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JEE Mains Chemistry Model Paper 4

CHEMISTRY
81. 82. How many grams of H2SO4 are present in 0.05 litres of 0.5 M solution? (a) 4.90g (b) 9.80g (c) 2.45g (d) 3.98g How many moles of Al2O3 will be formed when a mixture of 5.4g of Al and 3.2 g of O2 is heated? 1 1 1 1 (a) (b) (c) (d) 10 15 20 5 The temperature at which K.E. of a gas molecules is half of its value at 327C is (a) 13.5C (b) 150C (c) 27C (d) 123C 2g of hydrogen diffuse out from a container is 10 min. How many gram of chlorine will diffuse out from the same container under similar conditions? 2 71 2 71 71 (b) (c) (d) (a) 71 2

83.

84.

85.

86.

87.

An aqueous solution of a solute (molar mass = 150 g mol1) boils at 373.26 K (Kb for H2O = 0.52) at 1 atm pressure. The mass % of solution is approximately (a) 7% (b) 14% (c) 5% (d) 20% If C(s) + O2(g) CO2(g); H = r and CO(g) + (b) rs

.m

A 0.002 molar solution of NaCl having degree of dissociation of 90% at 27C has osmotic pressure equal to (a) 0.94 bar (b) 9.4 bar (c) 0.094 bar (d) 9.4 104 bar

88.

ye ng

A compound formed by elements A and B form cubic structure in which A atoms are at the corners of a cube and B atoms are at the face centre. The formula of the compound is (a) AB3 (b) AB2 (c) A2B (d) AB

g. c
1 O2(g) 2
(c) r + s

of formation of CO is (a) s r Space for rough work

om

CO2(g); H = s then the heat (d) r s

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JEE Mains Chemistry Model Paper 4

89.

The heat of combustion of yellow and red phosphorus are 9.91 kJ mol1 and 8.78 kJ mol1 respectively. The heat of transition of yellow P red P is (a) 18.69 kJ (b) +1.13 kJ (c) +18.69 kJ (d) 1.13 kJ The entropy change of a phase transformation is equal to H (c) G T H (a) zero (b) T

90.

(d)

HT S

91.

By the addition of an inert gas at constant pressure to the system 2HI(g) H2(g) + I2(g), the degree of dissociation of HI will be (a) suppressed (b) not altered (c) increased (d) doubled A solution of pH = 2 is more acidic than that of pH = 6 by a factor of (a) 4 (b) 12 (c) 400

92.

93.

What will be the solubility of AgCl in a 0.10 M NaCl soln? (Ksp for AgCl = 1.2 1010) (a) 1.1 M (b) 1.2 106 M (c) 1.2 109 (d) 1.2 1010 M Given standard electrode potentials E Fe++ + 2e Fe 0.440 V Fe 0.036 V Fe+++ + 3e The standard electrode potential (E) for Fe+++ + e Fe++ is (b) +0.404 V (a) 0.476 V

94.

.m

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(c) +0.404 V (d) +0.772 V

96.

A reaction is 50% complete in 2 hrs and 75% complete is 4 hrs. The order of reaction is (a) 0 (b) 1 (c) 2 (d) 3

Space for rough work

95.

The emf of the cell H2 (1 atm) Pt/H+ (pH = ?) ||H+ (a = 1) | H2(1 atm) Pt at 25C is 0.59 V. The pH of the solution is (a) 1 (b) 4 (c) 7 (d) 10

g. c

om

(d) 10,000

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JEE Mains Chemistry Model Paper 4

97.

The protective power of lyophilic sol is (a) dependent on the size of colloidal particles (b) expressed in terms of gold number (c) expressed by x/m (d) directly proportional to the magnitude of charge on it The ionization energy of H-atom (in the ground state) is x kJ. The energy required for an electron to jump from 2nd to 3rd orbit will be (a) x/6 (b) 5x (c) 7.2x (d) 5x/36 For which one of the following set of quantum number an electron will have the highest energy? (c) 4, 1, 0, 1/2 (d) 5, 0, 0, 1/2 (a) 3, 2, 1, 1/2 (b) 4, 2, 1, 1/2

98.

