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As we know that it is not possible for any half-cell to work independently and it is
not possible to determine the absolute electrode potential of an electrode. We
can only find the relative electrode potential.
But this can be made possible by selecting one of the electrodes as a reference
electrode and fixing its potential as zero. For this, reversible hydrogen electrode
has been universally accepted as a reference electrode. It is standard hydrogen
electrode (S.H.E.).
It consists of platinum wire sealed in a glass tube and has a platinum foil
attached to it. The foil is coated with finely divided platinum and acts as platinum
electrode. This electrode is dipped in an acidic solution containing H+ ion in 1M
concentrations. Hydrogen gas at 1atmosphere pressure is bubbled into the
solution at constant temperature.
Standard hydrogen electrode:
The surface of the foil acts as a site for the reaction.Since this electrode behaves
as both cathode as well as anode, so both oxidation and reduction reactions are
occurring at a single electrode. The reactions occurring at the electrode are:
Explanation:
Thus if the voltmeter gives the proper reading it indicates that the electrode
connected to the positive terminal of the voltmeter acts as cathode and the
electrode connected to the negative terminal of the voltmeter acts as anode and
electrons flow from anode to cathode.
In the given cell electrons flow from zinc electrode to hydrogen electrode.
Therefore the zinc electrode acts as anode and S.H.E. acts as cathode.