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Shales by geochemical or stratigraphic measures is arguably the most common lithology encountered in sedimentary basins. Shales are chemically and mechanically unstable and are often fractured which makes suitably sized core recovery a challenge.
Shales by geochemical or stratigraphic measures is arguably the most common lithology encountered in sedimentary basins. Shales are chemically and mechanically unstable and are often fractured which makes suitably sized core recovery a challenge.
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Shales by geochemical or stratigraphic measures is arguably the most common lithology encountered in sedimentary basins. Shales are chemically and mechanically unstable and are often fractured which makes suitably sized core recovery a challenge.
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SPECIAL SECTION: S ha l e s S ha l e s SPECIAL SECTION: S h a l e s
(ODVWLFDQLVRWURS\RIVKDOHV A ccompanying the resource potential of gas shales is a new interest in understanding the physical and petrophysical properties of shales. Shale by geochemical or stratigraphic measures is arguably the most common lithology encountered in sedimentary basins. Despite this, shales remain little studied while engineers and explorationists focused on conventional reservoirs. Geophysicists did this knowing full well that often a refection coefcient from a reservoir was controlled by the shale properties of the cap rock. We compensated for this ignorance by arguing that shales are deposited in deepwater environments in which lateral and vertical changes are slow and therefore inconsequential. We further compounded this ignorance by assuming that the shales were isotropic. An example of the consequences of this ignorance was clearly documented by Margesson and Sondergeld (1999). Engineers share culpability for this ignorance too, since most of the drilling problems occur in shales and most of the lithologies drilled through to reach the target reservoirs are shales; however, shales were rarely sampled unless a problem was encountered. Shales are now universally recognized as being anisotropic. Laboratory measurements are key to defning symmetries and magnitudes of anisotropy and indicate that weak anisotropy (defned here to be less than 10% in V P and V S ) is the exception and not the rule. Measurement of elastic anisotropy typically requires knowledge of the symmetry and orientation of principal axes. Tomographic approaches with multiply redundant observa- tions allow one to simultaneously deduce the anisotropic symmetry and magnitude of the elastic constants (Dellinger, unpublished work). Te practical challenges to measuring even simple transverse isotropy are formidable. First, shales are chemically and mechanically unstable and are often frac- tured which makes suitably sized core recovery a challenge. Only the stronger, more stable shales are recovered and mea- sured. Tis is compounded by the fact that shale often arrives desiccated after protracted periods in storage. Te most common approach to shale characterization is to assume a symmetry, extract oriented plugs, and measure the phase velocities corresponding to specifc elastic constants. For transverse isotropy (TI) symmetry this requires extrac- tion of horizontal, vertical, and 45 core plugs with respect to bedding, and measurements of compressional and polarized shear velocities to provide the fve required elastic constants. Te measurement confguration is shown schematically in Figure 1. Note that there are three measures of C 44 which provide a test of the assumed symmetry. Te method outlined by Wang (2002) is similar but signifcantly reduces the infuence of sample heterogeneity. For a TI medium, Tomsen (1986) parameterized the fve elastic constants as described below:
CARL H. SONDERGELD and CHANDRA S. RAI, University of Oklahoma
