Material Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION & COMPANY Material Name K- Othrine Flow Manufacturer Name Bayer Cropscience India Limited Manufacturer Address 6301a-10, Gidc , Ankleshwar 393 002 gujarat Alternate address: Bayer (India) Limited, Kolshet Road,Thane (Maharashtra) Pin Code 400 607 Phone Number 02646-21113 Fax Number 02646-50138 Emergency Number 02646)21113/20812 Emergency No In India 02646)21113/20812 2.COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Compounds in CAS No Classification Conc. % w/w Product Deltamethrin 52918-63-5 2.50% Chemical Family Pyrethroids Chemical Formula Not Available Molecular Weight Not Available Kind Of Use Insecticide 3. HAZARDS IDENTIFICATION Toxic By Inhalation & If Swallowed. Some Cutaneous Sensation Main Hazards May Occur Such As Burning, Stinging Sensation On The Face And Mucous Membrane Hazard Symbol/s Toxic 4. FIRST- AID MEASURES Rinse Immediately With Clean Water For At Least 15 Minutes Eyes And Obtain Medical Aid. Remove Contaminated Clothing Immediately. Skin Wash Affected Area Immediately With Soap And Water. Remove The Casualty Into Fresh Air And Keep Him Calm. Inhalation Summon A Doctor Immediately Wash Out Mouth With Water. Induce Vomiting : 1. If Medical Treatment Is Not Readily Ingestion Available. 2. If Patient Is Fully Conscious. 3. If Time Since Ingestion Less 1 Hour.

 Seek Medical Advise Immediately. Symptomatic Treatment After Decontamination. Local Contamination : Skin : Apply Vitamin E Cream Or Simple Toilet Milks. Eye : Instillation Of Local Anaesthetic Drops E.g. 1% Amethocaine Hydrochloride Eye Drops. Give Analgesics As Necessary. Systemic Poisoning : Monitor Function : Respiratory, Cardiac. Observe Specific Parameters : Electrocardiograph, Check Advice To Physicians For Pulmonary Oedema In Event Inhalation. Gastric Lavage, Charcoal Administration. Endotracheal Incubation. Artification Respiration As Necessary. Elimination By : Dialysis, Haemo - Perfusion. Anticonvulsions Therapy : Diazepam I.v. Contraindications : 1. Adrenergic Compounds. 2. Atropine. Recovery : Spontaneous. Must Not Be Confused With Organophosphorus Compounds 5. FIRE - FIGHTING MEASURES Extinguishing Media Water Jet. Dry Ice. Unsuitable Do Not Use Jet Of Water From A Fire Hose, Extinguishing Media Special Exposure In Case Of Fire The Product Emits Toxic And Irritating Hazards Fumes. Protective Equipment Wear A Self-contained Breathing Apparatus. Wear Protective For Fire Fighting Clothing. Use Water Spray To Cool Containers Exposed To Fire. keep Away From Heat And Flame If Possible. avoid Rejection Of Fire Fighting Guidance Extinguishing Water Into Drainage System, Suface Or ground Water. do Not Breathe Fumes. 6. ACCIDENTAL RELEASE MEASURES Before Intervention Wear Protective Equipment. Avoid Contact Personel Precautions With Chemical Or Contaminated Surfaces. Sweep Into A Suitable Container, Avoiding The Formation Of Environmental Dust Cloud Precautions and Store The Material Collected. prevent Entry Into Drains, Sewers And Watercourses. Wear All Ppe. Sweep And Shovel The Product In An Air-tight Bag For Eventual Disposal. rinse The Contaminated Area With Spillages A Large Quantity Of Water And Cleaning Agent. *store The Washing Waters Into A Suitable Container.

Note Not Available 7. HANDLING AND STORAGE Handling Handle In A Closed System. Wear All Ppe. Keep In Original Containers, Tightly Closed At Ambient Temperatures.keep Protected From Moisture.keep Protected Storage From Direct Sunlight.keep At Ambient Temperature.keep Away From Food, Drink And Animal Feedingstuffs.keep Container Tightly Closed And In A Well-ventilated Place. Technical Storage Use Local Exhaust Ventilation As Close As Possible To Dust. Measures provide An Ocular Shower And Sanitary Installations Near The Place Of work. keep Only In The Original Container. do Not Re-use Empty Containers. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards Engineering Control Mechanical Sucking Ventilation At Sources Of Formation Of Standards Dust.provide An Ocular Shower And Sanitary Installations Near The Place Of Work. Respiratory Protection Use Dust Mask Hand Protection Use Rubber Gloves Eye Protection Use Safety Goggles Others Use Safety Shoes And Protective Clothing Other Information Eye Wash & Safety Shower 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid Ph 04-Jun Boiling Range/Point 100 (deg.C) Melting Point/Freezing Not Available point (deg.C) Flash Point (deg.C) Not Concerned Explosion Limits (%) Not Concerned Solubility in Water Partly Soluble Vapour Pressure Not Available Density (g/ml) 1.01-1.04 Flammability Not Easily Flammable Auto-flammability Not Available (deg. C) Explosive properties Not Available Oxidising Properties Reacts With Strong Oxidisers Vapour Density (air=1) Not Available Dust Explosion Data St1 No Decomposition Under Normal Conditions . Carbon Oxides And Summary / Other Data Nitrogen Oxides May Be Formed As Thermal Decomposition Of Product. Keep Away From Heat And Source Of Ignition.

