BASE VALUES

OH
NH
CH

3600
3400

EXPANDED CH

3000
3300 3100 2900
C-H

=C-H

-C-H

2850
2750
-CHO

3000
CH2 and CH3 bend :

1465 and 1365

C N 2250
C C 2150

1800 1735 1725 1715 1710 1690

C=O 1715

acid
chloride

C=C 1650

anhydride :

C-O

benzene C=C : between 1400 and 1600

1100

aldehyde
acid
ester
ketone

amide

1810 and 1760

EXPANDED C=O

Also remember the effects of H-bonding, conjugation and ring size.

-OH -NH

DOWNFIELD
DESHIELDED

UPFIELD
SHIELDED

CHCl3 ,

TMS

12

RCOOH

11

10

RCHO

H
C=C

CH2F
CH2Cl
CH2Br
CH2I
CH2O
CH2NO2

(ppm)

CH2Ar
C-CH-C
CH2NR2
C
CH2S
C-CH2-C
C C-H
C=C-CH2 C-CH3
CH2-CO

Ranges can be defined for different general types of protons.

This chart is general, the next slide is more definite.

APPROXIMATE CHEMICAL SHIFT RANGES (ppm) FOR SELECTED TYPES OF PROTONS

R-CH3
R-CH2-R
R3CH

0.7 - 1.3
1.2 - 1.4
1.4 - 1.7

R-C=C-C-H
O

1.6 - 2.6

R-C-C-H
O

2.1 - 2.4

RO-C-C-H
O

2.1 - 2.5

HO-C-C-H

2.1 - 2.5

N C-C-H

2.1 - 3.0

R-C C-C-H

2.1 - 3.0

C-H
R-C C-H

2.3 - 2.7
1.7 - 2.7

R-N-C-H

2.2 - 2.9

R-S-C-H

2.0 - 3.0

I-C-H

2.0 - 4.0

Br-C-H

2.7 - 4.1

Cl-C-H

3.1 - 4.1

RO-C-H

3.2 - 3.8

HO-C-H
O

3.2 - 3.8

R-C-O-C-H

3.5 - 4.8

O2N-C-H

4.1 - 4.3

F-C-H

4.2 - 4.8

R-N-H 0.5 - 4.0

R-O-H 0.5 - 5.0

R-C=C-H
4.5 - 6.5
H
6.5 - 8.0
O
R-C-N-H
5.0 - 9.0
O
R-C-H
9.0 - 10.0
O
R-C-O-H
11.0 - 12.0

Ar-N-H 3.0 - 5.0 R-S-H

Ar-O-H 4.0 - 7.0 1.0 - 4.0

ALKENES

10

11
s

Monosubstituted

12

13

14

15

Disubstituted
s

cis-1,2-

trans-1,2-

1,1-

Trisubstituted

Tetrasubstituted

=C-H OUT OF PLANE BENDING

1000

900

800

700 cm-1

BENZENES

10

11

12

13

14

Monosubstituted

Disubstituted
ortho

s
m

meta

para

s
RING Hs
OOPS

Trisubstituted
m

1,2,4

1,2,3

1,3,5
combination bands

15

s
1000

900

m
m

800

700 cm-1