o and are the compressional and shear velocities perpen- dicular to bedding. r and are the P-wave and S-wave an- isotropies, the fractional diference between the fast and slow velocities, and o is a parameter which controls the slowness or velocity surface at polar angles to the principal direction. Te three-plug method provides a redundancy in the mea- surements of C 44 which provides a test of the validity of the TI assumption. We tested the validity of the TI assumption through direct measurements on Floyd Shale samples at vari- ous azimuthal angles. Sometimes insufcient data have been presented in legacy publications to check this assumption. We report legacy data at face value. An example: Anisotropy of the Floyd Shale Te Floyd Shale is a potential but to date uneconomic gas- shale prospect in Alabama. Exploratory cores taken by Brown and Wagner provided an opportunity to measure anisotropy of the Floyd Shale. A number of these measurements have Figure 1. Tree-plug measurement schematic. P-wave phase velocities provide C 11 , C 33 and C 13 while the polarized S-wave velocities provide C 44 and C 66 . Note that the two orthogonal shear velocities measured on the vertical plug and the shear velocity polarized perpendicularly to bedding on the horizontal plug provide redundant measures of C 44
(Figure from Wang, 2002). Downloaded 06 May 2012 to 129.15.105.109. Redistribution subject to SEG license or copyright; see Terms of Use at http://segdl.org/ March 2011 The Leading Edge 325 S ha l e s S ha l e s measured phase velocities with Tomsens (solid lines) and Berrymans (dashed line) theories for phase velocity subject to assumptions of weak and strong anisotropy (Figure 5). We simply inserted the measured values for r and o in the Tomsen expression and the values of C ij in the Berryman expression to calculate the predicted phase velocities. Te two Tomsen curves result from calculating o using the C 13 val- ues obtained on the 45 and 60 plugs. Te values measured parallel and perpendicular to bedding are also plotted. Te Berryman formulation provides much better agreement with the observations than Tomsens, but expectedly so, since it does not assume weak anisotropy. been presented by Sakar et al., (2008). We extracted one- inch plugs at various azimuthal (Figure 2) and polar (Figure 4) angles from a 4-inch diameter whole core. Te plugs were machined into right circular cylinders with ends ground fat and polished. A series of plugs was also extracted in the con- ventional manner, parallel, perpendicular and 45 to bed- ding. Additional plugs were extracted at polar angles of 15 and 60 with respect to bedding and a series of horizontal plugs taken at 45 azimuthal angles were extracted (Figure 2). Te azimuthal plugs were used to evaluate the TI sym- metry. Te polar plugs provide phase velocities for the cal- culation of C 13 from these orientations. Tese velocities are used to evaluate the weak (Tomsen) and strong (Berryman, 2008) phase-velocity approximations. Both formulations allow the calculation of phase velocities at any polar angle. However, the Tomsen (Equation 16a) formulation requires the magnitude of anisotropies be small, specifcally <10%. Most shales, as we will demonstrate, violate this assumption. Figure 3 shows the observed phase velocities for the com- pressional and fast and slow shear waves in the horizontal direction as a function of azimuth. Te phase-velocity mea- surements on six extracted plugs conform to the expected symmetry of a TI material. Te circles represent constant phase velocities, not fts to the observations. Te deviations are small, typically within the experimental uncertainty. Te symmetry is consistent with our assumption of transverse isotropy. Consistent with this symmetry is the argument that phase velocity measurements made at arbitrary polar angles can be used to measure C 13 . We attempted extraction of core plugs at 15, 45, and 60 to the bedding normal. Te plug orientations are shown in Figure 4. Only the plugs at 45 and 60 survived. Successful recovery of core plugs is a sys- temic problem when working with shales. We compare the Figure 2. Plan view of plugs extracted from the 4-inch (full-diameter) Floyd Shale core. Note the plugs at azimuthal angles of 135 and 315 could not be extracted. Figure 3. Compressional and shear phase velocities (km/s) in Floyd Shale measured on core plugs extracted at the indicated azimuthal angles. Lines are simple circles representing