ANKEN nh ngha, ng phn,cu trc,danh php 1.Anken l nhng hirocacbon A.Khng no,mch h,phn t c t nht 1 lin kt i C=C. B.

Khng no,mch vng,phn t c 1 lin kt i C=C. C.Khng no,mch h,phn t c mt lin kt i C=C. D.Khng no,mch h, phn t c mt hoc 2 lin kt i. 2.Cng thc phn t ca cc anken c dng A.CnH2n+2(n 2) B.CnH2n(n 3) C.CnH2n(n 2) D.CnH2n-2(n 3) 3.Anken c my loi ng phn (k c ng phn lp th)? A.1 B.2 C.3 D.4 4.Anken C4H8 c s ng phn cng chc l : A.3 B.4 C.6 D.7 5.C bao nhiu anken ng phn cu to ca nhau c cng cng thc phn t C4H8(3) A.2. B.3. C.4. D.5. 6.Anken 3-metylpent-2-en c cng thc cu to no di y?

7.Cho anken X c cng thc cu to sau:

Tn y ca X l: A.cis-pent-2-en B.trans-pent-2-en C.trans-pent-3-en D.cis-pent-3-en 8.Trong phn t eten,2 nguyn t cacbon u trng thi lai ha A.sp B.sp2 C.sp3 D.sp4 9. iu kin thng,nu anken l cht kh th trong phn t c cha s cacbon l A.t 2 n 3 B.t 2 n 4 C.t 2 n 5 D.t 2 n 6 10Trong phn t anken, 2 nguyn t cacbon mang ni i u dng lai ha : A.tam gic B.ng thng C.lp th D.t gic. THNH PHN NGUYN T,PTK 11.Theo chiu tng s nguyn t cacbon trong phn t,phn trm khi lng ca cacbon trong phn t anken A.Tng dn B.Gm dn C.Khng i D.Bin i khng theo quy lut 12.Anken X c t khi so vi nit bng 2.CTPT ca X l A.C3H6 B.C4H8 C.C4H10 D.C5H10 13.3 hiro cacbon X,Y,X l ng ng k tip nhau trong dy ng ng.Phn t lng ca X bng mt na phn t lng ca Z.Vy X,Y,Z c CTPT ln lt l A.C2H4,C3H6,C4H8 B.CH4,C2H6,C3H8 C.C2H2,C3H4,C4H6 D.C3H6,C4H8,C5H10 14.3 hiro cacbon A,B,C l ng ng k tip nhau trong dy ng ng,Phn t lng ca C gp i phn t lng ca A.Vy A,B,C thuc dy ng ng: A.ankan B.anken C.ankin D.xicloankan P CNG H2

