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1. Principle of the sample in a sealed container and heating distillation was acidified to release one of the sulfur dioxide (7446-09-5), emissions of lead acetate solution absorption. Absorbed with concentrated hydrochloric acid and then titrated with standard solution of iodine, according to the standard solution of iodine consumed by the sample in the calculation of sulfur dioxide (7446-09-5) content. This law applies to red wine and glucose syrup, dried fruit. 2. Reagent 2.1 hydrochloric acid (1 +1): 1 times concentrated hydrochloric acid diluted with water. 2.2 lead acetate solution (20g / L): Weigh 2g lead acetate, dissolved in a small amount of iodine in water and diluted to 100mL.2.3 standard solution [c (1/2I2 = 0.01mol / L)]: the standard solution of iodine (0.1mol / L) diluted with water 10 times. 2.4 Starch indicator solution (10g / L): Weigh 1g of soluble starch, with a little water into a paste, slowly pour boiling water into the 100mL, with the added with stirring, boil 2min, let cool, spare, this solution should be temporary use when the new system. 3. All-glass distillation apparatus, iodine bottles, acid burette. 4. Analysis of Step 4.1 sample handling solid samples cut with a knife or scissors after Unqualified mixing, homogeneous samples weighed about 5.00g (sample volume level of visual content may be). Liquid samples can be directly drawn 5.0 ~ 10.0mL sample, placed in 500mL round bottom distillation flask. 4.2 Determination 4.2.1 Distillation: The weighed samples were transferred to round bottom distillation flask, add 250mL of water, fitted with condensing unit, condenser tube should be inserted in the bottom of Iodine 25mL bottle of lead acetate (20g / L) absorption solution , and then distilling flask 10mL hydrochloric acid (1 +1), and immediately stopper, heated distillation. When about 200mL distilled liquid, the liquid leaving the bottom of the condenser, then distilling 1min. With a small amount of lead acetate solution of distilled water into the device section. To do while in the test sample blank test. 4.2.2 Titration: to remove the iodine are then added to 10mL bottle of concentrated hydrochloric acid, 1mL of starch indicator solution (10g / L). After shaking the standard titration with iodine solution (0.01mol / L) titrated to the blue and does not fade in the 30s so far. 4.3 The calculation formula: X3 - samples of sulfur dioxide (7446-09-5) total content, g / kg; A2 - titration samples by standard titration with iodine solution (0.01mol / L) of the volume, mL; B - reagent blank by titration with iodine standard titration solution (0.01mol / L) of the volume, mL; m2 - sample mass, g; 0.032 - iodine standard solution with 1mL [c (1/2I2) = 1.000mol / L] considerable sulfur dioxide (7446-09-5) quality, g. This article is taken from Locke ChemNet http://www.lookchem.cn/.
Posted on 30-11-2010 17:16
titulacin de estndar de yodo (0.01mol / L) del volumen, mL; m2 prueban la masa, la g; 0.032 - solucin de estndar de yodo con 1mL [c (1/2I2) = 1.000mol / L] dixido considerable de azufre (7446-09-5) calidad, g. Este artculo es tomado de Locke ChemNet http: // www.lookchem.cn/. Enviado el 30-11-2010 17:16