constant phase velocities and not ft to the measurements. Deviations from the circles are in most cases less than the measurement error. Figure 4. Plug extraction at polar angles 15, 45 and 60 with respect to the bedding normal. Downloaded 06 May 2012 to 129.15.105.109. Redistribution subject to SEG license or copyright; see Terms of Use at http://segdl.org/ 326 The Leading Edge March 2011 S ha l e s Weak anisotropy Stemming from the seminal work of Tomsen in 1986, the community has been quick to embrace the concept of anisot- ropy and its embodiment as weak anisotropy. Weak anisot- ropy is understood to mean that the magnitudes of r and are less than 10%. Unfortunately, the reality is that anisot- ropy in shale is not weak but strong, not only exceeding 10% but approaching 5060%. A summary of measurements of r and are presented in Figure 6. Tere are over 150 measure- ment compiled in this plot. Te diamonds represent mea- surements made in our laboratory while the circles are values taken from the literature. We fnd a functional relationship between r and to be = ~0.054 + 1.41r while Wang found = ~0.01 + 0.96r . Tsuneyama and Mavko (2005) report the following relationship for sands and shales based on log data: = ~0.028 + 1.2r. Te intercepts are consistently near zero, where they should be, and the slopes appear to vary some- what but are close to 1. Te values of r and equal to 10% are defned by the dashed vertical and horizontal lines. Te implication of these data is that we cannot model phase velocities using the linear approximation based weak anisotropy. Causes of anisotropy Tere are multiple causes of anisotropy in shales; these in- clude alignment of clay platelets, organic matter, stresses, and fractures. Work by Hornby (1998) suggested that compac- tion resulted in increased clay particle alignment (modeled as an isotropic component) which consequently increased anisotropy. In support, he argued that density increases with compaction and therefore should be correlated with anisot- ropy in shales. Sayers (1994, 2008) considers the deformation and shape of the pore space in shales as a control on anisotro- py. Johnston and Christensen (1994, 1995) developed a rela- tion between basal plane intensities of clays in well-indurated shales determined through X-ray difraction and anisotropy the greater the strength of the basal plane intensities, the greater the measured anisotropy. Work by Vernik and Nur (1992) and Sondergeld et al. (2000) suggests that anisotropy increased with organic matter content. Increasing organic content would decrease density and hence produce an efect opposite to compaction. Te existence of interparticle mi- crocracks is unresolved since most observations are made on desiccated and poorly preserved core samples. Recent SEM work on ion-milled samples is revealing the microstructural details of shales and showing that shale systems are much more complicated than our simple intuitive conceptual mod- V P V S r o gm/cc km/s km/s Shale 2.42 3.06 1.49 0.256 0.481 0.051 Sand 2 2.95 1.48 0 0 0 Table 1. Measured properties for sand and shale used in generating Figure 7. Figure 5. Comparison of predicted and measured phase velocities in Floyd Shale. Te solid line and short dashed lines use the Tomsen phase-velocity formula for weak anisotropy while the long dashed line uses Berrymans expression for strong anisotropy. Te better agreement is clearly with the Berryman formulation. Figure 6. A compilation of measures of r and on shales. Tese data are taken from available literature values (circles) as well as measurements made recently on gas shales (diamonds). Te red dashed lines defne the boundary of values of 10%. Over 95% of the measured values exceed this value, convincingly demonstrating that weak anisotropy is the exception and not the rule. A 1:1 line is also plotted for reference as well as a least-squares ft. Te references indicated with an * provided values used in this plot. Figure 7. Te calculated Backus response for mixtures of sand and shale layers having the properties given in Table 1. A concentration of 0 represents 100% sand while a value of 1 represents 100% shale. Downloaded 06 May 2012 to 