15.Mt hn hp anken A v H2 c d=0,689 cho qua niken,un nng A b hiro ha hon ton th t khi hn hp mi l 1,034(hh kh trc v sau trong cng k t,p).CTPT A l: A.C3H6 B.C5H10 C.C4H8 D.C6H12 P HALOGEN HA 16.C bao nhiu cht ng phn cu to c cng cng thc phn t C4H8 tc dng c vi brom(dung dch) A.5 B.6 C.4 D.3 17.Cho2,24 lt anken X(cn) tc dng vi brom(trong dung dch) thu c sn phm c khi lng ln hn khi lng anken l A.8,0 gam B.10,0 gam C.12,0 gam D.16,0 gam 18.Dn 0,2 mol mt olefin A qua dung dch Brom d,sau p khi lng bnh tng 5,6 gam.Vy cng thc phn t ca A l: A.C2H4 B.C3H6 C.C4H8 D.C5H10. 19.Anken Y tc dng vi brom to thnh dn xut ibrom trong phn trm khi lng cacbon bng 17,82%.CTPT ca Y l: A.C3H6 B.C4H8 C.C4H10 D.C5H10 20.Dn t t 5,6 lt hh Y gm C2H4 v C2H6 i vo dd brom thy dd brom nht mu v cn 4,48 lt kh thot rA.Cc th tch kh o cn.Phm trm th tch ca etilen trong hh Y l: A.25% B.40% C.20% D.50% 21.4,48 lt hh X gm propilen v xiclopropan(cn) c th tc dng ht bao nhiu lt dung dch brom 0,1M A.2,0 lt B.1,0 lt C.1,5 lt D.2,5 lt P CNG NC,AXIT 22.Theo quy tc Maccopnhicop,trong phn ng cng axit hoc nc vo ni i ca anken th phn mang in dng cng vo A.Cacbon bc cao hn B.Cacbon bc thp hn C.Cacbon mang ni i,bc thp hn D.Cacbon mang ni i, c t H hn 23.But-1-en tc dng vi HBr to ra sn phm chnh l A.1-clobuten B.2-clobuten C.1-clobutan D.2-clobutan 24.Hn hp gm propen v B(C4H8) tc dng vi HBr,un nng to ta hn hp c 3 sn phm.Vy B l: A.but-1-en B.but-2-en C. -butilen D.i-butilen 25.Cho mt th tch kh anken X tc dng vi nc (xt axit) c 4,6 gam ancol Y;nu cho lng anken X trn tc dng vi HBr thu c 10,9 gam cht Z.CTPT anken l A.C2H4 B.C3H6 C.C4H8 D.C5H10 26.Mt olefin X tc dng vi HBr cho hp cht Y.X tc dng vi HCl cho cht Z.Bit % C trong Z>%C trong Y l 16,85%.X l: A.C3H6 B. C5H10 C.C4H8 D.C6H12 P TRNG HP 27.Sn phm trng hp C2H4 l A.poli(etilen) B.polietilen C.poliepilen D.polipropilen 28.Sn phm trng hp propen l A.[CH2-CH(CH3)]n B.n(CH2-CH(CH3)) C.( CH2-CH(CH3) )n D. n[CH2-CH(CH3) ] 29.Mt on pilietilen c phn t khi M= 140000 vC.H s trng hp l: A.500 B.5000 C.50000 D.50 P OXI HA KHNG HON TON 30.Sn phm oxi ha etilen bng dd thuc tm l

A.HOCH2-CH2OH B.KOOCH2-COOK C.HOCH2-CHO D.HOOCH2-COOH 31. Sn phm phn ng oxiho propilen bng dung dch thuc tm l : A.propan-1,1-iol B.propan-1,2-iol C.propan-1,3-iol D.propan-1,3-ial 32.T etilen c th iu ch c cht no? A.etilen glicol B.etilenoxit C.anehit axetic D.c a,b,c 33.Trong phn ng oxiha anken CnH2n bng dung dch thuc tm c tng h s cc cht lc cn bng l A.15 B.16 C.17 D.18 34.Trong phn ng oxi ha anken CnH2n bng dung dch thuc tm c h s KMnO4 lc cn bng l A.2 B.3 C.4 D.5 35.Mt hn hp X gm 2 olefin ng ng k tip c th tch 1,792 lt(0C,2,5atm)sc qua dd KMnO4(d),khi lng bnh tng 7 gam.CTPT ca 2 olefin l: B A.C5H10,C6H12 B.C2H4,C3H6 C.C4H8,C5H10 D.C3H6,C4H8 P CHY 36.Khi t chy hirocacbon A ta thu c s mol CO2= s mol H2O.A l: A.anken hoc xicloankan B.xicloankan hoc ankan C.monoxicloankan D.anken hoc monoxicloankan 37. t chy 1 th tch hirocacbon mch h X cn 6 th tch oxi,to ra 4 th tch CO2,X cng HCl to ra 2 sn phm.Vy X l: A.but-1-en B.i-butilen C.but-2-en D.i-butylen 38. 4,48 lt hh etilen v propilen (ktc) tc dng vi oxi d thu c 22,0 gam kh CO2.Phn trm th tch ca etilen trong hn hp bng A.25% B.40% C.75% D.50% 39. t chy hon ton 1 lt kh hirocacbon X cn 4,5 lt oxi sinh ra 3 lt CO2(cng k).X c th lm mt mu dd KMnO4.Vy X l: A.propan B.propen C.propin. D.propaien 40.t 1 hn hp gm 1 th tch anken, 1 lng oxi c th tch gp 2 ln th tch kh oxi cn dng.Sau khi cho hi nc ngng t,a v iu kin ban u,th tch gim 25% so vi hh ban u.Cu to olefin l A.CH2=CH-CH2CH3 B.CH3CH2=CH-CH2CH3 C.CH2=CH-CH3 D.C a v B u ng 41.Hn hp X gm 1 ankan A v 1 anken B(u th kh).S nguyn t Ccbon trong B nhiu hn trong A. TN1: t 0,1 mol hn hp gm a mol A v b mol B thu c khi lng CO2ln hn khi lng nc l 7,6 gam. TN2: t 0,1 mol hn hp gm b mol A v a mol B thu c khi lng CO2ln hn khi lng ca nc l 6,2 gam.CTPT ca A,B ln lt l: A.C2H6,C4H8 B.C2H6,C3H6 C.C2H6,C5H10 D.C3H8,C4H8 42.Thc hin phn ng Crackinh hon ton 6,6 gam propan thu c hn hp A gm 2 hirocacbon.Cho A qua bnh cha 125ml dung dch brom c nng x mol/lt,dung dch brom b mt mu.Kh thot ra khi bnh brom c t khi i vi metan bng 1,1875.Ga tr ca X l: A.0,08M B.0,8M * C.1,8M D.0,18M 43. phn bit propen vi propan ,ta dng : A.dung dch brom B.dung dch thuc tm C.dung dch brom trong CCl4 D.c a,b,c.*

