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Hydroxylammonium sulphate
Revision date : 2010/06/24 Version: 2.1 Page: 1/7 (30042354/SDS_GEN_CA/EN)
Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA
24 Hour Emergency Response Information CANUTEC (reverse charges): (613) 996-6666 BASF HOTLINE: (800) 454-COPE (2673)
(NH(3)OH)(2)SO(4)
inorganic salts
Hydroxylammonium sulphate
2. Hazards Identification
Emergency overview IRRITANT. SENSITIZER. CORROSIVE. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Corrosive to metals
State of matter: solid Colour: white Odour: odourless Potential health effects Acute toxicity: Of moderate toxicity after short-term skin contact. Of moderate toxicity after single ingestion. There is a risk of damage to the blood (methemoglobinemia) after a single uptake of large quantities. The inhalation of a highly enriched/saturated vapor-air-mixture represents an unlikely acute hazard. Irritation / corrosion: Eye contact causes irritation. Skin contact causes irritation. Sensitization: Caused skin sensitization in animal studies. Chronic toxicity: Carcinogenicity: Indication of possible carcinogenic effect in animal tests.
Repeated dose toxicity: The substance may cause damage to the hematological system even after repeated ingestion of low doses, as shown in animal studies. Reproductive toxicity: Repeated oral uptake of the substance did not cause damage to the reproductive organs.
Teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies.
Genotoxicity: Most of the results from the numerous studies available show no evidence of a mutagenic effect. Potential environmental effects Aquatic toxicity: Very toxic (acute effect) to aquatic organisms. Depending on local conditions and existing concentrations, disturbances in the biodegradation process of activated sludge are possible.
4. First-Aid Measures
General advice: Immediately remove contaminated clothing. First aid personnel should pay attention to their own safety. If inhaled: Keep patient calm, remove to fresh air. Assist in breathing if necessary. Consult a physician. If on skin: Wash affected areas thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate medical attention required. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting. Immediate medical attention required. Note to physician Treatment:
Treat according to symptoms (decontamination, vital functions), treat with toluonium chloride to reverse methaemoglobinanaemia.
5. Fire-Fighting Measures
Flash point: Autoignition: Suitable extinguishing media: water spray Additional information: Use extinguishing measures to suit surroundings. No data available. No data available.
Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) particulate respirator. Hand protection: Chemical resistant protective gloves, Suitable materials, rubber, plastic Eye protection: Tightly fitting safety goggles (chemical goggles). Body protection: chemical protection overall (f.e. according to EN 13982) if dust is formed. General safety and hygiene measures: Avoid inhalation of dust. Wash soiled clothing immediately.
370 g/kg
Substances to avoid: Alkalines, alkalies, nitrites, oxidizing agents, nitrates, metal salts, heavy metal salts Hazardous reactions: Reacts with alkalis and nitrites. Reacts with oxidizing agents. Reacts with nitrates. Reacts with metals in powder form. Reacts with heavy metal salts. Decomposition products: Hazardous decomposition products: sulphur trioxide, Sulphur dioxide, hydroxylamine, nitrogen oxides Thermal decomposition: > 120 C Decomposition may extend over the whole product quantity. Violent decomposition, especially when heated under confinement. Corrosion to metals: Corrosive effect on metals.
Bioaccumulation Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. Other adverse effects: Very toxic (acute effect) to aquatic organisms. Do not release untreated into natural waters. Due to the pH-value of the product, neutralization is generally required before discharging sewage into treatment plants.
Land transport TDG Hazard class: Packing group: ID number: Hazard label: Proper shipping name: 8 III UN 2865 8, EHSM HYDROXYLAMINE SULPHATE
Sea transport IMDG Hazard class: Packing group: ID number: Hazard label: Marine pollutant: Proper shipping name: 8 III UN 2865 8, EHSM YES HYDROXYLAMINE SULPHATE
Air transport IATA/ICAO Hazard class: Packing group: ID number: Hazard label: Proper shipping name: 8 III UN 2865 8 HYDROXYLAMINE SULPHATE
released / listed
WHMIS classification:
D2B: Materials Causing Other Toxic Effects - Toxic material E: Corrosive material
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msds@basf.com
MSDS Prepared on: 2010/06/24 END OF DATA SHEET