:

: - 4.1.5
: 2

2.2.1
V 10 m3
T1 313 K
T2 293 K
pm1 1, 2 MPa
pm 2 0,3 MPa
pb 750 mmHg
T 273 K

pb Hg g xHg 13590 9,81 0, 75 99988, 4 Pa

( Hg 13590 5.3 .105 T 273 K)
: R 287

J
kg K

( 3.1 .21)

p1 pb pm1 99988 1200000 1299988 Pa

p2 pb pm 2 99988 300000 399988 Pa
p1 V m1 R T1
p2 V m2 R T2
m m1 m2
m

p1 V p2 V V p1 p2

( )
R T1 R T2 R T1 T2

10 1299988 399988
(

) 97,15 kg
287
313
293

1/5

:2

2.2.3

VA 2 m 3
VB 1 m3
p A1 pB1 p1 0, 2 MPa
TA1 TB1 T1 300 K
TA 2 260 K
TB 2 T1 300 K
p2 ?
p1 VA1 mA1 R TA1
p1 VB1 mB1 R TB1
p2 VA1 mA 2 R TA 2
p2 VB1 mB 2 R TB1
mA1 mB1 mA 2 mB 2

p1 VA p1 VB p2 VA p2 VB

R T1
R T1
R TA 2
R T1

VA VB
) 2 105 ( 2 1)
T1
300 0,1814 MPa

VA VB
2
1

260 300
TA 2 T1

p1 (
p2

2.2.5

x0 1 m
x1 0, 02 m
pb p1 0,1 MPa
Tw Tb T 293 K

2/5

:2

p V m R T , m, T idem p V idem
pb A x1 p A A ( x1 x) p A pb

x1
x1 x

1 1: pb g x0 p A g x
pb g x0 pb

x1
g x
x1 x

/ ( x1 x)

( pb g x0 ) ( x1 x) x1 pb g x ( x1 x)
( pb g x0 ) x1 ( pb g x0 ) x x1 pb g x x1 g x 2

g x 2 ( pb g x0 g x1 ) x ( pb g x0 pb ) x1 0
( H 2O 998, 2

kg
m3

T 20 C 4.2.8 58)

.......
9792,34 x 2 109988,19 x 195,85 0
x1 11, 2 m

x2 0, 00178 m

x1 x1 x1
x2 0, 00178 m

3/5

:2

2.3.1
O 2
n 3 kmol
T1 773 K 500 C
T2 1773 K 1500 C

J
kg K
kg
M O2 32
kmol
m n M 3 32 96 kg
RO2 260

cp
cp

cp

500
0
1500
0

1500
500

kJ
kg K
kJ
1, 071
kg K

0,9791

cp

1500
0

1500 c p

( 3.6 25)

500
0

500

1500 500

1,117

cv c p R 1,117 0, 260 0,857

kJ
kg K

kJ
kg K

kJ
kmol K
kJ
cvm cv M 27, 424
kmol K

c pm c p M 35, 744

u u2 u1 (cv

T2
0

T2 cv 01 T1 ) (0,811 1500 0, 7191 500) 857

u u2 u1 cv (T2 T1 ) 0,857 (1500 500) 857

h h2 h1 c p (T2 T1 ) (c p

T2
0

T1

kJ
kg

kJ
kg

T2 c p T1 ) (1, 071 1500 0,9791 500) 1117

0

kJ
kg

Q p ,1 2 m c p (T2 T1 ) 96 1,117 1000 107232 kJ

4/5

:2

2.3.2

cmp

T
0

29, 2 4, 07 103 (T 273)

T1 773 K 500 C
T2 1773 K 1500 C
a)
p idem
V2 0,8 m3
c pm
c pm

c pm

290
0
573
0

300
17

c pm

17

c pm

300

cp

300
0

J
mol K
J
30, 421
mol K

29, 269

300 c p

17
0

17

300 17

29,8

J
mol K

Q p ,1 2 m c p (T2 T1 ) n M c p (T2 T1 ) n c pm (T2 T1 )

p V2 n Ru T2 n

Q p ,1 2

p V2
Ru T2

p V2
1,5 106 0,8

c pm (T2 T1 )
29,8 (573 290) 2,128 MJ
Ru T2
8,314 573

b)
Qv ,1 2 n cvm (T2 T1 )

p V2
(c pm Ru ) (T2 T1 )
Ru T2

1,5 106 0,8

(29,8 8,314) (573 290) 1,58 MJ

8,314 573

5/5