of the third period of the Periodic
Table at room temperature.
0.6 mol of HCI was formed.
Which chloride was treated?
A MgCl
2
B AICl
3
C PCls D SiC4
4 Use of the Data Booklet is relevant to this question.
What do the ions
36
8
2
- and 37CI- have in common?
A Both ions have more electrons than neutrons.
B Both ions contain the same number of nucleons in their nuclei.
C Both ions have an outer electronic configuration 2s
2
2p6.
D Both ions have 20 neutrons in their nuclei.
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5 The table gives the successive ionisation energies for an element X.
1st 2nd 3rd 4th 5th 6th
ionisation energyI kJ mor
1
950 1800 2700 4800 6000 12300
What could be the formula of the chloride of X?
A XCI o XC4
6 Which molecule has the largest dipole?
A B c
CI
/
O=C
"-
CI
o
7 The diagram below shows the structure of part of a crystal of ice.
.... I' #
.... H ,I' H"
,,:/
o
H
. I
'. 0
H/ \.
Which statement is correct?
A All the bond angles surrounding each oxygen atom are 120
0
B Four electrons from each oxygen are involved in forming hydrogen bonds.
C The hydrogen bonds, shown by the dotted lines, are stronger than the O-H covalent bonds.
o The open structure of ice causes ice to be denser than water.
UCLES & MOE 2007
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8 A molten chloride of a Group I metal, XCl, and a molten chloride of a Group II metal, YCl2 , are
separately electrolysed using the same current for the same time.
Which statement about this experiment is correct?
A An equal number of moles of X and Y is deposited.
B Equal masses of X and Yare deposited.
C The number of moles of Y deposited is half the number of moles of X deposited.
D YCl
2
gives off twice the volume of chlorine gas as XCl, measured under the same conditions
of temperature and pressure.
9 A 25 cm
3
sample of 0.20 mol dm-
3
Tl + NO; required 25 cm
3
of 0.10 mol dm-
3
acidified KMn04 to
oxidise it to Tl
3
+ in solution.
What is the oxidation state of the manganese in the reduced form?
A 2 B 3 C 4 D 7
10 Some relevant redox half-equations are given in the table.
half-equation E?/V
1
2
(aq) + 2e- ~ 2I-(aq) +0.54
2H+(aq) + 02(g) + 2e- ~ H
2
0
2
(aq) +0.68
H
2
0
2
(aq) + 2H+(aq) + 2e- ~ 2H
2
O(I) +1.77
What will be observed when a few drops of acidified aqueous hydrogen peroxide are added to an
excess of aqueous potassium iodide?
A The solution turns brown and effervescence occurs.
B The solution turns brown without effervescence.
C The solution turns purple and effervescence occurs.
D The solution turns purple without effervescence.
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11 Values for the ionic product of water, K
w
, at two different temperatures are given below.
temperature/DC K
w
/moI
2
dm-6
25 1.00 x 10-
14
30 1.44 x 10-
14
What is correct for pure water at 30C?
A [H+] > [OH-]
B [H+] =1.44 x 10-
7
mol dm-
3
C pH<7
o pH= 7
12 The pH change when 0.100 mol dm-
3
NaOH is added dropwise to 10.0 cm
3
of a 0.100 mol dm-3
solution of a weak acid is shown below.
Where on the graph does pH = pK
a
where K
a
is the acid dissociation constant of the weak acid?
14
12
10
8
B
pH
6 A
4
2
0
0 2 4 6
o
C
8 10 12 14 16 18
volume ofO.100moldm-
3
NaOH added/cm
3
13 The pH of human blood is constant at about 7.40.
Which ion or molecule present in the human body will remove contaminating H+(aq) ions from the
blood to keep the pH constant?
A C0
2
-
3
B HCO; C o
P03-
4
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14 The reaction of manganate(VII) ions with ethanedioate ions in acid solution may be represented
by the following equation.
The graph shows concentration of manganate(VII) ions against time for this reaction.
What does the shape of the graph suggest about this reaction?
A It is exothermic.
B It is endothermic.
C It shows first order kinetics.
D It produces its own catalyst.
15 What is not a trend from left to right across the elements of the third period of the Periodic Table?
A The radii of the atoms decrease.
B The oxides of the elements change from basic to acidic.
C The melting points of the elements decrease steadily.
D The compounds of the elements change from ionic to covalent.
16 The ash from burnt seaweed contains chlorides and iodides of some Group I and Group II
elements. Some seaweed ash was treated with concentrated sulphuric acid and the resulting
fumes passed first through a cold tube and then bubbled through aqueous silver nitrate.
What would be observed during the experiment?
inside the cold tube with aqueous silver nitrate
A black deposit white precipitate
B black deposit yellow precipitate
C no deposit white precipitate
D no deposit yellow precipitate
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17 What is observed when magnesium chloride is added to water?
solubility in water pH of resulting solution
A dissolves 2
B dissolves 6.5
C insoluble 7
D very slightly soluble 8
18 Use of the Data Booklet is relevant to this question.
Which particle contains a single unpaired electron?
