0 оценок0% нашли этот документ полезным (0 голосов)
49 просмотров6 страниц
This paper describes the use of surface characterisation techniques, such as surface mass spectrometry and 3D topography, to analyse materials used in the aerospace industry in order to reduce its environmental impact. Examples of various techniques used to establish the properties of coatings and substrates are given, and the minimisation of surface contamination in jet engines is described. Courtesy of Dr Chris Pickles, Lucideon.
Оригинальное название
How Surface Characterisation is Helping the Aerospace Industry
This paper describes the use of surface characterisation techniques, such as surface mass spectrometry and 3D topography, to analyse materials used in the aerospace industry in order to reduce its environmental impact. Examples of various techniques used to establish the properties of coatings and substrates are given, and the minimisation of surface contamination in jet engines is described. Courtesy of Dr Chris Pickles, Lucideon.
Авторское право:
Attribution Non-Commercial ShareAlike (BY-NC-SA)
Доступные форматы
Скачайте в формате PDF, TXT или читайте онлайн в Scribd
This paper describes the use of surface characterisation techniques, such as surface mass spectrometry and 3D topography, to analyse materials used in the aerospace industry in order to reduce its environmental impact. Examples of various techniques used to establish the properties of coatings and substrates are given, and the minimisation of surface contamination in jet engines is described. Courtesy of Dr Chris Pickles, Lucideon.
Авторское право:
Attribution Non-Commercial ShareAlike (BY-NC-SA)
Доступные форматы
Скачайте в формате PDF, TXT или читайте онлайн в Scribd
HELPING THE AEROSPACE INDUSTRY TO ACHIEVE ENVIRONMENTAL TARGETS Dr Chris Pickles
This work by Lucideon is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
by Lucideon 2 INTRODUCTION The green agenda continues to dominate aerospace developments both from the regulatory perspective and from economic operating imperatives. The REACH directive and other regulatory pressures are targeting chromium removal by 2017 whilst fuel burn reduction is the main driver behind the use of composites as a means of light-weighting aircraft structures and components. In both these areas new material developments continue to hold the key to the successful achievement of the green objectives whilst maintaining, or improving, the other essential product performance requirements. Underpinning many areas of these technological advances is a need to understand surface and interface functionality from both a chemical and physical standpoint. In this paper we give examples of where surface characterisation techniques are continuing to make a major contribution to these endeavours to reduce the environmental impact of the aerospace industry in the future. THE BACKGROUND The picture is changing continuously but a reasonable estimate of the current use of carbon fibre in aerospace applications is in the region of 30000 tonnes per annum. According to informed sources this will rise to 170000 tepa by 2020. Fuel represents over half of total airline operating costs and a 30% weight loss would deliver a 6% fuel cost saving. The 787 Dreamliner is 50% composite, 20% aluminium, 15% titanium, 10% steel and 5% other materials. Maintenance costs are also reduced significantly by the use of composite structures - estimated to be 30% lower for the 787. Developments continue apace with thermoset resins coming under the influence of the REACH directive in terms of the need to phase out the curing agent MDA. Beyond this the attraction of thermoplastic resins in terms of their recyclability and the lower drag available from thinner wings are just two of the future developments that will maintain the inexorable demand for surface characterisation as an essential component of composite materials development programmes. Chromium is a known carcinogen and its use is limited by the COSHH regulations in the UK. The replacement of chromium compounds in anticorrosion coatings is a live topic in the aerospace and other industries. The complex chemistry involved in reformulating anti- corrosion coatings depends critically on the developers ability to understand the interfacial phenomena occurring between the various formulation ingredients, between the coating ingredients and the substrate layer(s) and between the coating ingredients and the corrosion challenge. All of these issues can be informed by surface characterisation techniques which are able to deliver understanding in terms of both the chemistry and the physical form of coating systems. SURFACE CHARACTERISATION OF COMPOSITE MATERIALS Composite materials depend critically for their operational performance on the strength of the bond between the fibre and the matrix polymer. Any disruption to this interface will affect the adhesion and can lead to resin-fibre disbondment. Similarly, coating adhesion to composite structures is dependent on both the physical and chemical nature of the substrate and of the coating. Whilst the substrate surface roughness has an optimum value related to the keying of the coating, the coating outer surface needs to be as smooth as possible to reduce drag. The machining of composites is also an area of potential concern in terms of fibre break-out and edge finish whether the structure is machined In all of these areas surface characterisation techniques are able to deliver quantitative and highly spatially resolved chemical and physical information. Typical examples include the analysis of a multilayer printed circuit board in which the glass fibre filled epoxy pre-preg layer was delaminating. Chemical analysis using surface mass spectrometry of both the fibre surfaces and the resin residues, when compared with conforming material, showed that insufficient adhesion promoter had been used in the pretreatment of the glass fibres prior to curing. or water jet cut.
