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Effluent
Sludge Treatment
What goes here depends on the method of final disposal: Solids concentration Pathogen reduction
Processed sludge
Sludge treatment and disposal may account for up to 80% of the total wastewater treatment cost.
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Sludge Disposal
Land application Landfill Incineration
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Preliminary
Primary Treatment
2 Treatment
Disinfection
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Sludge A mixture of organic and inorganic solids in water Color : from brown to black Treated sludge Incineration, landfilling Contain low levels of toxic compounds
Typical Sludge Concentration Source Primary sludge, without thickening Waste activated sludge Waste trickling filter sludge Digested sludge
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Dewatered sludge
Sludge Types
Primary sludge
3 to 8% solids About 70% organic material
Secondary sludge
Consists of wasted microorganisms and inert materials About 90% organic material WAS: 0.5 to 2% solids Trickling filter sludge: 2-5% solids
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Sludge Types
Tertiary sludge
If secondary clarifier is used to remove phosphate, this sludge will also contain chemical precipitates (more difficult to treat) Denitrification sludges - similar to WAS sludge
Sources of sludge Primary sedimentation tank Aeration basin or secondary clarifier Screening and grinder Filter backwash water
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Sludge Treatment
Reduction Ash
Sludge
Thicken
Condition
Dewater
Sanitary Landfill
Stabilize
Condition
Dewater
Soil Incorporation
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Sludge Thickening
Reducing the water in primary and secondary sludges. Methods Gravity thickening : using an additional clarifier to remove more water Dissolved air flotation (DAF) Used to concentrate secondary sludges Sludge is pressurized and injected with air releasing into a settling tank (when the pressure is released, the extra air comes our of solution, attaching to the sludge particles as microscopic bubbles) the sludge is floated to the surface in a concentrated form the underflow returns to the head of the plant.
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Gravity Thickener
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Flotation
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Thickening
Gravity thickening Flotation
Especially effective on activated sludge Increases solids content from 0.5 - 1% to 3-6%
Primary Sludge Secondary Sludge
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Best with primary sludge Increases solids content from 1-3% to 10%
Gravity Thickening
Accomplished in circular sedimentation basins Degree of thickening: 2~5 times the incoming solids conc. Max. achievable solids concentration: < 10% Chemical and waste activated sludges are difficult to thicken under gravity.
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Gravity thickener side water depth: 3 m (10 ft) Detention period: 24 hrs Hydraulic loading rate: 10~30 m3/m2d = 250~740 gpd/ft2 To achieve the hydraulic loading rate, secondary effluent is often blended with the sludge fed into the thickener. The sludge-blending tank may utilize mechanical mixing or air mixing. 11 11/30/2008
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Gravity Thickener
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Advantages of DAF
Space requirements are minimal. Capability to treat a wide variety of organic and inorganic solids and dissolved waste streams. Low retention time from wastewater stream to effluent ejection. Superior clarification of most waste streams. Easy to clean and maintain. Higher density sludge with low water content. Installation cost is low for low flows. The unit is typically delivered fully prefabricated. Normal concrete pad installation.
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Design Parameters
Hydraulic Loading: Effective design ranges from 1.0 to 2.5 gpm/ft2, depending upon the application. Solids Load: Design points for solid loadings range from 0.5 to 3.5 lbs/hr/ft2, depending on the application and the type of solids involved. It should be noted that any chemical additives used to promote coagulation and flocculation are generally included as solids determining the surface loading since the chemicals used are removed with the float from the system. Air-to-Solid Ratio: Generally, air is injected in a range of two percent to eight percent (2% to 8%) by volume. Depending upon the type of solids and application, the airto-solids ratio ranges from 0.020 to 0.1.
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Type of sludge
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Sludge Stabilization
Aerobic Digestion
Extension of activated sludge Accomplished by aeration of sludge then followed by sedimentation Supernatant goes back to head of plant (high in BOD, TKN, total-P) Treated sludge is 3% solids
Anaerobic Digestion
2 stage: acid fermentation followed by methane production Advantages: produce methane do not add oxygen As with aerobic digestion, supernatant goes to headworks
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Sludge Stabilization
Stabilization alters the characteristics of sludge so it can be returned to the environment with a minimum of environmental and health risks. Biological Treatment 1. Aerobic Digestion 2. Anaerobic digestion 3. Lagoons 4. Composting Chemical Treatment 1. Wet combustion 2. Lime stabilization 3. Chlorination 4. Heat stabilization 5. Irradiation
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Stabilization
Aerobic Digestion
Extension of activated sludge Accomplished by aeration of sludge then followed by sedimentation Supernatant goes back to head of plant (high in BOD, TKN, total-P) Treated sludge is 3% solids
Anaerobic Digestion
2 stage: acid fermentation followed by methane production Advantages: produce methane do not add oxygen As with aerobic digestion, supernatant goes to headworks
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Stabilization
Aerobic Digestion
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Anaerobic Digestion
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Aerobic Digestion
Primary sedimentation tank Aeration basin RAS Aerobic digester Decant Sludge Secondary clarifier
Aerate until O2 uptake < 2 mg O2/g VS/hr Sludge age = 10~20 days at 20C Loading = 0.02~0.15 lb VS/ft3day Thermophilic aerobic digestion: 77~122F (25~50C); higher removal of biodegradable fraction (up to 80%) at very short detention times (3~4 days)
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Anaerobic Digestion
1. Fermentative organisms (50% of viable organisms in anaerobic digester) Cellulose Acetate, alcohols, Strepto cocci Lipids other organic acids, Enterobacteria Proteins H2, CO2, NH3, HSChlostridia 2. Acetogenic bacteria (acid formers) Simple organics (except acetate) (fatty acids, sol. organics) Acetate 3. Methanogenic bacteria (methane formers) Get energy from forming CH4 Need low redox potential O2 toxic Need temp.