A a molecule of H
2
S
B one of the particles formed after the heterolytic fission of a chlorine molecule
C the ammonium ion in NH
4
CI
D the copper ion in CuO
19 A compound X is optically active. One mole of X liberates one mole of hydrogen when it reacts
with sodium.
What could be the formula of X?
A CH
3
CH(OH)CHO
B CH
3
CH(OH)C0
2
H
C HOCH
2
CH(CH
3
)CH
2
OH
D HOCH
2
CH
2
C0
2
H
20 Bupropion is an anti-depressant used in the treatment of hyperactive children and adults.
CH
3
CH3fNHCH(CH3)CO-<Q
CH3 CI
bupropion
Which deduction about bupropion can be made from this structure?
A It contains an amide linkage.
B It gives a phenol on heating with aqueous sodium hydroxide.
C It is optically active.
D Its aqueous solution is acidic.
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21 Aldehydes and ketones are produced industrially by the catalytic oxidation of alkenes. For
example, ethanal is manufactured from ethene as shown.
The process is also used industrially with but-2-ene, CH
3
CH=CHCH
3
.
Which compound is obtained from but-2-ene?
A CH
3
CH
2
CHO
B CH
3
COCH
2
CH
3
C CH
3
CH
2
CH
2
CHO
D (CH3)2CHCHO
22 Hydrogen iodide undergoes an addition reaction with propene forming 2-iodopropane. When
propene is bubbled through iodine monochloride, ICI, dissolved in a suitable solvent, a similar
reaction occurs.
Which product will be present in the greatest yield?
A CH
3
CHCH
2
CI
I
CI
B CH
3
CHCH
2
1
I
I
C CH
3
CHCH
2
1
I
CI
D CH
3
CHCH
2
CI
I
I
23 Chlorofluorocarbons (CFCs) have been widely used in aerosol sprays, refrigerators and in
making foamed plastics, but are now known to destroy ozone in the upper atmosphere.
What will not destroy ozone, and therefore can be used safely as a replacement for CFCs?
A CHBr3
B CCl3CBr3
C CHCIFCCIF
2
D CH
3
CH
2
CH
2
CH
3
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24 A solid compound Z dissolved readily in water to give a weakly alkaline solution. On evaporation
of the water, Z was recovered unchanged.
What could Z be?
A CH NWCZ-
3 3
B CCl
3
C0
2
Na+
C
C
6
H
s
O-Na+
D H
2
NCH
2
C0
2
H
25 Which compound reacts with ammonia?
A bromoethane
B chlorobenzene
C ethanol
D phenol
26 All the isomeric alcohols with the molecular formula C
S
H
12
0 are added separately to warm
alkaline aqueous iodine.
How many of the isomers will give a yellow precipitate? (Ignore stereoisomers.)
A 0 B 1 C 2 D 3
27 Which reaction yields a carbon compound incorporating deuterium, O? [0 =2H]
NaOO
A CH
3
CH
2
CN
O
2
B CH
3
CD(OD)C0
2
H
acidified KMn0
4
heat
NaOO
UCLES &MOE 2007
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28 N-Methyl-D-aspartic acid is a neuroprotective agent which is used in the treatment of strokes,
trauma and epilepsy. Its structure is shown.
Which statement is not correct?
A It is optically active.
B It reacts with ethanol to form an ester.
C It reacts with ethanoyl chloride to form an ester.
D It reacts with phosphorus pentachloride to form an acyl chloride.
29 Which salt will be the most acidic in aqueous solution?
B C
6
H
s
NH; CZ-
C K+CZ-
D NH; CZ-
30 Which structure will be present when the amino acid aspartic acid,
is in aqueous solution at pH10?
A B C D
+ + +
H
3
NCHC0
2
H H
3
NCHC0
2
H
3
NCHC0
2
H H
2
NCHCO;
I I I I
CH
2
CH
2
CH
2
CH
2
I I I I
C0
2
H C0
2
H CO; CO;
UCLES &MOE 2007 9746/01/0/N/07
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Section B
For each of the questions in this section, one or more of the three numbered statements 1 to 3 may
be correct.
Decide whether each of the statements is or is not correct (you may find it helpful to put a tick against
the statements that you consider to be correct).
The responses A to D should be selected on the basis of
A B C D
1,2 and 3 1 and 2 2 and 3 1 only
are only are only are is
correct correct correct correct
No other combination of statements is used as a correct response.
31 Which systems contain delocalized electrons?
1 cyclohexene
2 graphite
3 sodium
32 Calcium reacts with water to form calcium hydroxide and hydrogen.
The standard enthalpy change for this reaction can be measured in the laboratory.
What further information is needed in order to calculate the standard enthalpy change of
formation of calcium hydroxide, tiH1?
1 tiH1 for H
2
0(I)
2 tiH1 for H
2
(g)
3 first and second ionisation energies of Ca
33 A theoretical reaction involves P + Q ~ product.
The rate equation is rate =k[P][QYand the units of the rate constant, k, are molY dm
z
s-
1