THE ADITYA BIRLA PUBLIC SCHOOL-RENUKOOT SECOND PRE-BOARD EXAM-2012-13

CLASS SUBJECT

: XII : CHEMISTRY (043)

MAX. MARKS TIME

: :

70 3 HRS.

General Instruction: 1. All question are compulsory. 2. Question number 1 to 8 are very short answer questions and carry 1 mark each. 3. Question number 9 to 18 are short answer questions and carry 2 marks each. 4. Question number 19 to 27 are also short answer questions and carry 3 marks each. 5. Question number 28 to 30 are also long answer questions and carry 5 marks each. 6. Use log table, if necessary. Use of calculators is not allowed. Q. No
Q.1.

For the reaction. N2(g) + 3H2(g) [NH3] if t What is the value of t [H2] ? 2NH3(g)

= 4 X 10-8 mol l-1 Sec-1 ,

Q.2 Q.3.

What type of linkage holds together the monomers of DNA? Write the reaction which shows that all the carbon atoms in glucose are linked in a straight chain.

Q.4. Q.5.

Why is ortho-nitro phenol more acidic than ortho-methoxy phenol? What is the denticity of a co-ordination compound used for the treatment of lead poisoning?

Q.6.

Which of the following is most effective electrolyte in the coagulation of ag I/ ag+ sol?

K2SO4, MgCl2, K4[Fe(CN)6] Q.7. Q.8. What is the basiciy of H3PO2 acid and why? Give the IUPAC name of the following compound (CH3)3 C C COOH O Give reason for the following. (i) O- Toludine is more basic than aniline. (ii) Tertiary amines do not undergo acetylation reaction.

Q.9.

Q.10 Explain the following: (i) (ii) Nickel (II) does not form low spin octahedral complexes. [Fe(CN)6]4- and {Fe(H2O)6]2+ are of different colours in dilute solutions. Q.11 Rate constant K for first order reaction has been found to be 2.54 x 10-3 s-1. Calculate its three fourth life. Q.12 State a reaction for each of the following statements. (i) (ii) Soaps do not work in hard water. The use of the sweetner aspartame is limited to cold food and drinks. Q.13 Complete the following reaction equations: (i) (ii) C6H5N2Cl + H3PO2 + H2O C6H5NH2 + Br2(aq)

Q.14 Explain the following: (i) Actinoid contraction is greater from element to element than Lanthanoid contraction, Why? (ii) Cu2+ is much more stable than Cu+ in aqueous solution. Why ? OR (i) In the titration of FeSo4 with KMnO4 in the acidic medium, why is dil. H2SO4 used instead of dil. HCl ? (ii) Ce4+ is used as an oxidising agent in volumetric analysis. Why?

Q.15 Explain the following: (a) Grignard reagents should be prepared under anhydrous conditions : (b) C6H5CH(Cl)CH3 is hydrolysed more easily with KOH than C6H5CH2Cl. OR (a) Alcohols are easily protonated in comparison to phenols. (b) The relative ease of dehydration of alcohols is tertiary > secondary > primary Q.16 A 1.00 molal aqueous solution of trichloro acetic acid (CCl3COOH) is heated to its boiling point. The solution has the boiling point of 100.18oc. Determine the vant Hoff factor for trichloro acetic acid. [Kb for water = 0.512 K Kg mol -1]

Q.17 Sodium crystallizes in a bcc unit cell. Calculate the approximate number of unit cells in 9.2 g of sodium. ( Atomic mass of Na = 23 u ) Q.18 (a) For a weak electrolyte, molar conductance in dilute solution is increases sharply as its concentration in solution is decreased. Give reason. (b) Write overall cell reaction for lead storage battery when the battery being charged. Q.19 (a) Identify aliphatic biodegradable polymer which is used in packaging and orthopaedic devices. (i) (ii) (iii) Write its full form. Give the structures of monomers from which it is formed. Show the formation of polymer. is

(b) Write the name and structure of the monomer of nylon-6. Q.20 Account for the following: (a) Chloromethane reacts with KCN to form ethane nitrile as main product and with AgCN to form methylisocyanide as chief product. (b) Chloroform should be stored in dark coloured bottles and these bottles should be completely filled. (c) Benzylic halides show high reactivity towards SN1 reaction. Q.21 Write balanced chemical equations for the following reactions (a) Thermal decomposition of ammonium dichromate. (b) Reaction of Cl2 with cold and dilute NaOH . (c) When phosphine is passed through mercuric chloride solution. Q.22 (a) Extraction of gold (Au) by leaching with NaCN involves both oxidation and reduction. Justify by giving equations for the reaction involved. (b) Why is the froth floatation method selected for the concentration of sulphide ores? OR Outline the principle of the method used for refining of (a) Nickel (b) Zirconium (c) Tin

Q.23 Define the following terms giving one suitable example for each: (i) (ii) (iii) Electrophoresis Micelles Peptization OR What is observation when: (i) (ii) (iii) A beam of light is passed through a colloidal solution? Electric current is passed through a colloidal solution? River water meets sea, a delta is formed at the meeting place?