129.15.105.109. Redistribution subject to SEG license or copyright; see Terms of Use at http://segdl.org/ 328 The Leading Edge March 2011 S ha l e s els. Clay platelets are highly organized on a local level and are a complex of crystals and rather lenticular pores (Son- dergeld et al., 2010). Previous imaging capabilities produced images from fractured surfaces which show grain pull-outs and not true interparticle pores (Sayers, 2008). Tese obser- vations spurred conceptual models which do not capture the complexity of shale structures. Using Sayers theory, we fnd that values of the ratio of BN/BT from 0.2 to 0.8 cover the breadth of data plotted in Figure 6 and that a value of 0.4 fts the data best. A value of about 0.35 produces a 1:1 relation- ship between r and . Further observations reveal the organic matter to have porosities in excess of 50%. Te existence of porosity in organic matter changes the generic 2:1 conversion of weight percent TOC to volume percent. Lower organic matter densities suggest organic volumes are greater than previously thought. Te fundamental properties of clays and organics remain poorly defned and estimated values span considerable ranges (Prasad, 2002), hampering theoretical modeling of shale systems. Anisotropy is a generic characteristic of almost all crystal symmetry classes. Te organization of these minerals at some scale partially controls the apparent anisotropy of shales. In addition, simple composites of isotropic materials with welded boundaries result in overall anisotropic elastic behav- ior. Composites of anisotropic and isotropic materials with welded boundaries result in a system which can possess even stronger elastic anisotropy. Te magnitude of anisotropy is dependent in a predictable way on the volumetric concentra- tion of the constituents. Tis has implications for determin- ing the net to gross in a sand-shale sequence. Assuming the properties for sand and shale presented in Table 1, we can use a simple Backus average (Backus, 1962) to estimate what various concentrations of these components would do to the overall anisotropy. Shale anisotropy has multiple causes which complicate the interpretation of anisotropy measurements made on shales. Scale therefore is an inherent issue with anisotropy measurements. We would therefore anticipate a variation in observed anisotropy with the scale of observation, that is, anisotropy measurements on small core plugs may not sense what a logging tool does at the meter scale or what a seismic wavelength senses at tens to hundreds of meters. However, consistency among measurement scales would suggest aniso- tropic homogeneity. Above (Figure 8) is a picture of a small (1.8 0.744 1.129 mm) shale sample used for ultrasound resonance mea- surements of anisotropic elastic properties (Leisure, 2008, personal communication). Te results are compared in Table 2 to core measurements made on three 1-inch diameter by 1-inch long core plugs and measurements determined from a dipole sonic log run over the same depth interval from where the cores and resonance sample were recovered. Te values presented in Table 2 suggest the anisotropy observed in this section of the shale is homogeneous over the range of scales sampled (i.e., from mm to tens of centime- ters). Such comparisons are rare, statistically insignifcant but certainly enticing and suggestive. Pressure and efective pressure dependencies Many conventional reservoirs are overpressured and sealed c33 c44 c11 c66 c13 c12 Lab 30.4 12.5 49.9 20.2 11.8 9.6 Dipole 36 15 55 20.5 10 14 Rus-2 27.1 15.1 53.8 17.1 12.7 12.7 Table 2. Comparison of elastic constants made on shale samples and derived from a dipole log. Elastic constants are given in GPa.Note that the dipole was run in a deviated portion of the wellbore (Plona, 200, personal communication). Figure 8. A resonant ultrasound sample of Barnett Shale used to measure the anisotropic elastic constants. Downloaded 06 May 2012 to 129.15.105.109. Redistribution subject to SEG license or copyright; see Terms of Use at http://segdl.org/ March 2011 The Leading Edge 329 S ha l e s Figure 10. Computed values of P-wave, r, and S-wave, , anisotropies in Woodford (W) and Haynesville (H) gas shales as a function of confning pressure, P conf . Te pressure dependence of Woodford Shale anisotropy difers markedly from that of the Haynesville Shale. We attribute this to the microstructural diference (Sondergeld et al., 2010). Figure 11. Measured compressional-wave speeds in vertical, horizontal, and 45 gas shale plugs saturated and pressurized with nitrogen. Tese are plots of P-wave velocities at constant diferential pressure (P d = 500 psi). Te horizontal slopes suggest = 1 for the horizontal and 45 plugs. Te slope in the vertical plug is caused by the longer pore-pressure equilibration times due to the lower permeability perpendicular to bedding. Figure 9. Compressional velocities measured on horizontal, 45, and vertical plug samples from Woodford (W) and Haynesville (H) gas shales as a function of confning pressure, P conf . Te Woodford Shale displays much less pressure-dependence than the Haynesville Shale. by shales. A few gas-shale reservoirs are highly overpressured. Tus the efect of pressure and overpressure on shale behav- ior becomes of interest. If the reservoir is overpressured, the pore pressure is in excess of an equivalent hydrostat to that depth, implying there is an impermeable barrier bearing the gradient of this transition from normal to overpressure. In other lithologies, this topic has been studied extensively; Zimmerman (1991) gives an excellent treatment of the topic. Te mechanical behavior of the overpressured system obeys the efective pressure law:
where P ef is the efective pressure, P conf is the confning pres- sure, P pore is the pore pressure and is the Biot coefcient. is an empirical constant which has static and dynamic defni- tions and has been measured, depending on the property, to be both greater and less than 1. While the exact value of can be critical, for our discussion, the fundamental question is: Do velocities in shale obey the efective pressure law? If so, velocity perturbations induced by excess pore pressure can be used to detect and estimate pore pressures in shales. Hornby (1998) demonstrated that two shales appear to obey the ef- fective pressure law through direct measurements on brine- saturated North Sea shales. Hornby (1994) found that pore- pressure equilibration times are very long in these laboratory experiments. We have carried out similar measurements on a suite of gas shale samples from the Woodford and Haynesville shales. Te measured compressional velocities are presented in Figure 9 and the computed P-wave and S-wave anisotro- pies are plotted in Figure 10 as a function of confning pres- sure. In accord with the observations by Rai and Hanson (1998), fresh and well-preserved shales show little pressure dependence; we observe this velocity behavior in the Wood- ford shale (Figure 9). However, the pressure dependence of velocity in the Haynesville shale is strong; this is normally interpreted as a manifestation of desiccation cracks parallel to bedding. However, detailed scanning electron microscopy of ion-milled samples reveals the microstructure of the Haynes- ville is dominated by intrinsic slot-like micropores which impart this pressure dependence (Sondergeld et al., 2010). Predictably, this pressure dependency is also observed in the pressure dependence of the anisotropic parameters r and . Te consequence of these observations is that the Haynes- ville is more likely to display a strong pressure signature upon depletion than the Woodford, making seismic a potential management tool to monitor compartmentalization or by- passed gas. Figure 11 shows measurements of P-wave velocities on horizontal, vertical and 45 core plugs as a function of confn- ing pressure with constant diferential pressure. Diferential pressure was maintained at 500 psi. Nitrogen is the pressuriz- ing fuid. Increasing and decreasing pressure tests are shown. Downloaded 06 May 2012 to 129.15.105.109. Redistribution subject to SEG license or copyright; see Terms of Use at http://segdl.org/ 330 The Leading Edge March 2011 S ha l e s Clearly, the compressional velocities in the horizontal and 45 plugs show a simple diferential pressure-dependence. Te vertical plug appears to obey a similar