44. lm sch metan c ln etilen ta cho hn hp qua : A.kh hiro c Ni ,t. B.dung dch Brom.* C.dung dchAgNO3/NH3. D.kh hiroclorua. ANKAIEN NH NGHA,NG PHN,CU TRC,DANH PHP 1.Ankaien l: A.hirocacbon c 2 ni i C=C trong phn t. B.hirocacbon,mch h c 2 ni i C=C trong phn t.* C.hirocacbon c cng thc l CnH2n-2 trong phn t. D.hirocacbon ,mch h c cng thc l CnH2n-2 trong phn t. 2.Ankaien lin hp l: A.Ankaien c 2 lin kt i C=C lin nhau. B.Ankaien c 2 lin kt i C=C cch nhau 2 ni n. C.Ankaien c 2 lin kt i C=C cch nhau 1 ni n.* D.Ankaien c 2 lin kt i C=C cch xa nhau 3.Ankaien CH2=CH-CH=CH2 c tn gi quc t l: A.ivinyl B.1,3-butaien C.butaien-1,3 D.buta-1,3-ien* 4.Ankaien CH2=CH-CH=CH2 c tn gi thng thng l: A.ivinyl* B.1,3-butaien C.butaien-1,3 D.buta-1,3-ien 5.Trong phn t buta-1,3-ien , Cacbon trng thi lai ho: A.sp B.sp2 * C.sp3 D.sp3d2 P CNG 6.A(ien lin hp) + H2 isopentan.Vy A l: A.isopren* B. 2-metyl-1,3-butaien C.2-metyl-butaien-1,3 D.2-metylpenta-1,3-ien 7.ivinyl tc dng cng Brom theo t l mol 1:1 to ra sn phm : A.cng 1,2 v cng 1,3. B.cng 1,2 v cng 2,3. C.cng 1,2 v cng 3,4. D.cng 1,2 v cng 1,4* 8.ivinyl tc dng cng HBr theo t l mol 1:1, -80C to ra sn phm chnh l: A.3-brom-but-1-en* B..3-brom-but-2-en C.1-brom-but-2-en D.2-brom-but-3-en 9.ivinyl tc dng cng HBr theo t l mol 1:1, 40C to ra sn phm chnh l: A.3-brom-but-1-en B.3-brom-but-2-en C.1-brom-but-2-en* D..2-brom-but-3-en