by Lucideon 3
Electron Micrograph of glass fibre composite cross section
Chemical profiling of a multi-layer coating These post-mortem costs are significantly higher than the costs that would have been incurred when establishing material properties prior to installation. In another example a multilayer acrylic/metal laminate had suffered a different form of delamination due to compound formation at the interface. This condition was characterised by both quantitative 3D surface profiling giving nanometre resolved topographical images of the surface discontinuity together with quantitative, elemental surface spectroscopy to identify the chemical species present. The surface characterisation of both carbon fibre and glass fibre pre-pregs is an important application of all three analytical techniques whereby fibre surfaces can be diagnosed for both inorganic and organic residues as well as for chemical modification and surface pitting. Gel coats can similarly be measured for surface smoothness and/or imperfection with quantitative statistical data allied to nanometre resolved 3D images. Surface chemical characterisation has also been applied successfully to the analysis of release papers to investigate potential material transfer and, in an exercise to study the surface profiles of a series of treated release papers; valuable data on the variation in surface smoothness and treatment distribution was measured. SURFACE CHARACTERISATION OF COATINGS AND SUBSTRATE CONDITION The performance of chromium compounds as anticorrosion ingredients in coatings formulations is well known. There have also been a number of investigations into alternative systems. In all of these it is clear that the precise chemical and microstructural make-up of the coating is of crucial importance in order to optimise the galvanic mechanism by which corrosion protection is achieved. Surface characterisation techniques, such as surface mass spectrometry and surface elemental spectroscopy, have been widely used to study the chemical nature of both the substrates and coating formulations in order to optimise coating performance in terms of corrosion prevention. Quantitative 3D surface topographical profiling has also been applied to the specification and control of substrate surface roughness. For current chromium containing coatings the curing conditions are critical to the development of the active species both in terms of anti- corrosion performance and strength of bonding to the substrate. In particular, the oxidation state of the chromium is important in terms of its galvanic activity.
by Lucideon 4
3D topographical profile Substrates are often pre-treated prior to coating by a variety of processes most of which are either promoting surface oxidation (or nitriding) by chemical or thermal means. The characterisation of these treated surfaces is commonly achieved by surface mass spectrometry and/or by depth profiling mass spectrometry and also by surface elemental spectroscopy and/or depth profiling elemental spectroscopy which latter technique is, importantly, quantitative. In a typical example an anodised metal component was characterised by mass spectrometric depth profiling to establish the penetration of the treatment and by 3D surface topography to measure the effect on substrate surface roughness quantitatively. In another example the effect of part marking on the surface condition and potential susceptibility to subsequent performance was characterised by quantitative surface elemental spectroscopy and quantitative surface topographical imaging. It has already been mentioned that the oxidation state of chromium in anti-corrosion coatings is functionally important. Quantitative surface elemental spectroscopy operating in high resolution mode is able to distinguish between the two oxidation states of chromium with high precision and this analysis is routinely used in the characterisation of such coatings. Moreover, similar capability exists for all metallic elements to which it could otherwise apply and this will be important in supporting the development of non- chromium containing alternative anti-corrosion coatings. The adhesion of coatings, including replacement, non-chromium anti-corrosion coatings, is paramount in delivering in-service performance. The causes of delamination or the adhesive failure of coatings is susceptible to investigation by surface characterisation techniques. In a typical example, a two layer coating was exhibiting adhesive failure. Surface molecular mass spectrometry, together with quantitative surface elemental spectroscopy investigations of the substrate and coating layers, showed that ingredient segregation from one of the layers was affecting the inter-layer bond strength.