Q.24 (a) Write the Zwitterion structure of glycine. (b) What is meant by inversion of sugar? (c) (i) (ii) Name the vitamin in each case whose deficiency causes. Night blindness. Poor coagulation of blood.

Q.25 An organic compound X which is manufactured by heating a mixture of chloral and chlorobenzene in the presence of concentrated H2So4 is used as an insecticide. The use of compound X is banned in many countries. The compound is very effective against mosquitoes which spread malaria.

Answer the following questions based on above information: (i) Name the compound X Give its structural formula and IUPAC name. (ii) Why is the use of compound X banned in many countries? Should we also advocate the ban of this compound though it is banned in many countries? (iii) Which value is reflected in its ban?

Q.26 Complete the following chemical equations: (i) (ii) (iii) Cr2O72 + H+ + I MnO4- + NO2- + H+ MnO4- + C2O42 + H+ OR Write chemical equations for the following processes: (i) Chloride reacts with a hot concentrated solution of sodium hydroxides. (ii) (iii) Orthophosphorus acid is heated. Pt F6 and Xe are mixed together.

Q.27 An aromatic compound A on treatment with aqueous ammonia and heating

forms compound B which on heating with Br2 and KOH forms a compound C of molecular formulas C6H7N. Write the structures and IUPAC names of compounds A,B and C. Write the reactions involved. OR Write the structures of A, B and C in the following reactions: NaCN (i) CH3CH2I A Practical hydrolysis Fe/HCl (ii) C6H5NO2 A 273 K HNO2 B C6H5OH C OH B NaOH + Br2 C

NH3 (iii) CH3COOH Heat A

NaOBr B

NaNO2/ HCl HCLOBr

Q.28 (a) Account for the following: (i) (ii) Pkb of aniline is more than that of methylamine. Chloro acetic acid is stronger than acetic acid.

(iii) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (b) (i) How can you convert an amide into an amine having one carbon less than the starting compound ? Name the reaction. (ii) Give the IUPAC name and structure of the amine obtained by the above method if the amide is 3-chloro butanamide. OR (a) Give reasons: (i) (ii) P-Nitro benzoic acid has higher ka value than benzoic acid . Glucose does not give 2, 4 DNP test and Schiffs test.

(iii) An amide is more acidic than an amine? (b) How will you carry out the following conversions? (i) (ii) toluene P-toluidine P-toluic acid

P-toluidine diazonium chloride

Q.29

(a)

For the reactions: H+ C12H22O11 + H2O Write: (i) (ii) (iii) (iv) Rate of reaction expression Rate law equation Molecularity Order of reaction C6H12O6 + C6H12O6

(b)

The following data were obtained during the first order thermal decomposition of SO2Cl2 at constant volume SO2Cl2 SO2(g) + Cl2(g)

Experiment 1 2

Time/s 0 100

Total pressure/ atm 0.5 0.6

Calculate the rate of reaction when total pressure is 0.65 atm. OR

(a) (b) (c)

Illustrate graphically the effect of Catalyst on activation energy. catalyst have no effect on the equilibrium constant. Why? The decomposition of A into product has value of K as 4.5 x 103 s-1 at 10c and activation energy is 60 KJ mol-1. calculate the temperature at which the value of K would be 1.5 x 104 sec-1.

Q.30 (a)

Account for the following : (i) (ii) Chlorine water has both oxidising and bleaching properties. H3PO2 and H3PO3 act as good reducing agents while H3PO4 does not. (iii) On addition of ozone gas to KI solution, violet-vapours are obtained.

Write chemical equation for the reactions involved in each .

(b)

Draw the structures of the followings : (i) (ii) XeF4 BrF3 OR

(a)

Account for the following : (i) (ii) Bond dissociation energy of F2 is less than that of Cl2. Both NO and ClO2 are odd electron species but NO dimerises while ClO2 does not. (iii) H2S acts only as reducing agent but SO2 acts both as a reducing agent as well as an oxidising agent.

(b)

Draw the structures of the following: (i) (ii) XeF2 H2S2O7