P CHY 10.t chy hon ton hiro cacbon kh X thu c sn phm cha 76,52 % CO2 v khi lng.Cng thc phn t ca X l: A.C2H6 B.C3H6 C.C4H6* D.C4H8 11.4,48 lt(ktc)mt hirocacbon A th kh trong iu kin thng tc dng va vi 100ml dd brom 1M thu c sn phm cha 85,562% Br v khi lng.Cng thc phn t ca A l: A.C2H6 B.C3H6 C.C4H6* D.C4H8 12.t chy hon ton m gam hn hp gm buta-1,3-ien v isopren thu c 0,9 mol CO2 v 12,6g nc.Gi tr ca m bng: A.12,1g B.12,2g* C.12,3g D.12,4g 13.t chy hon ton agam hn hp gm buta-1,3-ien v isopren thu c 20,16l CO2 ktc v 12,6g nc.Th tch oxi cn dng ktc l: A.28 lit.* B.29 lit C.18 lit D.27 lit 14.t 0,05 mol cht A(C,H) thu c 0,2 mol H2O.Bit A trng hp cho B c tnh n hi.Vy A l: A.buta-1,3-ien B.2-metylbuta-1,3-ien C.2-metylbuta-1,2-ien D.2-metylbuta-1,3-ien* P TRNG HP 15.Sn phm trng hp A Cao su BuNA.Vy A l: A.2-metyl-butaien-1,3 B.1,3-butaien C.butaien-1,3 D.buta-1,3-ien* 16.Sn phm trng hp B Cao su isopren.Vy B l: A.isopren* B. 2-metyl-1,3-butaien C.2-metyl-butaien-1,3 D.2-metylpenta-1,3-ien 17.Sn phm trng hp ca ivinyl c tn gi l: A.poly(butaien) B.polybutaien* C.poly(isopren) D.polyisopren 18.Sn phm trng hp ca isopren c tn gi l: A.poly(butaien) B.polybutaien C.poly(isopren) D.polyisopren* 19.Sn phm trng hp ca: CH2=C(CH3)-CCl=CH2 c tn gi l: A.Cao suBuNa B.Cao isopren C.Cao suBuNa-S D.Cao cloropren* TNG HP nhn bit butan v buta-1.3-ien ta c th dng thuc th: A.dd brom B.dd thuc tm C.kh H2 D.dd brom hoc thuc tm*

 nhn bit but-1-en v buta-1.3-ien ta c th dng thuc th: A.dd brom v phng php nh tnh B.dd brom v phng php nh lng* C.kh H2 v phng php nh tnh D.dd thuc tm v phng php nh tnh Cho s phn ng etilen A(C,H,O) B Cao su BuNA. Vy A ; B ln lt l: A.buta-1,3-ien ; etanol B.etanol ; buta-1,3-ien* C.etanol ; buta-1,2-ien D.etanal ; buta-1,3-ien Cho s phn ng 3-metyl-but-1-en A B Cao su isopren. A , B ln lt l: A. isopren ; isopentan B.isopentan ; isopren .* C.isopenten ; isopren D.isobutan ; but-1,3-ien :Cho s phn ng axetilen AB Cao su BuNA. Vy A , B ln lt l: A.buta-1,3-ien ; etanol B.etanol ; buta-1,3-ien C.vinyl axetilen ,buta-1,3-ien, D. buta-1,3-ien,vinyl axetilen* ANKIN NH NGHA,NG PHN,CU TRC,DANH PHP Ankin l hirocacbon: A.c dng CnH2n-2,mch h B. c dng CnH2n+1,mch h C.Mch h ; 1 lin kt ba trong phn t* D.a,c u ng. Dy ng ng ca axetilen c cng thc chung l: A. CnH2n+2 (n>=2) B. CnH2n-2 (n>=1) C. CnH2n-2 (n>=3) D. CnH2n-2 (n>=2)* Cc ankin c ng phn v tr khi s cacbon trong phn t ln hn hoc bng : A.2 B.3 C.4* D.5 Cc ankin bt u c ng phn mch C khi s C trong phn t: A. 2 B. 3 C. 4 D. 5* C5H8 c s ng phn cu to ca ankin l: A.2 B.3* C.4 D.5 CH3-C C-CH2-CH3 ; c tn gi h thng thay th l: A.etylmetylaxetilen B.pent-3-in C.pent-2-in* D.pent-1-in S cng thc cu to c th c ca ankin C4H6 l: A.1 B.2* C.3 D.4 Trong phn t axetilen lin kt ba gia 2 Cacbon gm: A.1 lin kt pi v 2 lin kt xich-ma B.2 lin kt pi v 1 lin kt xich-ma*

