MT S BI TON T LUN HIROCCBON NO Cu 1: Bnh kn dung tch 2 lt 27,30C cha 0,03 mol C2H2, 0,015 mol C2H4 v 0,04

4 mol H2 c p sut P1. Tnh P1. -Nu trong bnh c t xc tc Ni (V khng ng k), nung bnh nhit cao n phn ng hon ton, sau a v nhit ban u c hh kh A c p sut P2. Tnh P2. - Cho A tc dng vi dd AgNO3/NH3 d thu c 3,6 gam kt ta. Tnh s mol mi cht trong A. Cu 2: 1) t chy hon mt hirocacbon A c CO2 v H2O theo t ln mol 2:1. Bit, nu lng oxi dng nhiu hn 20% so vi lng oxi cn thit phn ng th th tch hh kh thu c sau phn ng bng 2,5 ln th tch A ( o cng ktc). Xc nh A. 2) Gi X l hh gm A v B (vi B l mt HCB thuc cng dy ng ng vi A) , th tch X l 17,92 lt ktc, khi lng X l 29,2 gam. Cho X qua dd AgNO3/NH3 d c 120 gam kt ta. Xc nh B. 3) Gi Y l hh gm 17,92 lt hh X trn v H2. Cho Y vo mt bnh kn th tch 11,2 lt c cha t Ni th p sut P1=5,6 atm 00C. Nung bnh mt thi gian sau a v 00C th p sut gim 4/7 so vi p sut ban u. Hi phn ng c hon ton khng ? Tnh t khi ca hh Z sau phn ng so vi H2? Cu 3: Mt hh gm H2 v 2 hirocacbon X, Y mch h cha trong bnh kn c xa tc Ni, th tch bnh 8,96 lt (00C , 2 atm). Nung bnh mt thi gian ri a bnh v 00C th thu c hh kh B c p sut 1,5 atm. Dn B qua dd Br2 th nc brom b nht mu, cn li 1 hirocacbon duy nht X i ra khi bnh. t X c CO2 v H2O theo t l khi lng 88:45. t 1/2B cn li c 30,8 gam CO2. Xc nh CTPT, vit CTCT, tnh % th tch ca X, Y trong A.

Cu 4: X l hh 3 HCB mch h c s nguyn t hiro khc nhau, c dX/H2 = 21,2. t chy hon ton 4,24 gam X c 6,72 lt CO2 ktc. Khi cho 2,12 gam X vo bnh kn c th tch 560ml cha Ni (V khng ng k) th p sut bnh l P1. Cho tip H2 vo bnh th p sut bnh l P2=2P1. Nung bnh, p sut gim dn n gi tr nh nht l P. Lc ny trong bnh ch cha 2 kh khng lm mt mu nc brom.

Bit trong X hirocacbon c phn t khi nh nht chm 20% th tch hh. Tnh P1, P. Xc nh CTPT ca 3 hirocacbon Cu 5: Hn hp X gm 2 hirocacbon A, B cng s nguyn t C, u l cht kh iu kin tiu chun. t chy 17,92 lt hh kh X vi 67,2 lt O2 d, sau a v ktc th thu c hh X c th tch 49,28lt. Cho X qua dd KOH d cn li 13,44 lit kh thot ra. a) Xc nh CTPT A, B v % th tch ca chng c trong hh X. b) Ly 17,92 lt hh X, thm 1,2 gam H2 c hh Y. Cho Y qua Ni nung nng thu c hh Z vi dY/Z = . Cho Z qua nc brom d th cn li hh kh T c dT/H2=10. Tnh % th tch ca hh Z v T. (cho cc th tch o ktc)