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Anaerobic Digestion
Anaerobic digestion of sludge decrease the volatile organics by 40-50% and reduce the numbers of pathogenic organisms in sludges. Accomplished by holding the sludge in closed tanks for periods of 10 to 90 days. Old process : unmixed, unheated, long detention time (30-90 days) Recent process : complete mixing, heating (3545), detention time 10-20 days
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Digester gas Gas storage Gas storage Scum Heater mixer Supernatant
Settled, Digested sludge
Digester gas
Digestion
Separation
Advantages
High degree of waste stabilization at high organic loading rates Very little sludge production (< 5% of biodegradable organic matter being converted to cell material) (10% of aerobic sludge production) Easy dewatering of the excess sludge Low nutrient requirement (10% of aerobic process requirement) No aeration equipment Methane production very low energy input (if the methane gas is used to heat the digester)
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Disadvantages
Low bacterial yield
prolonged periods of biomass build-up, requiring longer start-up period (8 to 12 weeks).
Temperature, pH, toxic sensitive Inherent process instability High capital costs Complex operation requiring skilled operators
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Acetogenic phase 2%
Methanogenic phase
Methanogenic phase
Rate limiting steps Conversion of propionic and acetic acid to CH4 Hydrolysis of organic solids (cellulose)
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Recycle increases biomass levels and sludge age, thereby separating sludge age from HRT. Difficult to obtain efficient settling of the biomass. A degasifier is required to aid in solids settling.
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Mixing Device
Gas injection
Unconfined: collect gas at the top of the digesters, compress the gas, and then discharge the gas through a pattern of bottom diffusers or through a series of radially placed top-mounted lances... Confined: collect gas at the top of the digesters, compress gas and then discharge through confined tubes...
Mechanical stirring: low speed turbine or mixers, suitable for fixed or floating covers Mechanical pumping: propeller-type pumps mounted in internal or external draft tubes or axial flow or centrifugal pumps and piping installed externally, suitable for fixed covers
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Mixer Types
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Digester Heating
To raise the incoming sludge to digestion tank temperatures, to compensate for the heat losses through the walls, floor, and roof of the digester, and to make up the losses that might occur in the piping between the source of the heat and the tank. Internal or external heat exchangers Heat requirements q = U A T where q = heat loss, BTU/h (W); U = overall coefficient of heat transfer, BTU/ft2hrF (W/m2C); A = cross-sectional area through which the heat loss is occurring, ft2 (m2); and T = temperature drop across the surface in question, F 11/30/2008 38 (C).
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Sludge Conditioning
Chemical Conditioning
Add lime, ferric chloride, or alum Can also add polymers Chemicals are added just prior to de-watering stage
Heat Treatment
High temperatures (175230 oC) High pressures (10 to 20 atmospheres) Advantages
bound water is released and sludge is easily dewatered
Disadvantages
complex process highly concentrated liquid stream
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Heat Treatment
Heating sludge under pressure to temperatures in the range of 200-300 for a few minutes can effectively sterilize it and convert it to a form that is easily dewatered. Disadvantages Its high energy requirement The production of a high-strength return liquid form the dewatering process Heat treatment is used only in a few large POTWs
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Filtration
Apply vacuum to pull out water Force out water by essentially squeezing water between two moving filter belts
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De-watering
Vacuum Filtration
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Filter Press
Dewatering is accomplished by pumping sludge into chamber (A) surrounded by filter cloths (B). As pumping pressure is increased, the filtrate is forced through the accumulated filter cake (C) and cloth, leaving the chambers full of solid filter cake. The chambers in HEI presses are formed by two recessed plates held together under hydraulic pressure. The hydraulic ram (D) moves the follower (E) against the stack of filter plates (F) closing the press. The ram continues to apply pressure of sufficient force to counteract the high internal compaction pressures. The head stock (G) and tail stock (H) are held in place by specially engineered side rail supports bars (I). The filtrate passes through the filter cloth and is directed by channels in the plates and drain ports (J) to the head stock for discharge. The filtrate typically contains less than 15 ppm suspended solids. The filter cake is easily removed by simply reversing the hydraulic ram, thus opening the press. The lightweight plates may then be moved apart permitting the compacted cake to fall from the 11/30/2008 44 chamber.
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Centrifuges
Centrifugation is the process of separating solids from liquids by the use of centrifugal force. The centrifuge is a cylindrical drum that rotates to develop the separating force. When the slurry enters the interior of a rotating centrifuge, it is thrown out against the bowl wall. The denser materials are separated first, and hug the interior wall of the rotating machine.
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Centrifuges - continued
A helical screw conveyor fits inside the bowl. Rotating at a slightly lower rate that the bowl, it conveys solids from the zone of settling to the dewatering beach, where it is discharged to screw conveyors located below. The main bowl is turned by an electric motor while the screw conveyor inside is controlled or slowed down using a hydraulic backdrive. Prior to entering the centrifuge, sludge would have been conditioned with polymer. Larger and heavier particles are most easily captured by the centrifuge. Fine particles that cannot be settled separately must be agglomerated by chemicals (polymer) to a size that will settle.
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Incineration Other methods Care must be taken in applying sludge to land, so that excessive concentrations of heavy metals or other toxic materials do not accumulate in the soil Incineration : lager municipalities Maximum volume reducing, detoxification, and energy recovery Capital and operating costs are high There are environmental effects (air discharges, scrubber sludge generation), operation problems, and the continuing need for trained operating personnel.
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+ Biosolids =
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