10. STABILITY AND REACTIVITY Stability Stable Under Normal Temperature And Pressure On Combustion Produces Carbon Oxides & Nitrogen Oxides (thermal Decomposition) When Heated It Emits Toxic Fumes Of Conditions to Avoid. Br, Cn, & No2, Hence Keep Away From Source Of Ignition And Heat. Materials to Avoid Not Available 11. TOXICOLOGICAL INFORMATION LD 50 66.7 Mg/kg (oral Rat) LC 50 Inhalation/rat(4 Hours)=2.2 Mg/lt Carcinogenicity Not Carcinogenic Genotoxity Not Teratogenic And Mutagenic. Reproductive Toxicity Not Teratogenic Some Cutaneous Sensations Occur, Such As Burning, Stinging Other Information Sensations On The Face And Mucosa, Without Lesions And Transient Some Hours, Maximum 24 H. 12. ECOLOGICAL INFORMATION Mobility Fixed In Most Soils. Persistence / Not Available Degradability Bio-Accumulation Not Known Aquatic Toxicity Aqua Toxic. Other Toxicity Not Available 13. DISPOSAL CONSIDERATIONS Incineration In Accordance With The Local Waste Regulation Authority. do Not Discharge Washing Waters In Public Sewers And Water Sources (ponds, Streams...) Make The Container Unusable. Container Disposal disposal Must Be Traited According To Official Regulation. 14. TRANSPORT INFORMATION Transport information Pyrethroid Pesticide Solid, Toxic. (deltamethrin) Note U.N. Number 3349 U.n. Class 6.1 ADR/RID-Description Pyrethroid Pesticide Solid, Toxic. (deltamethrin) 15. REGULATORY INFORMATION Hazard Classification F - Highly flammable NO Xn - Harmful YES T - Toxic YES N - Dangerous For Environment YES R phrases Harmful By Inhalation. toxic If Swallowed. very Toxic To Aquatic Organisms, May Cause Long-term Adverse Effects In The aquatic Environment. Product Disposal

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After Contact With Skin, Wash Immediatly With Plenty Of Water And Soap. wear Suitable Protective Clothing, Gloves And Eyes/face Protection. in Case Of Insufficient Ventilation, Wear Suitable Respiratory Equipment. in Case Of Accident Or If You Feel Unwell, Seek Medical Advice Immediatly (show The Label Where Possible).

this Material And Its Container Must Be Disposed Of As Hazardous Waste. avoid Release To The Environment. Refer To Special Instructions/safety Data sheets. 16. OTHER INFORMATION MSDS first Issued 25/07/2000 MSDS data revised 18/02/2002 M.S.D.S. Version 1 Revisions Highlights The Existing Msds Has Been Modified According To Global Requirements. The Informations Are Made Available In 16 Sections Instead Of 8. This information is based on the present state of ourknowledge Note and is intended to describe safety requirements.It should therefore be not taken as guaranteed properties. Annexure I ACTIVE INGREDIENT: PYRETHROIDS (INCLUDING DELTAMETHRIN) FIRST AID MEASURES 1. Standard *Yes No *See below If No: State Specific Measure: ............................................................. State Rationale: .................................................................................... 2. Induction of Vomiting Yes No If Yes: State Circumstances where recommended:1. Medical treatment not readily available. 2. Patient is fully conscious. 3. Time since ingestion less than 1 hour. State Rationale: Toxicity - c.130 mg/Kg. MEDICAL ADVICE 1. BRIEF SUMMARY OF SYMPTOMS AND SIGNS: Local: Skin and eye paraesthesiae which may be severe. Usually transient with resolution within 24 hours. Systemic: Dizziness, headache, listlessness, nausea and vomiting, epigastric pain, muscular fasciculation of limbs,

unconsciousness, convulsions and coma (very high doses). 2. TREATMENT: LOCAL CONTAMINATION Standard Yes No If No: State Specific Measure: Skin: Apply Vitamin E cream or simple toilet milks. Eye: Instillation of local anaesthetic drops e.g. 1% Amethocaine Hydrochloride eye drops. Give Analgesics as necessary. State Rationale: Can cause severe pain. SYSTEMIC POISONING: Standard Yes No If No: State Specific Measures listed below: (i) Monitor Function: Respiratory Cardiac Kidney Other (ii) Observe Specific Parameters: 1. Electrocardiograph 2. Check for pulmonary oedema in event of inhalation. (iii) Gastric Lavage Charcoal administration ........................................................................................ ................. (iv) Endotracheal Intubation *Artificial Respiration *As necessary (v) Elimination by: Dialysis Haemo-perfusion (vi) Anticonvulsant Therapy Yes No If Yes, specify: Diazepam i.v. (vii) Antidote Yes No If Yes, Specify: (viii) Contraindications Yes No If Yes, specify: 1. Adrenergic compounds. 2. Atropine. (ix) Recovery: Spontaneous Delayed Effects If Delayed Effects, Specify .......................................................... (x) Other Comments: Must NOT be confused with Organophosphorus compounds