99.

100. Which of the following is most soluble in water? (a) Be(OH)2 (b) Mg(OH)2 (c) Ca(OH)2 101. Which of the following species has highest electron affinity? (a) F (b) O (c) O 102. IF5 has the following hybidisation (a) sp3d2 (b) sp3d3 103. Zinc is obtained on large scale by? (a) electrolysis of ZnCl2 (c) precipitation with Ag

om

(d) Ba(OH)2 (d) Na+

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g. c
(c) sp3d (b) reduction of ZnO (d) all are correct

(d) none of these

105. Which compound will show the highest lattice energy? Space for rough work

104. The hydride ion H is a stronger base than hydroxide ion, which of the following reactions will occur if sodium hydride (NaH) is dissolved in water? (a) H(aq) + H2O(l) H3O+(aq) (b) H(aq) + H2O(l) OH(aq) + H2(g) (c) H + H2O no reaction (d) any of these depending upon temperature

.m

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JEE Mains Chemistry Model Paper 4

(a) RbF

(b) CsF

(c) NaF

(d) KF

Space for rough work

.m

ye ng

g. c

om

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JEE Mains Chemistry Model Paper 4

106. The basic character of hydrides of the 15 group elements decreases in the order (a) SbH3 > PH3 > AsH3 > NH3 (b) NH3 > SbH3 > PH3 > AsH3 (c) NH3 > PH3 > AsH3 > SbH3 (d) SbH3 > AsH3 > PH3 > NH3 107. NH4NO3 on heating gives (a) N2O (b) NO (c) N2 (d) N2O3

108. Hexafluroferrate (III) ion is an outer orbital complex. The number of unpaired electrons present in it is (a) 1 (b) 5 (c) 4 (d) unpredictable 109. Out of the following, which will not show geometrical isomerism,? (a) [Pt (NH3)2Cl2] (b) [Co(NH3)5NO2]Cl2 (c) [Co(en)2 Cl2]Cl Cr(NH3)4Cl2]Cl

g. c
(c) (b)

110. Which of the following is expected to be a paramagnetic complex? (a) [Ni(H2O)6]2+ (b) [Ni(CO)4] (c) [Zn(NH3)4]2+

om
CH 2

(d)

(d) [Co(NH3)6]3+

CH 2 CH 2

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111. The most stable carbanion among the following is

CH 2

CH 2

(a)

(b)

(d)

.m

OCH3

NO2

112. Among the species given below which has lowest value of pKb?

N H2
(a)

NH C6 H 5

Space for rough work

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JEE Mains Chemistry Model Paper 4

(c)

N H

(d)

:N H

113. Iodoethane reacts with sodium in the presence of dry ether. The main product is (a) ethane (b) propyne (c) butane (d) butene 114. Which of the following is most reactive towards electrophilic substitution? (a) C6H5NO2 (b) C6H5Cl (c) C6H5CH3 (d) C6H6

g. c
(c)

116. Which of the following will be least soluble in sodium carbonate solution? OH OH O2N NO2 COOH NO2 (a) (b)

om

115. Which of the following compounds will not give a yellow precipitate with iodine and alkali? (a) ethanal (b) acetophenone (c) 2-Butanone (d) pentan-3-ol

SO2OH

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(d)

NO2

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117. Which of the following aldehyde can given Cannizzaro reaction with base? (a) CH3CH2CH2CHO (b) H3CCH2CH2CHCHO

CH
(d) (CH3)3CCHO
3

118. Ethyl acetate reacts with CH3MgBr to form (a) secondary alcohol (c) primary alcohol and acid Space for rough work

(c) (H3C)2CHCH2CHO

(b) tertiary alcohol (d) carboxylic acid

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JEE Mains Chemistry Model Paper 4

119.

HNO 2

Y (Major)

HO

CH2NH2
O

(a)

(b)

(c)

(d)

120.

Space for rough work

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g. c

Dglucopyranose and Dglucopyranose are (a) anomers (b) epimers (c) enantiomers

om

HO

CH2OH

HO

CH3

(d) tautomers