C. 3 lin kt pi D.3 lin kt xich-ma Trong phn t ankin hai nguyn t Cacbon mang ni ba dng lai ho: A.sp* B.sp2 C.sp3 D.sp3d2 di ca lin kt ba,lin kt i,lin kt n gia 2 nguyn t C tng theo th t: A.ba,n,i B.n,ba,i C. i,n,ba D. ba,i,n* ben ca lin kt ba,lin kt i,lin kt n tng theo th t: A.ba,n,i B.n,i,ba* C. i,n,ba D. ba,i,n THNH PHN NGUYN T,PTK A,B,C l 3 ankin k tip nhau trong dy ng ng c tng khi lng 162 vC.Cng thc A,B,C ln lt l: A.C2H2;C3H4;C4H6 B.C3H4;C4H6;C5H8* C.C4H6;C3H4;C5H8 D.C4H6;C5H8;C6H10 A,B l 2 ankin ng ng th kh ,trong iu kin thng T khi hi ca B so vi A bng 1,35.Vy A,B l: A.etin;propin B.etin;butin C.propin;butin* D.propin;pentin Mt trong nhng loi ng phn nhm chc ca ankin l: A.ankan B.anken C.Ankaien* D.aren Axetilen + CH3COOH (xt) A.Vy A l: A.etylaxetat B.vinylaxetat* C.etilenglicol D.metylacrylat P CNG HIRO Nu chuyn ho ankin thnh anken ta thc hin phn ng cng H2 trong iu kin c xc tc: A.Ni/ t B.Mn/ t C.Pd/ PbCO3* D.Pb/PdCO3 Nu chuyn ho ankin thnh ankan ta thc hin phn ng cng H2 trong iu kin c xc tc: A.Ni/ t* B.Mn/ t

C.Pd/ PbCO3 D.Pb/PdCO3 P NH HP, TAM HP Trong iu kin thch hp (C;600C),axetilen tham gia phn ng tam hp to thnh phn t: A.stiren B.benzen* C.toluen D.hexen Propin tham gia phn ng tam hp to ra sn phm: A.1,2,3-trimetylbenzen B. 2,4,6-trimetylbenzen C. 1,3,5-trimetylbenzen* D.etyl,metylbenzen Trong iu kin thch hp pent-2-in tam hp thnh sn phm: A.1,2,3-trietyl-4,5,6-trimetylbenzen B. 1,2,4-trietyl-3,5,6-trimetylbenzen C. 1,3,5-trietyl-2,4,6-trimetylbenzen* D. 4,5,6-trimetyl-1,2,3-trietyl-benzen P TH KIM LOI Cho cc cht (1)but-1-in (2)but-2-in (3)propin (4)buta-1,3-in.Cc cht c phn ng vi dd AgNO3/NH3 to kt ta vng nht l: A.(1),(3),(4)* B. (2),(3),(4) C. (1),(2),(3) D. (1),(2),(4) HC CH + [Ag(NH3)2](OH)2 A + B + H2O .Vy A,B ln lt l: A. HC CAg ; NH3 B. AgC CAg ; NH3 * C. AgC CAg ; NH4NO3 D. HC CAg ; NH4NO3 Cho A(C4H6)c phn ng vi AgNO3/NH3 to kt ta vng nht .A l: A.But-2-in B.But-1-en C.But-2-en D.But-1-in* R-C CH + AgNO3 + NH3 + H2O A +B. A ,B ln lt l: A. R-C CAg B. R-C CAg ; NH4NO3 * C. Ag ; NH4NO3 D. R-CAg=CAg ; NH4NO3 Cho 1,3 g ankin A cht kh k thng tc dng vi dd AgNO3/NH3 to 12 g kt ta vng nht.Vy CTPT ca A l: A.C2H2* B.C3H6 C.C3H4 D.C4H8 Mt hn hp X gm 1 g propin v 2,7 g ankin B(C4H6) tc dng vi dd AgNO3/NH3 to 3,675 g kt ta.Vy B l: A.but-1-in B.but-2-in* C.ivinyl D. but-1-in hoc but-2-in P OXI HO KHNG HON TON t chy a mol ankin b mol CO2 v c mol H2O.Quan h gia a,b,c l: A.b>c v a= b-c* B. b<c v a= b-c

