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(-CH2-CH-)n
COOH
CH2
CH2
(-CH2-CH2-CH2-O-)n
H2N-(CH2)5-NH2
ClO-(CH2)5-COCl
(-HN-(CH2)5-NH-O-(CH2)5-CO-)n
H3C
NCO + HO-CH2CH2-OH
CH3
HN-C(O)-OCH2CH2-O
-C(O)-NH
NCO
Condensation polymer
CH2=CH-F
(-CH2-CH-)n
F
Vinyl flour, addition polymer
2. Polystyren
Fraction
A
B
C
D
E
F
G
H
M = 103 g
Weight fraction
(wi)
0.01
0.19
0.24
0.18
0.2
0.08
0.06
0.04
Molecular
weight Mi
12.103
21.103
35.103
49.103
73.103
102.103
122.103
146.103
Number of
molecules Ni
8.3.10-4
90.5.10-4
68.6.10-4
.36.7.10-4
27.4.10-4
7.8.10-4
4.9.10-4
2.7.10-4
Number of
fraction ni
0.03
0.37
0.28
0.15
0.11
0.03
0.02
0.01
Ni =
wi M
Mi
M i = wi M i = 57250g / mol
i
M n = ni M i = 40270g / mol
i
Number fraction
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
0
20
40
60
80
100
120
140
160
Mi 10-3
3. Osmotic pressure
(1) fill out the osmotic pressure
Concentration, c (g/l)
2.00
4.00
6.00
2.585
5.965
9.660
Osmotic pressure (cm, xylene)
-2
2030.972
4684.744
7586.694
Osmotic pressure (g/cm.sec )
2
-2
1.015
1.171
1.264
/c (cm /sec
(2) Draw the graph showing relationship between concentration and /c
180
120
y = 5.76x + 91.65
60
0
0
10
8.00
13.9535
10944.159
1.368
N M
=
N M
Mw
W M
i
Wi
= wi M i
i
Mole
fraction
0.003
0.039
0.165
0.286
0.270
0.165
0.057
0.014
Weight
fraction
0.226
0.116
0.596
0.031
0.016
0.008
0.004
0.002
Molecular weight
(g/mol)
97051
49888.44
255585.86
13152.25
6745.28
3467.368
1778.28
913.06
y = -0.0579x + 12.514
1.000
0.000
130
135
140
145
150
155
160
165
170
retention volume