behavior but the response is not exactly as fat as that for the other plugs. Te simple explanation is that, with the horizontal and 45 plugs, the fuid has access parallel to the bedding planes while the access is across the bedding planes for the vertical plug. Te pore pressure equilibration time for the vertical plug without the screening employed by Hornby (1994) is much longer. Given these limitations, these measurements suggest that the compressional velocities in shale obey the efective pressure law. Tus overpressured shales should display diagnostic ve- locity changes. Equivalently, these signatures can be used to map untapped, isolated or compartmentalized zones. Summary and conclusions Limited core measurements on shales suggest a good start- ing anisotropic model for the lithology is TI symmetry and that the magnitude of the anisotropy is large (2050%); thus, weak anisotropic assumptions should not be used in modeling shales. Berrymans formulation should be used to model phase velocities when anisotropy is strong. Tere ex- ists a strong correlation between r and and this correlation can be interpreted in terms of the ratio of normal and shear compliances between clay platelets (Sayers, 1994, 2008) but no correlation between either r or and o. Tat is to say, if you know either r or , you can predict the other with confdence. Intrinsic anisotropy and pressure-dependence of velocities in shales are often masked by inadequate preser- vation after post recovery. However, SEM studies indicate that microstructural diferences in shales are responsible for pressure dependencies of velocities and anisotropies. Pore- pressure studies suggest shales obey the efective pressure law when proper pore-pressure equilibration times are em- ployed. On geological time scales, we expect this behavior to be observed. Progress in refning our understanding of shales and shale anisotropy requires more and better controlled measurements as well as access to fresh and preserved cores. Heretofore, most authors report measurements, but not mea- surement conditions (i.e., core saturation or equilibration time between measurements). References Backus, G. E., 1962, Long-wavelength elastic ansiotropy produced by horizontal layering: Journal of Geophysical Research, 67, no. 11, 44274440, doi:10.1029/JZ067i011p04427. Berryman, J. G., 2008, Exact seismic velocities for transversely isotro- pic media and extended Tomsen formulas for stronger anisotro- pies: Geophysics, 73, no. 1, D1D10, doi:10.1190/1.2813433. Hornby, B. E., 1994, Te elastic properties of shale: Ph.D. thesis, Cambridge University. Hornby, B. E., 1998, Experimental laboratory determination of the dy- namic elastic properties of wet, drained shales: Journal of Geophys- ical Research, 103, B12, 2994529964, doi:10.1029/97JB02380. Johnston, J. E. and N. I. Christensen, 1994, Elastic constants and ve- locity surfaces of indurated ansiotropic shales: Surveys in Geophys- ics, 15, no. 5, 481494, doi:10.1007/BF00690171. Johnston, J. E. and N. I. Christensen, 1995, Seismic anisotropy of shales: Journal of Geophysical Research, 100, B4, 59916003, doi:10.1029/95JB00031. Lo, T., K. B. Coyner, and M. N. Toksz, 1986, Experimental de- termination of elastic anisotropy of Berea sandstone, Chicopee shale and Chelmsford granite: Geophysics, 51, no. 1, 164171, doi:10.1190/1.1442029. Margesson, R. W. and C. H. Sondergeld, 1999, Anisotropy and am- plitude versus ofset: a case history from the West of Shetlands, in A. J. Fleet and S. A. R. Boldy, eds., Petroleum geology of northwest Europe: Geological Society London, 635643. Prasad, M., M. Kopycinska, U. Rabe and W. Arnold, 2002, Mea- surement of Youngs modulus of clay minerals using atomic force acoustic microscopy: Geophysical Research Letters, 29, 8, 13-1- 13-4. Rai, C. S. and K. E. Hanson, 1998, Shear-wave velocity anisotropy in sedimentary rocks: A laboratory study: Geophysics, 53, no. 6, 800806, doi:10.1190/1.1442515. Sakar, M., C. S. Rai, and C. H. Sondergeld, 2008, A petrophysical study of Floyd shale: AAPG Annual Convention. Sayers, C. M., 1994, Te elastic anisotrophy of shales: Journal of Geo- physical Research, 99, B1, 767774, doi:10.1029/93JB02579. Sayers, C. M., 