Jet engine Eurofighter Jet Engine by Tony Hisgett is licensed under a Creative Commons Attribution 3.0 Unported License.
The most common cause of adhesive failure however is the occurrence of extraneous surface contamination - often of silicone based materials. This can be as relevant to coated composites as it is to coated metals and alloys. Aerospace manufacturers routinely operate multi-stage cleaning procedures to ensure substrates are adequately cleaned prior to being presented to the coating process. The quality of cleaning is commonly monitored by a rinse/filter/particle count procedure with various limit values. Crucially however this procedure does not reveal what potential contamination may still be remaining on the cleaned component. Surface characterisation can measure part cleanliness directly and quantitatively. Cleaning processes can be routinely monitored using prequalified coupons which are passed through the process with the components. These can then be analysed by surface elemental spectroscopy and, by the use of a bespoke chemical combinatorial algorithm, a % cleanliness measure can be generated. This capability allows for both an unequivocal cleanliness specification to be set and an ongoing quality control procedure to be implemented which relate directly to the cleanliness of the substrate surface to be coated.
by Lucideon 5
CONCLUSION The aerospace industry is committed to developing and adopting technologies which reduce its environmental impact in both the short and long term. In particular the use of composite materials for lightweighting to reduce fuel burn and the replacement of chromium in anti-corrosion coatings are just two areas where this policy is already being implemented. In this paper we have considered how techniques for both the chemical and topographical characterisation of surfaces and interfaces can be applied to ensure that both these developments benefit significantly therefrom.
by Lucideon
ABOUT LUCIDEON
Lucideon is a leading international provider of materials development, testing and assurance. Through its offices and laboratories in the UK, US and the Far East, Lucideon provides materials and assurance expertise to clients in a wide range of sectors, including healthcare, construction, ceramics and power engineering. The company aims to improve the competitive advantage and profitability of its clients by providing them with the expertise, accurate results and objective, innovative thinking that they need to optimise their materials, products, processes, systems and businesses.
ABOUT THE AUTHOR
DR CHRIS PICKLES - CONSULTANT TO LUCIDEON EXPERTISE IN: AUTOMOTIVE; POLYMERS; SURFACES & COATINGS Chris holds a Degree in Chemistry, a PhD in Polymer Science, and a Postdoctoral Fellowship. AEROSPACE Chris has been supplying surface analysis capabilities to the aerospace industry for over three years with particular emphasis on carbon reduction programmes involving composite developments, coating analysis and lubricant developments in relation to the introduction of biofuels. AUTOMOTIVE Chris has worked in both the aftercare sector as a Company Technical Manager and in tier one supply chain manufacturing as Managing Director. Chris has been responsible for the plastic injection moulding and blow moulding manufacture of automotive component systems including highly technical mouldings such as fuel tanks and 3D spoilers. In addition Chris has also managed an integral supply chain utilising Toyota production system protocols. POLYMERS During his career, Chris has spent four years researching copolymer design for bulk property manipulation and the statistical mechanics of PVC to determine conformational sequencing. Chris's knowledge also encompasses plastics manufacturing, including injection moulding of glass-filled nylon and co-extrusion blow moulding of complex 3D components. SURFACES AND COATINGS In the field of surface science, Chris has conducted research projects on alternative material sources for surfactants and detergent product re-formulation. These include the re- launch of a branded fabric washing product in Brazil and the design of a surfactant system utilising renewable resources. As Technical Manager in the automotive aftercare industry he has managed the development and quality control of spray paints for high speed aerosol filling.