C. b>c v a= b+c D. b>c v a= c-b t chy hon ton 4 g ankin A 6,72 l CO2 (ktc) v 3,6 ml H2O(lng).Cng thc phn t A l: A.C2H2 B. C3H4 * C. C4H6 D. C5H8 t chy ht 5,4 g Hirocacbon X(CnH2n-2) thu c 0,4 mol CO2 v 0,3 mol H2O.X tc dng vi dd AgNO3/NH3 to kt ta vng nht.Vy X l: A.But-1-in* B.but-2-in C.buta-1,2-ien D. buta-1,3-ien t chy hon ton 0,2 mol ankin A 0,4 mol H2O.Hiro ho hon ton 0,2 mol ankin A ri t ht sn phm to thnh thu c a mol H2O.Gi tr ca A l: A.0,8* B.0,6 C.1,25 D.2,5 t chy V(l) (cn) mt ankin A 21,6 g H2O.Nu cho ton b sn phm chy hp th hon ton vo bnh ng dd nc vi trong ly d ,th khi lng bnh tng 100,8 g .V c gi tr l: A.6,72l B.4,48l C.3,36l D.13,44l* t chy V(l) (cn) mt ankin th kh thu c CO2 v H2O c tng khi lng bng 50,4 g.Nu cho sn phm chy qua bnh ng nc vi trong th thu c 90 g kt ta.V c gi tr l: A.6,72l* B.4,48l C.3,36l D.13,44l NG DNG,IU CH Cho s : Kh thin nhin A + HCl B P.V.C Vy A,B ln lt l: A.axetilen;vinylclorua* B. vinylclorua; axetilen C. axetilen;1,1-icloetan D. axetilen;1,2-icloetan vi ABCDP.V.C .A,B,C,D ln lt l: A.Canxioxit;etin;t n;vinylaxetat B. t n;Canxioxit;etin; vinylaxetat C. Canxicacbua;etin;t n;vinylaxetat D. Canxioxit ;t n;etin; vinylaxetat* CH4 ABDCaosu BuNa .A,B,D ln lt l: A.axetilen;vinylaxetilen;buta-1,3-ien* B. axetilen;vinylaxetilen;butaien-1,3 C. vinylaxetilen;axetilen; buta-1,3-ien D. axetilen;but-2-en;buta-1,3-ien 08-A-H Cu 48: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l 2. B. 3. C. 1. D. 4. CH2=CH-CH=CH-CH2-CH3 =>Cu C 08-B-H Cu 21: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra chy chy, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t

chy chy chy 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o cn) CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6. k(hirocacbon khng no) = (4/160)/[(1,68 1,12)/22,4] = 1 =>loi B. n(trung bnh) = 2,8/1,68 = 5/3 = 1,67 =>loi D. n(hirocacbon khng no) = (2,8 1,12*1)/0,56 = 3 =>CTPT ca hai hirocacbon l : CH4 v C3H6 Cu 38: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy chy chy 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l 3. B. 4. C. 2. D. 5. X ->6CO2 =>X c 6C. X mch h, ch cha lin kt =>X l C6H14. X c 2 nguyn t C bc ba =>X l : 2,3-imetylbutan. Cho X tc dng vi Cl2 (t l mol 1:1) ch sinh ra ti a 2 dn xut monoclo =>cu C Cu 48: t chy chy chy 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l C2H6. B. C2H4. C. CH4. D. C3H8. S nguyn t C trung bnh = 2/1 = 2 =>X c 2C. Do : V(CO2) = V(H2O) =>X l ankan. => X l C2H6. =>Cu A Cu 49: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng ankan. B. ankaien. C. anken. D. ankin. Gi X l CaHb =>Z l CaHb(C2H4) M(Z) = 2M(X) => CaHb C2H4 => Cc cht X, Y, Z thuc dy ng ng 09-A-H Cu 30: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( cn). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4. Pp th m=0.2*42+0.1*40=12.4g =>Cu D