2008, Te efect of low aspect ratio pores on the seismic anisotropy of shales: 78th Annual International Meeting, SEG, Extended Abstracts, 2606-2611. Sondergeld, C. H., C. S. Rai, R. W. Margesson, and K. J. Whidden, 2000, Ultrasonic measurements of anisotropy on Kimmeridge shale: 70th Annual International Meeting, SEG, Expanded Ab- stracts, 18581861. Sondergeld, C. H., R. J. Ambrose, C. S. Rai, and J. Moncreif, 2010, Micro-structural studies of gas shales: SPE paper 131771. Tomsen, L., 1986, Weak elastic anisotropy: Geophysics, 51, no. 10, 19541966, doi:10.1190/1.1442051. Tsuneyama, F., and G. Mavko, 2005, Velocity anisotropy estimation for brine-saturated sandstone and shale: Te Leading Edge, 24, no. 9, 882888, doi:10.1190/1.2056371. Vernik, L. and A. Nur, 1992, Ultrasonic velocity and anisotropy of hydrocarbon source rocks: Geophysics, 57, no. 5, 727735, doi:10.1190/1.1443286. Wang, Z., 2002, Seismic anisotropy in sedimentary rocks, part 1: A single-plug laboratory method: Geophysics, 67, no. 5, 14151422, doi:10.1190/1.1512787. Zimmerman, R. W., 1991, Compressibility of sandstones: Elsevier. Data references Hornby, B. E., 1994, Te elastic properties of shale: Ph.D. thesis, Cambridge University. Hornby*, B. E., 1998, Experimental laboratory determina- tion of the dynamic elastic properties of wet, drained shales: Journal of Geophysical Research, 103, B12, 2994529964, doi:10.1029/97JB02380. Jakobsen*, M. and A. Johansen, 2000, Anisotropy approximations for mudrocks: A seismic laboratory study: Geophysics, 65, no. 6, 17111725, doi:10.1190/1.1444856. Johnston*, J. E. and N. I. Christensen, 1994, Elastic constants and velocity surfaces of indurated ansiotropic shales: Surveys in Geo- physics, 15, no. 5, 481494, doi:10.1007/BF00690171. Johnston*, J. E. and N. I. Christensen, 1995, Seismic anisotropy of shales: Journal of Geophysical Research, 100, B4, 59916003, doi:10.1029/95JB00031. Jones*, L. E. A., and H. F. Wang, 1981, Ultrasonic velocities in Cre- Downloaded 06 May 2012 to 129.15.105.109. Redistribution subject to SEG license or copyright; see Terms of Use at http://segdl.org/ March 2011 The Leading Edge 331 S ha l e s taceous shales from the Williston basin: Geophysics, 46, no. 3, 288297, doi:10.1190/1.1441199. Kaarsberg*, E. A., 1968, Elastic studies of isotropic and anisotropic rock samples: Transactions of the American Institute of Mining and Metallurgical Engineers, 241, 470475. Lo*, T., K. B. Coyner, and M. N. Toksz, 1986, Experimental de- termination of elastic anisotropy of Berea sandstone, Chicopee shale and Chelmsford granite: Geophysics, 51, no. 1, 164171, doi:10.1190/1.1442029. Melaku*, M. T., 2007, Velocity anisotropy of shales and sandstones from core samples and well logs on the Norwegian contential shelf: masters thesis, University of Oslo. Rai*, C. S. and K. E. Hanson, 1988, Shear-wave velocity anisotropy in sedimentary rocks: A laboratory study: Geophysics, 53, no. 6, 800806, doi:10.1190/1.1442515. Sakar*, M., C. S. Rai, and C. H. Sondergeld, 2008, A petrophysical study of Floyd shale: AAPG Annual Convention. Sarout*, J., Molez, Y. Gueguen, and N. Hoteit, 2006, Shale dynamic properties and anisotropy under triaxial loading: experimental and theoretical investigations: Physics and Chemistry of the Earth, 32, 896906, doi: 10.1016/j.pce.2006.01.007. Vernik*, L. and A. Nur, 1992, Ultrasonic velocity and anisotropy of hydrocarbon source rocks: Geophysics, 57, no. 5, 727735, doi:10.1190/1.1443286. Wang*, Z., 2002, Seismic anisotropy in sedimentary rocks, part 2: Laboratory data: Geophysics, 67, no. 5, 14231440, doi:10.1190/1.1512743. Acknowledgments: Tis work was supported by Brown and Wagner and Devon Energy and the members of the IC 3 Experimental Rock Physics Consortium. Te laboratory support of Gary Stowe was critical in making these measurements. We thank Colin Sayers for his critical comments and shared insight. Measurements made by J. Simmons, Gary Stowe, and Mriganko Sakar were incorporated in this study; we thank them for their contributions. Corresponding author: csondergeld@ou.edu Downloaded 06 May 2012 to 129.15.105.109. Redistribution subject to SEG license or copyright; see Terms of Use at http://segdl.org/