THE PAPER OF ANALYTICAL CHEMISTRY EXPERIMENT III

IRON AXTRACTION

By :

-AISAH IKA W. (K3309006) - FEBRIYANI S. (K3309039) -NURUL AINI (K3309064)

- VIANDHIKA D. (K3309083)

DEPARTMENT OF METHEMATICS AND NATURE SCIENCES EDUCATION SEBELAS MARET UNIVERSITY SURAKARTA 2011

I. II. III.

TITLE IRON AXTRACTION PURPOSE - Determine the influence of pH toward Dc value OBSERVATION DATA Observation pH pH - pH FAS + Buffer - 3 -4 - Up layer color - Grey - Grey Bottom layer color - Yellow - Yellow

pH -6 - More grey - Colorless

pH -8 - Black - Colorless

Up Layer pH 4 5 7 8 Bottom layer pH 4 5 7 8 Standard Solution FAS (M) 0.001 0.003 0.005 Absorbance 0.008 0.059 0.046 0.638 Absorbance 0.035 0.036 0.041 0.058

Absorbance Water 0.002 0.003 0.005

Absorbance Chloroform 0.001 0.003 0.004

CALCULATION First making the graph of concentration Vs Absorbance standard solution

The Graph of Fe3+ in up layer

0.006 0.005 Absorbance 0.004 0.003 0.002 0.001 0 0 0.001 0.002 0.003 0.004 0.005 0.006 Concentration y = 0.75x + 0.0011 R = 0.9643

Y Linear (Y)

The graph of Fe3+ in bottom layer

0.0045 0.004 0.0035 Absorbace 0.003 0.0025 0.002 0.0015 0.001 0.0005 0 0 0.001 0.002 0.003 0.004 0.005 0.006 Concentration Y Linear (Y) y = 0.75x + 0.0004 R = 0.9643

From graph of standard solution above we making graph to up and bottom layer.

Data that obtained from graphic - Up Layer pH 4 5 7 8 Bottom layer pH 4 5 7 8

Absorbance 0.035 0.036 0.041 0.058

Concentration 0.043 0.044 0.047 0.069

Absorbance 0.008 0.059 0.046 0.638

Concentration 0.02 0.06 0.59 0.85

Determine of Dc

Dc = pH 4 Dc = = 0.465 pH 5 Dc = = 1.364 Making graph of log Dc Vs pH Dc 0.465 1.364 12.553 12.319 Log Dc (Y) -0.333 0.135 1.099 1.091 - pH 7 Dc = = 12.553 - pH 8 Dc = = 12.319

pH (X) 4 5 7 8

Graphic of relation between Log Dc Vs pH Buffer

1.5 1 Log Dc 0.5 0 0 -0.5 2 4 pH 6 8 10 y = 0.3812x - 1.7892 R = 0.9466 Y Linear (Y)

IV.

DISCUSSION This experiment has purpose to determine the influence of pH toward Dc value. The work principle of this experiment is first diluting 5 ml FAS (Ferry Ammonium Sulphate) with pH buffer until 50 ml into measuring flask. Then diluting oksin 1% in 5 ml of chloroform with using measuring flask until chloroform 25 ml. Then measure pH of mixturation FAS and its pH buffer. Mix the both solution into separating funnel then separate bottom and up layer. The up layer is water and bottom layer is organic solution. Then measure the absorbance the both layer. To measuring up layer absorbance we use Spectronic 20D and to measure bottom layer absorbance we use Spectrophotometer UV-Vis. Plot absorbance into graphic standard solution to searching of concentration. Then calculate Dc value after that make graphic log Dc Vs pH. To calculating of Dc we use the formula such as:

Dc =

From observation data that obtained if pH increases (more basic) so the absorbance will increase too. This is occurring in both solution in up and bottom layer. And the function from pH buffer is to keep pH from solution that will calculated their absorbance, in order to when given addition of base or acid solution the pH from solution always awake. Based on theory, if pH value is increase, the metal ion which can be extracted will increase too. Appropriate with kinds of ligand which will used, that is proton of ligand was ionized. So increase of ph value, ligand will be more inclined dissociate release H+ ion and form anion ligand. By increase of anion ligand in the system will be more incline form of coplex. Its appropriate with statement thet extraction a metal is influenced by ligand concentration and concentration of H3O+ as pH in water phase.

The influence ph toward ion extraction, in other side that equilibrium happen in solution is influenced by pH. In this case pH solution influence to form complex association ion to be known, in order to can reach optimum condition in measuring. From this experiment reagent oksin is produce the neutral molecule or insoluble in water, but can dissolve in chloroform. So can undergo a reaction of Fe3+ with oksin form oxalic chelate. V. CONCLUSION - The influence of pH toward Dc value is increasing of pH will making Dc value is increase too. Because if pH value is increase, the metal ion which can be extracted will increase too. So, pH increases (more basic) so the absorbance value will be increased too. BIBLIOGRAPHY Day, Underwood. 1990. Analysis Kimia Kuantitatif. Jakarta : Erlangga. Eits, James. 18987. Kimia Analitik Kuantitatif. Jakarta : Erlangga. Khopar. 1990. Konsep Dasar Kimia Analitik. Jakarta : Erlangga. Skoog, D. A. West. 1996. Fundamental of Analytical Chemistry 7th ed. Souders College. Team of Leacture. 2011. The Guide Book of Analytical Chemistry Experiment III. Surakarta : chemical Laboratory FKIP UNS.

VI.