Cu 45: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to ra kt ta l A.3. B. 4. C. 5. D. 2. C2H2, HCHO, HCOOH, CH COOCH3 =>Cu B 09-B-H Cu 19: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra chy chy, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. B. CH2=CH2. C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3. CnH2n Ni CnH2n+2 H2 MX=18,2 MY= 26 t s mol ca X=1 mol=>mX =18,2g Bo chy khi lng: mX=mY =>nY=0,7 mol=>n H2p= 0.3 mol=nCnH2n=>nH2b=0,7mol 0,7.2 +14 n.0,3 1,4 + 4,2n 1 1 M X= =>18,2= =>n=4=>C4H8 cng HBr cho sn phm hu c duy nht=>anken l CH3-CH=CH-CH3 =>Cu D Cu 23: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. buta-1,3-ien; cumen; etilen; trans-but-2-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl cloruA. =>Cu D Cu 35: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( cn) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt tA. Phn trm th tch ca CH4 c trong X l 20%. B. 50%. C. 25%. D. 40% Trong13,44 lit X : S mol hn hp X = 13,44/22,4 = 0,6 mol S mol C2Ag2= 36/240 = 0,15 mol.Suy ra s mol C2H2= 0,15 mol S mol Br2P = 48/160 = 0,3 mol Trong 8,6gam X: CH4: amol; C2H4: bmol; C2H2: c mol Trong 13,44 lit X: CH4: na mol; C2H4: nb mol; C2H2: nc mol Ta c: 16a + 28b + 26c = 8,6 b + 2c = 0,3 nc = 0,15 na + nb + nc = 0,6% a = 0,2

=>b = 0,1 c = 0,1 V ca CH4= (0,2/0,4).100 = 50%=>B Cu 43:Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l but-1-en. B. xiclopropan. C. but-2-en. D. propilen. Theo bi th X s cha 1 lk i(cng HBr->2 sn phm) CnH2n+ Br2=>CnH2nBr2 Ta c %mBr= 74,08% =>n=4 v da vo X cng HBr cho 2 sp=>p n A 2010-A-H Cu 9: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (cn) thot rA. T khi ca Z so vi H2 l 10,08. Gi tr ca m l 0,585. B. 0,620. C. 0,205. D. 0,328. mX=0,58g MZ=20,15;nZ=0,0125mol=>mZ=0,252g M bnh tng = m hh- m kh bay ra =0,328g=>D Cu 33: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l 3-etylpent-3-en. B. 2-etylpent-2-en. C. 3-etylpent-2-en. D. 3-etylpent-1-en. =>Cu C Cu 50: t chy chy chy mt lng hirocacbon X. Hp th chy b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l C3H8. B. C2H6. C. C3H4. D. C3H6 n kt ta = 0,15= n CO2 m dd gim = m kt ta m vo=>19,35=29,55-m vo=>m vo=10,2=>mH2O=0,2 mol nC:nH=0,15:0,4=3:8=>Cu A 2010-B-H Cu 13: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy chy chy 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o cn). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8. M =22,5=>c CH4(M=14<22,5) mX mC 2 nCO2=0,3=>H2O= =0,45 n CH4=n H2O-NCO2=0,15=>n anken= 0,05mol nCO 2 nCO 2(CH 4) nanken nC anken= =3=>Chn cu C Cu 23: Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy chy chy M, thu c 8,96 lt kh CO2 (cn) v 7,2 gam H2O. Hirocacbon Y l CH4. B. C2H2. C. C3H6. D. C2H4.

Anehit no,n CnH2nO n CO2= n H2O=0,4=>Y l anken n = 2 =>c 2 cht u c 2C=>chn D